Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis
American Journal of Nano Research and Applications
Volume 3, Issue 1-1, January 2015, Pages: 8-12
Received: Nov. 29, 2014; Accepted: Dec. 19, 2014; Published: Jan. 3, 2015
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Authors
Xiong Peng, School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)
Radoelizo S. A., School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)
Liping Liu, School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)
Yi Luan, School of Materials Science and Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian district, Beijing, 100083 (P. R. China)
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Abstract
A novel homochiral nanoscale compound, [Ca(L-C4H4O6)(H2O)2]•2H2O (Ca(L-tart)(H2O)2), which is derived from calcium ions and L-tartaric acid (L-tart =C4H4O6), was synthesized under hydrothermal condition. It has been characterized by single crystal X-ray diffraction, SEM, XRD, FTIR and TG. The calcium atoms adopt a tetrahedron geometry and each atom coordinates with eight oxygen atoms. The compound forms a two-dimensional network structure in the solid state via hydrogen bonds. Its performance of L-proline detection was tested, which attained effective result for the porous framework. Meanwhile, the high activity was also shown in acetalization catalysis.
Keywords
L-Tartaric Acid, Inorganic-Organic Framework Compound, L-Proline Detection
To cite this article
Xiong Peng, Radoelizo S. A., Liping Liu, Yi Luan, Synthesis of a Novel L-Tartaric Acid Derived Homochiral Nanoscale Framework and Its Application in L-Proline Detection and Acetalization Catalysis, American Journal of Nano Research and Applications. Special Issue: Nanomaterials and Nanosensors for Chemical and Biological Detection. Vol. 3, No. 1-1, 2015, pp. 8-12. doi: 10.11648/j.nano.s.2015030101.12
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