Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattanaik; Anita Routaray; Prasanta Rath; Tungabidya Maharana

doi:doi:10.11648/j.ajac.20130102.13

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Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, Tungabidya Maharana

Published in American Journal of Applied Chemistry (Volume 1, Issue 2)

Received: 25 May 2013 Accepted: Published: 10 July 2013

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Abstract

The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of 3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.

Published in	American Journal of Applied Chemistry (Volume 1, Issue 2)
DOI	10.11648/j.ajac.20130102.13
Page(s)	28-36
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Schiff Base, Polymer Support, Catalysis, Metal Complexes, Phenol, Oxidation

References

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APA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. (2013). Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. American Journal of Applied Chemistry, 1(2), 28-36. https://doi.org/10.11648/j.ajac.20130102.13

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ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattanaik; Anita Routaray; Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am. J. Appl. Chem. 2013, 1(2), 28-36. doi: 10.11648/j.ajac.20130102.13

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AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am J Appl Chem. 2013;1(2):28-36. doi: 10.11648/j.ajac.20130102.13

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@article{10.11648/j.ajac.20130102.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattanaik and Anita Routaray and Prasanta Rath and Tungabidya Maharana},
  title = {Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {2},
  pages = {28-36},
  doi = {10.11648/j.ajac.20130102.13},
  url = {https://doi.org/10.11648/j.ajac.20130102.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130102.13},
  abstract = {The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.},
 year = {2013}
}

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TY  - JOUR
T1  - Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattanaik
AU  - Anita Routaray
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/07/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130102.13
DO  - 10.11648/j.ajac.20130102.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 28
EP  - 36
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130102.13
AB  - The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.
VL  - 1
IS  - 2
ER  -

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Author Information

Alekha Kumar Sutar

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Yasobanta Das

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Sasmita Pattanaik

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Anita Routaray

Catalysis Research Lab, Department of Chemistry, Ravenshaw University, Cuttack-3, Odisha, India
Prasanta Rath

School of Applied Sciences (Chemistry), KIIT University, Bhubaneswar, Odisha, India
Tungabidya Maharana

Department of Chemistry, National Institute of Technology, Raipur, India

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APA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. (2013). Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. American Journal of Applied Chemistry, 1(2), 28-36. https://doi.org/10.11648/j.ajac.20130102.13

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ACS Style

Alekha Kumar Sutar; Yasobanta Das; Sasmita Pattanaik; Anita Routaray; Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am. J. Appl. Chem. 2013, 1(2), 28-36. doi: 10.11648/j.ajac.20130102.13

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AMA Style

Alekha Kumar Sutar, Yasobanta Das, Sasmita Pattanaik, Anita Routaray, Prasanta Rath, et al. Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands. Am J Appl Chem. 2013;1(2):28-36. doi: 10.11648/j.ajac.20130102.13

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@article{10.11648/j.ajac.20130102.13,
  author = {Alekha Kumar Sutar and Yasobanta Das and Sasmita Pattanaik and Anita Routaray and Prasanta Rath and Tungabidya Maharana},
  title = {Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands},
  journal = {American Journal of Applied Chemistry},
  volume = {1},
  number = {2},
  pages = {28-36},
  doi = {10.11648/j.ajac.20130102.13},
  url = {https://doi.org/10.11648/j.ajac.20130102.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20130102.13},
  abstract = {The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.},
 year = {2013}
}

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TY  - JOUR
T1  - Preparation, Characterization, and Catalytic Studies of Iron and Cobalt Complexes Supported by ONNO – Tetradentate Schiff-Base Ligands
AU  - Alekha Kumar Sutar
AU  - Yasobanta Das
AU  - Sasmita Pattanaik
AU  - Anita Routaray
AU  - Prasanta Rath
AU  - Tungabidya Maharana
Y1  - 2013/07/10
PY  - 2013
N1  - https://doi.org/10.11648/j.ajac.20130102.13
DO  - 10.11648/j.ajac.20130102.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 28
EP  - 36
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20130102.13
AB  - The free and polymer anchored complexes of iron and cobalt [3-MHBdMBn-M and P-3-MHBdMBn-M], supported by ONNO-tetradentate Schiff-base ligands are prepared by the reactions of metal solution with one molar equivalent of unsupported 3-MHBdMBn (N, N'-bis (2-hydroxy-3-methylbenzaldehyde) 4-Methylbenzene-1,2-diamine) or polymer supported (P-3-MHBdMBn) Schiff-base ligands in methanol. The structural study reveals that iron(III) complex of  3-MHBdMBn Schiff base is octahedral in geometry, whereas, cobalt(II) ions complexes is square planar. Complexation of metal ions increased the thermal stability of 3-MHBdMBn Schiff base. The catalytic activities of metal complexes towards the oxidation of phenol are investigated in the presence of hydrogen peroxide. Experimental results indicate that the reactivity of P-3-MHBdMBn-M is dramatically affected by the polymer support over 3-MHBdMBn-M and iron complexes have greater activity than the cobalt analogue.
VL  - 1
IS  - 2
ER  -

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