Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base
American Journal of Applied Chemistry
Volume 1, Issue 4, October 2013, Pages: 49-52
Received: Sep. 24, 2013; Published: Oct. 30, 2013
Views 3038      Downloads 135
Author
KHALIL KHALAF ABID, Department of Chemistry, College of Science, Al – Mustanseriyah University, 10053 Baghdad Iraq
Article Tools
PDF
Follow on us
Abstract
A new macrocyclic Schiff base complexes were prepared in the presence of lanthanide metal ion[La(III), Ce(III) and Gd(III)] by the reaction of 2,6 – diamino pyridine, benzoyl aceton and metal ion as template effect in the molar ratio of 2: 2: 1 respectively. The lanthanide metal complexes were characterized and investigated by using; 1HNMR, FTIR, UV/Visible spectroscopy, Elemental analysis (C.H.N.), Magnetic susceptibility and Molar conductivity measurements. The lanthanide metal ions coordinated to six nitrogen atoms of the ligand and three chloride ions to complete geometry of nine coordination complexes.
Keywords
Macrocyclic, Schiff Bases, Lanthanide Complexes, Template Synthesis
To cite this article
KHALIL KHALAF ABID, Synthesis and Characterization of Lanthanide Complexes of N6 – Macrocyclic Schiff Base, American Journal of Applied Chemistry. Vol. 1, No. 4, 2013, pp. 49-52. doi: 10.11648/j.ajac.20130104.11
References
[1]
P. A. Vigato and S. Tamburini; Coord. Chem. Rev., 248 (2004) 1717.
[2]
P. A. Vigato, S. Tamburini and L. Bertolo; Coord. Chem. Rev., 251 (2004) 1311.
[3]
W. Radecka-Paryzek, V. Patroniak and J. Lisowski; Coord. Chem. Rev., 249 (2005) 2156.
[4]
H. Karsilayan, I. Hemmila, H. Takalo, A. Toivonen, K. Pettersson, T. Lovgren and V-M. Mukkala; Bioconjugate Chem., (1997) 871.
[5]
M. Li and P. Selvin; Bioconjugate Chem., 8 (1997) 127.
[6]
R. B. Lauffer; Chem. Rev., 87 (1987) 901.
[7]
S. Aime, M. Botta, M. Fasano and E. Terreno; Acc. Chem. Res., 32 (1999) 941.
[8]
P. H. Smith, J. R. Brainard, D. E. Morris, G. D. Jarvinen and R. R. Ryan; J. Am. Chem. Soc., 111 (1989) 7437.
[9]
K. Kolasa, A. Sharma and J. R. Morrow; Inorg. Chem., 32 (1993) 3983.
[10]
L. L. Chappell, D. A. Voss Jr., W. DeW. Horrocks Jr. and J. R. Morrow; Inorg. Chem., 37 (1998) 3989.
[11]
S. Amin, D. A. Voss Jr, W. DeW. Horrocks Jr. and J. R. Morrow; Inorg. Chem., 35 (1996) 7466.
[12]
J. R. Morrow;" Metal Ions in Biological Systems" (1996) 33H, Sigel (Ed.) Dekker, New York, pp. 561–591.
[13]
A. De Mesmaeker, R. Haner, R. P. Martin, H. E. Moser; Acc. Chem. Res.,28 (1995) 366.
[14]
D. Magda, M. Wright, S. Crofts, A. Lin and J. L. Sessler; J. Am. Chem. Soc.,119 (1997) 6947.
[15]
J. R. Morrow, L. A. Buttrey, V. M. Shelton and K. A. Berback; J. Am. Chem. Soc., 114 (1992) 1903.
[16]
J. Lisowski and P. Starynowicz; Polyhedron,18 (1998) 443.
[17]
E. Spodine, Y. Moreno, M.T. Garland,O. Pena and R. Baggio; Inorg. Chim. Acta,30 (2000) 957
[18]
S. Chandrai, M. Tyagi and S. Agrawalj; Serb. Chem. Soc. 75 (7) (2010) 935
[19]
S. S. Nivasan and P. Athappan ; Transition Met. Chemistry, 26 (2001) 588
[20]
C. Lodeiro, R. Basitida, E. Bertolo, A. Macias and R. Rodriguez ; Transition Met. Chemistry, 28 (2003) 388.
[21]
V. B. Rana, J. N. Gurtu and M. P. Teotia; Indian J. Chem., 19A (1980) 133.
[22]
P. K. Sasmal , S. Saha , R. Majumdar and R. Dighe ; Inorg. Chem., 49(3) (2010) 849.
[23]
M. R. Maurya, A. Kumar, A. R. Bhat, A. R. Azam, A. Bader and D. Rehder ; Inorg. Chem., 45(3) (2006) 1260.
[24]
T. Szczurek, and M. Schlesinger" Rare Earth Spectroscopy" World Scientific, Singapore (1985) p309
[25]
M. H. V. Werts ; Science Progress, 88 (2005) 101.
[26]
N. Greenwood and A. Earnshaw;"Chemistry of the Elements " (1997) p 1242, 2ndedition, Butterworth – Heinmann. ISBN 0080379419.
ADDRESS
Science Publishing Group
1 Rockefeller Plaza,
10th and 11th Floors,
New York, NY 10020
U.S.A.
Tel: (001)347-983-5186