American Journal of Applied Chemistry

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Physical and Spectral Characterization of Ni (II) Cu(II) Co(II) and Cd(II) Complexes with Schiff Base of Salicylaldehyde and 2-Aminopyridine Towards Potential Microbial Application

Received: 01 September 2018    Accepted: 06 October 2018    Published: 29 October 2018
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Abstract

A Schiff base (SB) is derived from salicylaldehyde and 2-aminopyridine. The transition metal complexes of N i(II), Cu (II), Co and Cd (II) metal ions were prepared with this Schiff base (SB), which were used as ligand. Several physical tools, in particular; elemental analysis, molar conductivity, magnetic susceptibility, infrared spectroscopy (IR), electronic absorption spectroscopy (ESR) to investigate the chemical structure of the prepared transition metal complexes. The elemental analysis data shows the formation of 1:2 [M:2L] complex of the formula of M2+L2, where M2+ =Ni(II), Cu(II), Co(II), Cd(II) and L = Schiff base (SB). The molar conductance (conductivity) measurements were revealed that all the complexes are non-electrolyte in nature. The infrared (IR) spectral studies indicated the binding sites of the Schiff base ligand with the transition metal ions. The magnetic susceptibility measurements and electronic spectral results supported the predicted coordination geometry of the complexes and magnetic properties (para or dia-magnetic nature) of the complexes. The Ni(II), Cu(II), Co(II) ion forms high spin tetrahedral geometry, whereas Cd(II) ion forms low spin tetrahedral structure. The free Schiff base and its complexes have been tested for their antimicrobial activities against four human pathogenic (two gram-positive and two gram-negative) bacteria. The obtained results showed that only Cu(II) complex exhibited strong activity toward human pathogenic gram positive and gram negative bacteria whereas the Ni(II), Co(II) and Cd(II) complexes showed week to moderate antimicrobial activity compared with standard Kanamycin and Ampicillin.

DOI 10.11648/j.ajac.20180604.13
Published in American Journal of Applied Chemistry (Volume 6, Issue 4, August 2018)
Page(s) 147-155
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Schiff Base, Metal Complex, Spectral Studies, Antimicrobial Activity

References
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Author Information
  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Textile Engineering, Khwaja Yunus Ali University, Sirajgonj, Bangladesh

  • Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh

  • Department of Chemistry, Begum Rokeya University, Rangpur, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

  • Department of Chemistry, University of Rajshahi, Rajshahi, Bangladesh

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    Md. Motahar Hossain, Md. Abul Bashar, Md. Nuruzzaman Khan, Pijush Kanti Roy, Md. Abdul Mannan, et al. (2018). Physical and Spectral Characterization of Ni (II) Cu(II) Co(II) and Cd(II) Complexes with Schiff Base of Salicylaldehyde and 2-Aminopyridine Towards Potential Microbial Application. American Journal of Applied Chemistry, 6(4), 147-155. https://doi.org/10.11648/j.ajac.20180604.13

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    ACS Style

    Md. Motahar Hossain; Md. Abul Bashar; Md. Nuruzzaman Khan; Pijush Kanti Roy; Md. Abdul Mannan, et al. Physical and Spectral Characterization of Ni (II) Cu(II) Co(II) and Cd(II) Complexes with Schiff Base of Salicylaldehyde and 2-Aminopyridine Towards Potential Microbial Application. Am. J. Appl. Chem. 2018, 6(4), 147-155. doi: 10.11648/j.ajac.20180604.13

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    AMA Style

    Md. Motahar Hossain, Md. Abul Bashar, Md. Nuruzzaman Khan, Pijush Kanti Roy, Md. Abdul Mannan, et al. Physical and Spectral Characterization of Ni (II) Cu(II) Co(II) and Cd(II) Complexes with Schiff Base of Salicylaldehyde and 2-Aminopyridine Towards Potential Microbial Application. Am J Appl Chem. 2018;6(4):147-155. doi: 10.11648/j.ajac.20180604.13

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  • @article{10.11648/j.ajac.20180604.13,
      author = {Md. Motahar Hossain and Md. Abul Bashar and Md. Nuruzzaman Khan and Pijush Kanti Roy and Md. Abdul Mannan and Md. Siddik Ali and Md. Akhter Farooque},
      title = {Physical and Spectral Characterization of Ni (II) Cu(II) Co(II) and Cd(II) Complexes with Schiff Base of Salicylaldehyde and 2-Aminopyridine Towards Potential Microbial Application},
      journal = {American Journal of Applied Chemistry},
      volume = {6},
      number = {4},
      pages = {147-155},
      doi = {10.11648/j.ajac.20180604.13},
      url = {https://doi.org/10.11648/j.ajac.20180604.13},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajac.20180604.13},
      abstract = {A Schiff base (SB) is derived from salicylaldehyde and 2-aminopyridine. The transition metal complexes of N i(II), Cu (II), Co and Cd (II) metal ions were prepared with this Schiff base (SB), which were used as ligand. Several physical tools, in particular; elemental analysis, molar conductivity, magnetic susceptibility, infrared spectroscopy (IR), electronic absorption spectroscopy (ESR) to investigate the chemical structure of the prepared transition metal complexes. The elemental analysis data shows the formation of 1:2 [M:2L] complex of the formula of M2+L2, where M2+ =Ni(II), Cu(II), Co(II), Cd(II) and L = Schiff base (SB). The molar conductance (conductivity) measurements were revealed that all the complexes are non-electrolyte in nature. The infrared (IR) spectral studies indicated the binding sites of the Schiff base ligand with the transition metal ions. The magnetic susceptibility measurements and electronic spectral results supported the predicted coordination geometry of the complexes and magnetic properties (para or dia-magnetic nature) of the complexes. The Ni(II), Cu(II), Co(II) ion forms high spin tetrahedral geometry, whereas Cd(II) ion forms low spin tetrahedral structure. The free Schiff base and its complexes have been tested for their antimicrobial activities against four human pathogenic (two gram-positive and two gram-negative) bacteria. The obtained results showed that only Cu(II) complex exhibited strong activity toward human pathogenic gram positive and gram negative bacteria whereas the Ni(II), Co(II) and Cd(II) complexes showed week to moderate antimicrobial activity compared with standard Kanamycin and Ampicillin.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Physical and Spectral Characterization of Ni (II) Cu(II) Co(II) and Cd(II) Complexes with Schiff Base of Salicylaldehyde and 2-Aminopyridine Towards Potential Microbial Application
    AU  - Md. Motahar Hossain
    AU  - Md. Abul Bashar
    AU  - Md. Nuruzzaman Khan
    AU  - Pijush Kanti Roy
    AU  - Md. Abdul Mannan
    AU  - Md. Siddik Ali
    AU  - Md. Akhter Farooque
    Y1  - 2018/10/29
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ajac.20180604.13
    DO  - 10.11648/j.ajac.20180604.13
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 147
    EP  - 155
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20180604.13
    AB  - A Schiff base (SB) is derived from salicylaldehyde and 2-aminopyridine. The transition metal complexes of N i(II), Cu (II), Co and Cd (II) metal ions were prepared with this Schiff base (SB), which were used as ligand. Several physical tools, in particular; elemental analysis, molar conductivity, magnetic susceptibility, infrared spectroscopy (IR), electronic absorption spectroscopy (ESR) to investigate the chemical structure of the prepared transition metal complexes. The elemental analysis data shows the formation of 1:2 [M:2L] complex of the formula of M2+L2, where M2+ =Ni(II), Cu(II), Co(II), Cd(II) and L = Schiff base (SB). The molar conductance (conductivity) measurements were revealed that all the complexes are non-electrolyte in nature. The infrared (IR) spectral studies indicated the binding sites of the Schiff base ligand with the transition metal ions. The magnetic susceptibility measurements and electronic spectral results supported the predicted coordination geometry of the complexes and magnetic properties (para or dia-magnetic nature) of the complexes. The Ni(II), Cu(II), Co(II) ion forms high spin tetrahedral geometry, whereas Cd(II) ion forms low spin tetrahedral structure. The free Schiff base and its complexes have been tested for their antimicrobial activities against four human pathogenic (two gram-positive and two gram-negative) bacteria. The obtained results showed that only Cu(II) complex exhibited strong activity toward human pathogenic gram positive and gram negative bacteria whereas the Ni(II), Co(II) and Cd(II) complexes showed week to moderate antimicrobial activity compared with standard Kanamycin and Ampicillin.
    VL  - 6
    IS  - 4
    ER  - 

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