Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification

M. F. Elkady; M. A. khodary; A. A. Zaatout

doi:doi:10.11648/j.ajac.s.2015030301.17

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Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification

M. F. Elkady, M. A. khodary, A. A. Zaatout

Published in American Journal of Applied Chemistry (Volume 3, Issue 3-1)

Received: 12 February 2015 Accepted: 13 February 2015 Published: 28 March 2015

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Abstract

Nano-zirconium antimonate was successfully prepared using two different techniques of sol-gel and homogeneous precipitation. The different preparation parameters affecting onto the two preparation techniques such as HCl concentration, reactants molar ratio and effect reaction temperature were optimized to attain cation exchange material with high ion exchange capacity and produced in nano-size structure. The different prepared samples were screened based on their ion exchange capacities. The most proper prepared sample produced from the sol-gel technique poses higher ion exchange capacity value of 3.5meq/g compared with that produced from the homogeneous precipitation that recorded ion exchange capacity of 2.8meq/g. The physico-chemical properties of the two nano-zirconium antimonate samples produced from each technique were compared using various analytical techniques such as XRD, SEM and TEM. XRD results indicated that the sample produced from the homogeneous precipitation attains high crystallinity degree compared with the amorphous sol-gel prepared sample. The morphological structure investigation evident the nano-spherical morphology for the two prepared samples. The average nano-size of the homogeneous precipitation sample of 22nm is smaller than that of the sol-gel sample that recorded 34nm. The dye decontamination behavior of the two prepared nano-zirconium antimonate samples was compared for C.I basic blue 3dye. The sol-gel prepared sample recorded higher dye decolorization of 81.5% compared with 54% for the homogeneous precipitation sample.

Published in	American Journal of Applied Chemistry (Volume 3, Issue 3-1) This article belongs to the Special Issue Nano-Technology for Environmental Aspects
DOI	10.11648/j.ajac.s.2015030301.17
Page(s)	46-53
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Nano- Materials, Zirconium Antimonate, Chemical Characterization, Dye Decolorization

References

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[5]	H. Shokry Hassan, M.F. Elkady, Ahmed El-Shazly, Hesham Bamufleh, Journal of Nanomaterials, 1 (2014) 1-14.
[6]	M. Rikukawa, D. Inagaki, K. Kaneko, Y. Takeoke, I. Ito, Y. Kanzaki, K. Sanui, J. Mol.Stuct., 739 (2005) 153-161.
[7]	Y. Inoue, J. Inorg. Nucl., Chem., 26 (1964) 2241-2253.
[8]	C. Abraham, Inorganic Ion Exchange Materials, CRC Press Inc., Boca Roton, Fl, 1982.
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APA Style

M. F. Elkady, M. A. khodary, A. A. Zaatout. (2015). Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification. American Journal of Applied Chemistry, 3(3-1), 46-53. https://doi.org/10.11648/j.ajac.s.2015030301.17

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ACS Style

M. F. Elkady; M. A. khodary; A. A. Zaatout. Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification. Am. J. Appl. Chem. 2015, 3(3-1), 46-53. doi: 10.11648/j.ajac.s.2015030301.17

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AMA Style

M. F. Elkady, M. A. khodary, A. A. Zaatout. Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification. Am J Appl Chem. 2015;3(3-1):46-53. doi: 10.11648/j.ajac.s.2015030301.17

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@article{10.11648/j.ajac.s.2015030301.17,
  author = {M. F. Elkady and M. A. khodary and A. A. Zaatout},
  title = {Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification},
  journal = {American Journal of Applied Chemistry},
  volume = {3},
  number = {3-1},
  pages = {46-53},
  doi = {10.11648/j.ajac.s.2015030301.17},
  url = {https://doi.org/10.11648/j.ajac.s.2015030301.17},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.s.2015030301.17},
  abstract = {Nano-zirconium antimonate was successfully prepared using two different techniques of sol-gel and homogeneous precipitation. The different preparation parameters affecting onto the two preparation techniques such as HCl concentration, reactants molar ratio and effect reaction temperature were optimized to attain cation exchange material with high ion exchange capacity and produced in nano-size structure. The different prepared samples were screened based on their ion exchange capacities. The most proper prepared sample produced from the sol-gel technique poses higher ion exchange capacity value of 3.5meq/g compared with that produced from the homogeneous precipitation that recorded ion exchange capacity of 2.8meq/g. The physico-chemical properties of the two nano-zirconium antimonate samples produced from each technique were compared using various analytical techniques such as XRD, SEM and TEM. XRD results indicated that the sample produced from the homogeneous precipitation attains high crystallinity degree compared with the amorphous sol-gel prepared sample. The morphological structure investigation evident the nano-spherical morphology for the two prepared samples. The average nano-size of the homogeneous precipitation sample of 22nm is smaller than that of the sol-gel sample that recorded 34nm. The dye decontamination behavior of the two prepared nano-zirconium antimonate samples was compared for C.I basic blue 3dye. The sol-gel prepared sample recorded higher dye decolorization of 81.5% compared with 54% for the homogeneous precipitation sample.},
 year = {2015}
}

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TY - JOUR
T1 - Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification
AU - M. F. Elkady
AU - M. A. khodary
AU - A. A. Zaatout
Y1 - 2015/03/28
PY - 2015
N1 - https://doi.org/10.11648/j.ajac.s.2015030301.17
DO - 10.11648/j.ajac.s.2015030301.17
T2 - American Journal of Applied Chemistry
JF - American Journal of Applied Chemistry
JO - American Journal of Applied Chemistry
SP - 46
EP - 53
PB - Science Publishing Group
SN - 2330-8745
UR - https://doi.org/10.11648/j.ajac.s.2015030301.17
AB - Nano-zirconium antimonate was successfully prepared using two different techniques of sol-gel and homogeneous precipitation. The different preparation parameters affecting onto the two preparation techniques such as HCl concentration, reactants molar ratio and effect reaction temperature were optimized to attain cation exchange material with high ion exchange capacity and produced in nano-size structure. The different prepared samples were screened based on their ion exchange capacities. The most proper prepared sample produced from the sol-gel technique poses higher ion exchange capacity value of 3.5meq/g compared with that produced from the homogeneous precipitation that recorded ion exchange capacity of 2.8meq/g. The physico-chemical properties of the two nano-zirconium antimonate samples produced from each technique were compared using various analytical techniques such as XRD, SEM and TEM. XRD results indicated that the sample produced from the homogeneous precipitation attains high crystallinity degree compared with the amorphous sol-gel prepared sample. The morphological structure investigation evident the nano-spherical morphology for the two prepared samples. The average nano-size of the homogeneous precipitation sample of 22nm is smaller than that of the sol-gel sample that recorded 34nm. The dye decontamination behavior of the two prepared nano-zirconium antimonate samples was compared for C.I basic blue 3dye. The sol-gel prepared sample recorded higher dye decolorization of 81.5% compared with 54% for the homogeneous precipitation sample.
VL - 3
IS - 3-1
ER -

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Author Information

M. F. Elkady

Chemical and Petrochemical Engineering Department, Egypt-Japan University of Science and Technology, New Borg El-Arab City, Alexandria, Egypt; Fabrication Technology Department, Advanced Technology and New Materials and Research Institute (ATNMRI), City of Scientific Research and Technological Applications, Alexandria, Egypt
M. A. khodary

Chemical Engineering Department, Faculty of Engineering, Alexandria, Egypt
A. A. Zaatout

Chemical Engineering Department, Faculty of Engineering, Alexandria, Egypt

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APA Style

M. F. Elkady, M. A. khodary, A. A. Zaatout. (2015). Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification. American Journal of Applied Chemistry, 3(3-1), 46-53. https://doi.org/10.11648/j.ajac.s.2015030301.17

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ACS Style

M. F. Elkady; M. A. khodary; A. A. Zaatout. Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification. Am. J. Appl. Chem. 2015, 3(3-1), 46-53. doi: 10.11648/j.ajac.s.2015030301.17

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AMA Style

M. F. Elkady, M. A. khodary, A. A. Zaatout. Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification. Am J Appl Chem. 2015;3(3-1):46-53. doi: 10.11648/j.ajac.s.2015030301.17

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@article{10.11648/j.ajac.s.2015030301.17,
  author = {M. F. Elkady and M. A. khodary and A. A. Zaatout},
  title = {Novel Nano-Zirconium Antimonate as Cation Exchange Material for Organic Dye Pollutants Purification},
  journal = {American Journal of Applied Chemistry},
  volume = {3},
  number = {3-1},
  pages = {46-53},
  doi = {10.11648/j.ajac.s.2015030301.17},
  url = {https://doi.org/10.11648/j.ajac.s.2015030301.17},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.s.2015030301.17},
  abstract = {Nano-zirconium antimonate was successfully prepared using two different techniques of sol-gel and homogeneous precipitation. The different preparation parameters affecting onto the two preparation techniques such as HCl concentration, reactants molar ratio and effect reaction temperature were optimized to attain cation exchange material with high ion exchange capacity and produced in nano-size structure. The different prepared samples were screened based on their ion exchange capacities. The most proper prepared sample produced from the sol-gel technique poses higher ion exchange capacity value of 3.5meq/g compared with that produced from the homogeneous precipitation that recorded ion exchange capacity of 2.8meq/g. The physico-chemical properties of the two nano-zirconium antimonate samples produced from each technique were compared using various analytical techniques such as XRD, SEM and TEM. XRD results indicated that the sample produced from the homogeneous precipitation attains high crystallinity degree compared with the amorphous sol-gel prepared sample. The morphological structure investigation evident the nano-spherical morphology for the two prepared samples. The average nano-size of the homogeneous precipitation sample of 22nm is smaller than that of the sol-gel sample that recorded 34nm. The dye decontamination behavior of the two prepared nano-zirconium antimonate samples was compared for C.I basic blue 3dye. The sol-gel prepared sample recorded higher dye decolorization of 81.5% compared with 54% for the homogeneous precipitation sample.},
 year = {2015}
}

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