Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS)

Sayudi Yahaya Haruna; Umar Zaki Faruq; Aminu Yakubu Zubairu; Muhammad Gidado Liman; Maryam Lami Riskuwa

doi:doi:10.11648/j.ajac.20180601.13

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Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO₄+H₂O₂/CH₃COOH and KMnO₄+H₂O₂/HCOOH Via Oxidative Desulphurization (ODS)

Sayudi Yahaya Haruna, Umar Zaki Faruq, Aminu Yakubu Zubairu, Muhammad Gidado Liman, Maryam Lami Riskuwa

Published in American Journal of Applied Chemistry (Volume 6, Issue 1)

Received: 10 December 2017 Accepted: 28 December 2017 Published: 17 January 2018

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Abstract

Increase by agency protocols, international organisation regulations, and government regulations in many countries, demand for uncontaminated fuel and the use of more environmentally friendly transportation fuels with minor contents of sulphur compound (SOx) and aromatics compound lead to the search of pre-sulphur. In the present time, the demand for transportation fuels has been increasing in many countries for the past two decades. The study reported the compared oxidation-extraction desulphurization of heavy crude oil using combined oxidants potassium permanganate and hydrogen peroxide (KMnO₄+H₂O₂) over acetic acid (CH₃COOH) and Formic acid (HCOOH) catalysis. The following results were obtained; formic acid (HCOOH) with higher sulphur reduction by (73.00%), while acetic acid (CH₃COOH) with lower sulphur reduction by (27.02%). The study concluded that combined oxidants (KMnO₄+H₂O₂) with formic acid (HCOOH) catalysed reaction system is better than using combined oxidants (KMnO₄+H₂O₂) with acetic CH₃COOH catalyst. Moreover DMSO was found to be a pathetic and inadequate solvent for extraction of oxidized sulphur since, it present more sulphur into the oxidised oil higher than that up fresh sample.

Published in	American Journal of Applied Chemistry (Volume 6, Issue 1)
DOI	10.11648/j.ajac.20180601.13
Page(s)	15-24
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Acetic Acid, Formic Acid, Heavy Crude Oil, ODS, Mix Oxidants (KMnO₄+H₂O₂)

References

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Sayudi Yahaya Haruna, Umar Zaki Faruq, Aminu Yakubu Zubairu, Muhammad Gidado Liman, Maryam Lami Riskuwa. (2018). Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS). American Journal of Applied Chemistry, 6(1), 15-24. https://doi.org/10.11648/j.ajac.20180601.13

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ACS Style

Sayudi Yahaya Haruna; Umar Zaki Faruq; Aminu Yakubu Zubairu; Muhammad Gidado Liman; Maryam Lami Riskuwa. Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS). Am. J. Appl. Chem. 2018, 6(1), 15-24. doi: 10.11648/j.ajac.20180601.13

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AMA Style

Sayudi Yahaya Haruna, Umar Zaki Faruq, Aminu Yakubu Zubairu, Muhammad Gidado Liman, Maryam Lami Riskuwa. Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS). Am J Appl Chem. 2018;6(1):15-24. doi: 10.11648/j.ajac.20180601.13

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@article{10.11648/j.ajac.20180601.13,
  author = {Sayudi Yahaya Haruna and Umar Zaki Faruq and Aminu Yakubu Zubairu and Muhammad Gidado Liman and Maryam Lami Riskuwa},
  title = {Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS)},
  journal = {American Journal of Applied Chemistry},
  volume = {6},
  number = {1},
  pages = {15-24},
  doi = {10.11648/j.ajac.20180601.13},
  url = {https://doi.org/10.11648/j.ajac.20180601.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180601.13},
  abstract = {Increase by agency protocols, international organisation regulations, and government regulations in many countries, demand for uncontaminated fuel and the use of more environmentally friendly transportation fuels with minor contents of sulphur compound (SOx) and aromatics compound lead to the search of pre-sulphur. In the present time, the demand for transportation fuels has been increasing in many countries for the past two decades. The study reported the compared oxidation-extraction desulphurization of heavy crude oil using combined oxidants potassium permanganate and hydrogen peroxide (KMnO4+H2O2) over acetic acid (CH3COOH) and Formic acid (HCOOH) catalysis. The following results were obtained; formic acid (HCOOH) with higher sulphur reduction by (73.00%), while acetic acid (CH3COOH) with lower sulphur reduction by (27.02%). The study concluded that combined oxidants (KMnO4+H2O2) with formic acid (HCOOH) catalysed reaction system is better than using combined oxidants (KMnO4+H2O2) with acetic CH3COOH catalyst. Moreover DMSO was found to be a pathetic and inadequate solvent for extraction of oxidized sulphur since, it present more sulphur into the oxidised oil higher than that up fresh sample.},
 year = {2018}
}

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TY  - JOUR
T1  - Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS)
AU  - Sayudi Yahaya Haruna
AU  - Umar Zaki Faruq
AU  - Aminu Yakubu Zubairu
AU  - Muhammad Gidado Liman
AU  - Maryam Lami Riskuwa
Y1  - 2018/01/17
PY  - 2018
N1  - https://doi.org/10.11648/j.ajac.20180601.13
DO  - 10.11648/j.ajac.20180601.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 15
EP  - 24
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20180601.13
AB  - Increase by agency protocols, international organisation regulations, and government regulations in many countries, demand for uncontaminated fuel and the use of more environmentally friendly transportation fuels with minor contents of sulphur compound (SOx) and aromatics compound lead to the search of pre-sulphur. In the present time, the demand for transportation fuels has been increasing in many countries for the past two decades. The study reported the compared oxidation-extraction desulphurization of heavy crude oil using combined oxidants potassium permanganate and hydrogen peroxide (KMnO4+H2O2) over acetic acid (CH3COOH) and Formic acid (HCOOH) catalysis. The following results were obtained; formic acid (HCOOH) with higher sulphur reduction by (73.00%), while acetic acid (CH3COOH) with lower sulphur reduction by (27.02%). The study concluded that combined oxidants (KMnO4+H2O2) with formic acid (HCOOH) catalysed reaction system is better than using combined oxidants (KMnO4+H2O2) with acetic CH3COOH catalyst. Moreover DMSO was found to be a pathetic and inadequate solvent for extraction of oxidized sulphur since, it present more sulphur into the oxidised oil higher than that up fresh sample.
VL  - 6
IS  - 1
ER  -

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Author Information

Sayudi Yahaya Haruna

Department of Pure and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria
Umar Zaki Faruq

Department of Pure and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria
Aminu Yakubu Zubairu

Department of Pure and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria; Department of Science Laboratory Technology, Umaru Ali Shinkafi Polytechnic, Sokoto, Nigeria
Muhammad Gidado Liman

Department of Pure and Applied Chemistry, Usmanu Danfodiyo University, Sokoto, Nigeria
Maryam Lami Riskuwa

Department of Micro Biology, Usmanu Danfodiyo University, Sokoto, Nigeria

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APA Style

Sayudi Yahaya Haruna, Umar Zaki Faruq, Aminu Yakubu Zubairu, Muhammad Gidado Liman, Maryam Lami Riskuwa. (2018). Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS). American Journal of Applied Chemistry, 6(1), 15-24. https://doi.org/10.11648/j.ajac.20180601.13

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ACS Style

Sayudi Yahaya Haruna; Umar Zaki Faruq; Aminu Yakubu Zubairu; Muhammad Gidado Liman; Maryam Lami Riskuwa. Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS). Am. J. Appl. Chem. 2018, 6(1), 15-24. doi: 10.11648/j.ajac.20180601.13

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AMA Style

Sayudi Yahaya Haruna, Umar Zaki Faruq, Aminu Yakubu Zubairu, Muhammad Gidado Liman, Maryam Lami Riskuwa. Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS). Am J Appl Chem. 2018;6(1):15-24. doi: 10.11648/j.ajac.20180601.13

Copy | Download

@article{10.11648/j.ajac.20180601.13,
  author = {Sayudi Yahaya Haruna and Umar Zaki Faruq and Aminu Yakubu Zubairu and Muhammad Gidado Liman and Maryam Lami Riskuwa},
  title = {Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS)},
  journal = {American Journal of Applied Chemistry},
  volume = {6},
  number = {1},
  pages = {15-24},
  doi = {10.11648/j.ajac.20180601.13},
  url = {https://doi.org/10.11648/j.ajac.20180601.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180601.13},
  abstract = {Increase by agency protocols, international organisation regulations, and government regulations in many countries, demand for uncontaminated fuel and the use of more environmentally friendly transportation fuels with minor contents of sulphur compound (SOx) and aromatics compound lead to the search of pre-sulphur. In the present time, the demand for transportation fuels has been increasing in many countries for the past two decades. The study reported the compared oxidation-extraction desulphurization of heavy crude oil using combined oxidants potassium permanganate and hydrogen peroxide (KMnO4+H2O2) over acetic acid (CH3COOH) and Formic acid (HCOOH) catalysis. The following results were obtained; formic acid (HCOOH) with higher sulphur reduction by (73.00%), while acetic acid (CH3COOH) with lower sulphur reduction by (27.02%). The study concluded that combined oxidants (KMnO4+H2O2) with formic acid (HCOOH) catalysed reaction system is better than using combined oxidants (KMnO4+H2O2) with acetic CH3COOH catalyst. Moreover DMSO was found to be a pathetic and inadequate solvent for extraction of oxidized sulphur since, it present more sulphur into the oxidised oil higher than that up fresh sample.},
 year = {2018}
}

Copy | Download

TY  - JOUR
T1  - Comparative Studies on Reduction of Sulphur Content of Heavy Crude Oil Using KMnO4+H2O2/CH3COOH and KMnO4+H2O2/HCOOH Via Oxidative Desulphurization (ODS)
AU  - Sayudi Yahaya Haruna
AU  - Umar Zaki Faruq
AU  - Aminu Yakubu Zubairu
AU  - Muhammad Gidado Liman
AU  - Maryam Lami Riskuwa
Y1  - 2018/01/17
PY  - 2018
N1  - https://doi.org/10.11648/j.ajac.20180601.13
DO  - 10.11648/j.ajac.20180601.13
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 15
EP  - 24
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20180601.13
AB  - Increase by agency protocols, international organisation regulations, and government regulations in many countries, demand for uncontaminated fuel and the use of more environmentally friendly transportation fuels with minor contents of sulphur compound (SOx) and aromatics compound lead to the search of pre-sulphur. In the present time, the demand for transportation fuels has been increasing in many countries for the past two decades. The study reported the compared oxidation-extraction desulphurization of heavy crude oil using combined oxidants potassium permanganate and hydrogen peroxide (KMnO4+H2O2) over acetic acid (CH3COOH) and Formic acid (HCOOH) catalysis. The following results were obtained; formic acid (HCOOH) with higher sulphur reduction by (73.00%), while acetic acid (CH3COOH) with lower sulphur reduction by (27.02%). The study concluded that combined oxidants (KMnO4+H2O2) with formic acid (HCOOH) catalysed reaction system is better than using combined oxidants (KMnO4+H2O2) with acetic CH3COOH catalyst. Moreover DMSO was found to be a pathetic and inadequate solvent for extraction of oxidized sulphur since, it present more sulphur into the oxidised oil higher than that up fresh sample.
VL  - 6
IS  - 1
ER  -

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