American Journal of Applied Chemistry

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Heavy Metals Adsorption from Aqueous Solutions onto Unmodified and Modified Jordanian Kaolinite Clay: Batch and Column Techniques

Received: 16 December 2017    Accepted: 06 January 2018    Published: 18 January 2018
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Abstract

Awareness of, and concern about, water pollution all over the world has been increasing. In Jordan, water also has been polluted by different kinds of pollutants such as heavy metals, It is widely agreed that a properly developed green, low – cost and more efficient adsorbent is desired approach towards removing pollutants. Jordan has huge reserves of kaolinite. Unfortunately, it has a relative low cation–exchange capacity and a small surface area. However, it can be modified to enhance its adsorption capacity towards heavy metal ions. Humic acid was used to this purpose. Two types of humic acid were used; one was commercial from Fluka Company and the other was natural extracted from King Talal Dam sediments. Comparison of Pb (II), Cd (II) and Zn (II) adsorption from aqueous solutions onto unmodified and modified Jordanian kaolinite clay were studied using batch technique at different temperatures (25, 35 and 45°C) and different pH (4, 5 and 6). The effects of contact time, adsorbent dose, and the initial metal ion concentration were also studied. The uptake at low concentration reaches above 90% for Pb (II). The adsorbed amount trend was as follows: Pb (II) > Cd (II) > Zn (II) for both modified kaolinite clay. The column technique was used effectively for the determination of metal ion loading capacity. The uptake percentage fall in the same order (Pb (II) > Cd (II) > Zn (II)) for both modified kaolinite clay.

DOI 10.11648/j.ajac.20180601.14
Published in American Journal of Applied Chemistry (Volume 6, Issue 1, February 2018)
Page(s) 25-34
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Heavy Metal Ions, Adsorption Isotherms, Humic Acid, Jordanian Kaolinite, Batch Technique, Column Technique

References
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Author Information
  • Chemistry Department, Jerash University, Jerash, Jordan

  • Chemistry Department, University of Jordan, Amman, Jordan

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    Khansaa Al-Essa, Fawwaz Khalili. (2018). Heavy Metals Adsorption from Aqueous Solutions onto Unmodified and Modified Jordanian Kaolinite Clay: Batch and Column Techniques. American Journal of Applied Chemistry, 6(1), 25-34. https://doi.org/10.11648/j.ajac.20180601.14

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    ACS Style

    Khansaa Al-Essa; Fawwaz Khalili. Heavy Metals Adsorption from Aqueous Solutions onto Unmodified and Modified Jordanian Kaolinite Clay: Batch and Column Techniques. Am. J. Appl. Chem. 2018, 6(1), 25-34. doi: 10.11648/j.ajac.20180601.14

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    AMA Style

    Khansaa Al-Essa, Fawwaz Khalili. Heavy Metals Adsorption from Aqueous Solutions onto Unmodified and Modified Jordanian Kaolinite Clay: Batch and Column Techniques. Am J Appl Chem. 2018;6(1):25-34. doi: 10.11648/j.ajac.20180601.14

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  • @article{10.11648/j.ajac.20180601.14,
      author = {Khansaa Al-Essa and Fawwaz Khalili},
      title = {Heavy Metals Adsorption from Aqueous Solutions onto Unmodified and Modified Jordanian Kaolinite Clay: Batch and Column Techniques},
      journal = {American Journal of Applied Chemistry},
      volume = {6},
      number = {1},
      pages = {25-34},
      doi = {10.11648/j.ajac.20180601.14},
      url = {https://doi.org/10.11648/j.ajac.20180601.14},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajac.20180601.14},
      abstract = {Awareness of, and concern about, water pollution all over the world has been increasing. In Jordan, water also has been polluted by different kinds of pollutants such as heavy metals, It is widely agreed that a properly developed green, low – cost and more efficient adsorbent is desired approach towards removing pollutants. Jordan has huge reserves of kaolinite. Unfortunately, it has a relative low cation–exchange capacity and a small surface area. However, it can be modified to enhance its adsorption capacity towards heavy metal ions. Humic acid was used to this purpose. Two types of humic acid were used; one was commercial from Fluka Company and the other was natural extracted from King Talal Dam sediments. Comparison of Pb (II), Cd (II) and Zn (II) adsorption from aqueous solutions onto unmodified and modified Jordanian kaolinite clay were studied using batch technique at different temperatures (25, 35 and 45°C) and different pH (4, 5 and 6). The effects of contact time, adsorbent dose, and the initial metal ion concentration were also studied. The uptake at low concentration reaches above 90% for Pb (II). The adsorbed amount trend was as follows: Pb (II) > Cd (II) > Zn (II) for both modified kaolinite clay. The column technique was used effectively for the determination of metal ion loading capacity. The uptake percentage fall in the same order (Pb (II) > Cd (II) > Zn (II)) for both modified kaolinite clay.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Heavy Metals Adsorption from Aqueous Solutions onto Unmodified and Modified Jordanian Kaolinite Clay: Batch and Column Techniques
    AU  - Khansaa Al-Essa
    AU  - Fawwaz Khalili
    Y1  - 2018/01/18
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ajac.20180601.14
    DO  - 10.11648/j.ajac.20180601.14
    T2  - American Journal of Applied Chemistry
    JF  - American Journal of Applied Chemistry
    JO  - American Journal of Applied Chemistry
    SP  - 25
    EP  - 34
    PB  - Science Publishing Group
    SN  - 2330-8745
    UR  - https://doi.org/10.11648/j.ajac.20180601.14
    AB  - Awareness of, and concern about, water pollution all over the world has been increasing. In Jordan, water also has been polluted by different kinds of pollutants such as heavy metals, It is widely agreed that a properly developed green, low – cost and more efficient adsorbent is desired approach towards removing pollutants. Jordan has huge reserves of kaolinite. Unfortunately, it has a relative low cation–exchange capacity and a small surface area. However, it can be modified to enhance its adsorption capacity towards heavy metal ions. Humic acid was used to this purpose. Two types of humic acid were used; one was commercial from Fluka Company and the other was natural extracted from King Talal Dam sediments. Comparison of Pb (II), Cd (II) and Zn (II) adsorption from aqueous solutions onto unmodified and modified Jordanian kaolinite clay were studied using batch technique at different temperatures (25, 35 and 45°C) and different pH (4, 5 and 6). The effects of contact time, adsorbent dose, and the initial metal ion concentration were also studied. The uptake at low concentration reaches above 90% for Pb (II). The adsorbed amount trend was as follows: Pb (II) > Cd (II) > Zn (II) for both modified kaolinite clay. The column technique was used effectively for the determination of metal ion loading capacity. The uptake percentage fall in the same order (Pb (II) > Cd (II) > Zn (II)) for both modified kaolinite clay.
    VL  - 6
    IS  - 1
    ER  - 

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