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Study on Ultra Shallow Junction n-MOS with 350°C Microwave Annealing for Activation of Phosphorus Dopants in Germanium

Received: 1 March 2017    Accepted:     Published: 3 March 2017
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Abstract

In this study, low-energy microwave annealing is used to fabricate ultra-shallow junctions for less than 20 nm IC node applications in a potential material: Germanium (Ge). Germanium is a new promising material and might replace silicon in the future. A novel microwave annealing technique with two steps for the solid phase epitaxial recrystallization (SPER) and phosphorus dopants activation was applied to Germanium. The purpose of the first step, microwave annealing of 1.2 kW for 75 s, is to re-grow the amorphous layer and repair the destroyed crystal lattices caused by ion implantation. In the second-step of annealing, low-energy microwave, 0.9 kW (≈350°C) for 300 s, is used to activate the phosphorus dopants effectively without diffusion and de-activation. The target dopant activation concentration level will achieve 1020 cm-3. The sheet resistance will decrease to 78 ohm/sq. The low resistance after activating is reflected to the performance of the n-MOS device fabricated by the Ge substrate. The S. S. factor is 900 mV/dec, and the Ion/off ratio rise to 2.6×101. This has demonstrated that the two-step MWA has excellent control, significantly regarding leakage current.

Published in Journal of Electrical and Electronic Engineering (Volume 5, Issue 1)
DOI 10.11648/j.jeee.20170501.12
Page(s) 7-12
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Activation, Germanium, Implant, Microwave Annealing, Solid Phase Epitaxial Recrystallization (SPER)

References
[1] Aditya Agarwal, H. -J. Gossmann, D. J. Eaglesham, L. Pelaz, D. C. Jacobson, T. E. Haynes and Yu. E. Erokhin, “Reduction of transient diffusion from 1–5 keV Si+ ion implantation due to surface annihilation of interstitials,” Appl. Phys. Lett. 71, 3141 (1997).
[2] B. J. Pawlak, W. Vandervorst, A. J. Smith, N. E. B. Cowern, B. Colombeau and X. Pages, “Enhanced boron activation in silicon by high ramp-up rate solid phase epitaxial regrowth,” Appl. Phys. Lett., 86, 101913 (2005).
[3] M. Koike, Y. Kamata, T. Ino, D. Hagishima, K. Tatsumura, M. Koyama and A. Nishiyama, “Diffusion and activation of n-type dopants in germanium,” J. Appl. Phys., 104, 023523, 31 July (2008).
[4] T. Yamaguchi, Y. Kawasaki, T. Yamashita, Y. Yamamoto, Y. Goto, J. Tsuchimoto, S. Kudo, K. Maekawa, M. Fujisawa, and K. Asai, “Low-resistive and homogenous NiPt-silicide formation using ultra-low temperature annealing with microwave system for 22nm-node CMOS and beyond,” IEDM Tech. Dig. (2010), p. 576.
[5] J. M. Kowalski, J. E. Kowalski, and B. Lojek, “Microwave Annealing for Low Temperature Activation of As in Si,” Proc. 15th IEEE Int. Conf. Advanced Thermal Processing of Semiconductors (RTP). (2007), p. 51.
[6] C. Hu, P. Xu, C. Fu, Z. Zhu, X. Gao, A. Jamshidi, M. Noroozi, H. Radamson, D. Wu, and S.-L. Zhang, “Characterization of Ni (Si, Ge) films on epitaxial SiGe (100) formed by microwave annealing,” Appl. Phys. Lett. 101, 092101 (2012).
[7] T. L. Alford, D. C. Thompson, J. W. Mayer, and N. D. Theodore, “Dopant activation in ion implanted silicon by microwave annealing,” J. Appl. Phys. 106, 114902 (2009).
[8] T. L. Alford, I. Ahmad, and R. Hubbard, “Variable frequency microwave induced low temperature dopant activation in ion implanted silicon,” in Proc. 17th Int. Conf. Adv. Thermal Process. Semicond., Oct. 2009, pp. 1–5.
[9] Y. J. Lee, F. K. Hsueh, M. I. Current, C. Y. Wu, and T. S. Chao, “Susceptor coupling for the uniformity and dopant activation efficiency in implanted Si under fixed-frequency microwave anneal,” IEEE Electron Device Lett., vol. 33, no. 2, pp. 248–250, Feb. 2012.
[10] Yao-Jen Lee, Ta-Chun Cho, Shang-Shiun Chuang, Fu-Kuo Hsueh, Yu-Lun Lu, Po-Jung Sung, Hsiu-Chih Chen, Michael I. Current, Tseung-Yuen Tseng, Tien-Sheng Chao, Chenming Hu, and Fu-Liang Yang, “Low-Temperature Microwave Annealing Processes for Future IC Fabrication—A Review,” IEEE TRANSACTIONS ON ELECTRON DEVICES, VOL. 61, NO. 3, MARCH 2014.
[11] Lee, Y. J., Chuang, S. S. and Liu, C. I., “Dopant activation in single crystalline germanium by low temperature microwave annealing,” International Electron Devices Meeting, San Francisco, USA, pp. 514–516, 10–13 December, (2012).
[12] N. Ioannou, D. Skarlatos, C. Tsamis, C. A. Krontiras, S. N. Georga, A. Christofi, and D. S. McPhail, “Germanium substrate loss during low temperature annealing and its influence on ion-implanted phosphorous dose loss,” Appl. Phys. Lett. 93, 101910 (2008).
[13] Shinichi Takagi, Rui Zhang, JunkyoSuh, Sang-Hyeon Kim, Masafumi Yokoyama, Koichi Nishi, and Mitsuru Takenaka, “III–V/Ge channel MOS device technologies in nano CMOS era,” Appl. Phys. 54, 06FA01 (2015).
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    Tzu-Lang Shih, Wen-Hsi Lee. (2017). Study on Ultra Shallow Junction n-MOS with 350°C Microwave Annealing for Activation of Phosphorus Dopants in Germanium. Journal of Electrical and Electronic Engineering, 5(1), 7-12. https://doi.org/10.11648/j.jeee.20170501.12

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    ACS Style

    Tzu-Lang Shih; Wen-Hsi Lee. Study on Ultra Shallow Junction n-MOS with 350°C Microwave Annealing for Activation of Phosphorus Dopants in Germanium. J. Electr. Electron. Eng. 2017, 5(1), 7-12. doi: 10.11648/j.jeee.20170501.12

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    AMA Style

    Tzu-Lang Shih, Wen-Hsi Lee. Study on Ultra Shallow Junction n-MOS with 350°C Microwave Annealing for Activation of Phosphorus Dopants in Germanium. J Electr Electron Eng. 2017;5(1):7-12. doi: 10.11648/j.jeee.20170501.12

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  • @article{10.11648/j.jeee.20170501.12,
      author = {Tzu-Lang Shih and Wen-Hsi Lee},
      title = {Study on Ultra Shallow Junction n-MOS with 350°C Microwave Annealing for Activation of Phosphorus Dopants in Germanium},
      journal = {Journal of Electrical and Electronic Engineering},
      volume = {5},
      number = {1},
      pages = {7-12},
      doi = {10.11648/j.jeee.20170501.12},
      url = {https://doi.org/10.11648/j.jeee.20170501.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeee.20170501.12},
      abstract = {In this study, low-energy microwave annealing is used to fabricate ultra-shallow junctions for less than 20 nm IC node applications in a potential material: Germanium (Ge). Germanium is a new promising material and might replace silicon in the future. A novel microwave annealing technique with two steps for the solid phase epitaxial recrystallization (SPER) and phosphorus dopants activation was applied to Germanium. The purpose of the first step, microwave annealing of 1.2 kW for 75 s, is to re-grow the amorphous layer and repair the destroyed crystal lattices caused by ion implantation. In the second-step of annealing, low-energy microwave, 0.9 kW (≈350°C) for 300 s, is used to activate the phosphorus dopants effectively without diffusion and de-activation. The target dopant activation concentration level will achieve 1020 cm-3. The sheet resistance will decrease to 78 ohm/sq. The low resistance after activating is reflected to the performance of the n-MOS device fabricated by the Ge substrate. The S. S. factor is 900 mV/dec, and the Ion/off ratio rise to 2.6×101. This has demonstrated that the two-step MWA has excellent control, significantly regarding leakage current.},
     year = {2017}
    }
    

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  • TY  - JOUR
    T1  - Study on Ultra Shallow Junction n-MOS with 350°C Microwave Annealing for Activation of Phosphorus Dopants in Germanium
    AU  - Tzu-Lang Shih
    AU  - Wen-Hsi Lee
    Y1  - 2017/03/03
    PY  - 2017
    N1  - https://doi.org/10.11648/j.jeee.20170501.12
    DO  - 10.11648/j.jeee.20170501.12
    T2  - Journal of Electrical and Electronic Engineering
    JF  - Journal of Electrical and Electronic Engineering
    JO  - Journal of Electrical and Electronic Engineering
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    EP  - 12
    PB  - Science Publishing Group
    SN  - 2329-1605
    UR  - https://doi.org/10.11648/j.jeee.20170501.12
    AB  - In this study, low-energy microwave annealing is used to fabricate ultra-shallow junctions for less than 20 nm IC node applications in a potential material: Germanium (Ge). Germanium is a new promising material and might replace silicon in the future. A novel microwave annealing technique with two steps for the solid phase epitaxial recrystallization (SPER) and phosphorus dopants activation was applied to Germanium. The purpose of the first step, microwave annealing of 1.2 kW for 75 s, is to re-grow the amorphous layer and repair the destroyed crystal lattices caused by ion implantation. In the second-step of annealing, low-energy microwave, 0.9 kW (≈350°C) for 300 s, is used to activate the phosphorus dopants effectively without diffusion and de-activation. The target dopant activation concentration level will achieve 1020 cm-3. The sheet resistance will decrease to 78 ohm/sq. The low resistance after activating is reflected to the performance of the n-MOS device fabricated by the Ge substrate. The S. S. factor is 900 mV/dec, and the Ion/off ratio rise to 2.6×101. This has demonstrated that the two-step MWA has excellent control, significantly regarding leakage current.
    VL  - 5
    IS  - 1
    ER  - 

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Author Information
  • Department of Electrical Engineering, National Cheng Kung University, Tainan, Taiwan

  • Department of Electrical Engineering, National Cheng Kung University, Tainan, Taiwan

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