Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel

Andrei Vladimirovich Afineevskii; Tatiana Yurievna Osadchaia; Dmitrii Alekseevich Prozorov; Mikhail Viktorovich Lukin; Yaroslav Pavlovich Suhachev; Marina Dmitrievna Chelysheva; Vladislav Olegovich Gundorov

doi:doi:10.11648/j.ogce.20170506.15

Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel

Andrei Vladimirovich Afineevskii, Tatiana Yurievna Osadchaia, Dmitrii Alekseevich Prozorov, Mikhail Viktorovich Lukin, Yaroslav Pavlovich Suhachev, Marina Dmitrievna Chelysheva, Vladislav Olegovich Gundorov

Published in International Journal of Oil, Gas and Coal Engineering (Volume 5, Issue 6)

Received: 17 February 2017 Accepted: 10 March 2017 Published: 28 November 2017

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Abstract

4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.

Published in	International Journal of Oil, Gas and Coal Engineering (Volume 5, Issue 6)
DOI	10.11648/j.ogce.20170506.15
Page(s)	153-157
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Liquid-Phase Hydrogenation, 4-Nitrotoluene, Maleic Acid Diethyl Ester, Skeletal Nickel

References

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APA Style

Andrei Vladimirovich Afineevskii, Tatiana Yurievna Osadchaia, Dmitrii Alekseevich Prozorov, Mikhail Viktorovich Lukin, Yaroslav Pavlovich Suhachev, et al. (2017). Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. International Journal of Oil, Gas and Coal Engineering, 5(6), 153-157. https://doi.org/10.11648/j.ogce.20170506.15

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ACS Style

Andrei Vladimirovich Afineevskii; Tatiana Yurievna Osadchaia; Dmitrii Alekseevich Prozorov; Mikhail Viktorovich Lukin; Yaroslav Pavlovich Suhachev, et al. Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. Int. J. Oil Gas Coal Eng. 2017, 5(6), 153-157. doi: 10.11648/j.ogce.20170506.15

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AMA Style

Andrei Vladimirovich Afineevskii, Tatiana Yurievna Osadchaia, Dmitrii Alekseevich Prozorov, Mikhail Viktorovich Lukin, Yaroslav Pavlovich Suhachev, et al. Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. Int J Oil Gas Coal Eng. 2017;5(6):153-157. doi: 10.11648/j.ogce.20170506.15

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@article{10.11648/j.ogce.20170506.15,
  author = {Andrei Vladimirovich Afineevskii and Tatiana Yurievna Osadchaia and Dmitrii Alekseevich Prozorov and Mikhail Viktorovich Lukin and Yaroslav Pavlovich Suhachev and Marina Dmitrievna Chelysheva and Vladislav Olegovich Gundorov},
  title = {Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {5},
  number = {6},
  pages = {153-157},
  doi = {10.11648/j.ogce.20170506.15},
  url = {https://doi.org/10.11648/j.ogce.20170506.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20170506.15},
  abstract = {4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.},
 year = {2017}
}

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TY  - JOUR
T1  - Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel
AU  - Andrei Vladimirovich Afineevskii
AU  - Tatiana Yurievna Osadchaia
AU  - Dmitrii Alekseevich Prozorov
AU  - Mikhail Viktorovich Lukin
AU  - Yaroslav Pavlovich Suhachev
AU  - Marina Dmitrievna Chelysheva
AU  - Vladislav Olegovich Gundorov
Y1  - 2017/11/28
PY  - 2017
N1  - https://doi.org/10.11648/j.ogce.20170506.15
DO  - 10.11648/j.ogce.20170506.15
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 153
EP  - 157
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20170506.15
AB  - 4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.
VL  - 5
IS  - 6
ER  -

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Author Information

Andrei Vladimirovich Afineevskii

Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia
Tatiana Yurievna Osadchaia

Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia
Dmitrii Alekseevich Prozorov

Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia
Mikhail Viktorovich Lukin

Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia
Yaroslav Pavlovich Suhachev

Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia
Marina Dmitrievna Chelysheva

Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia
Vladislav Olegovich Gundorov

Department of Physical and Colloidal Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo Region, Ivanovo, Russia

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APA Style

Andrei Vladimirovich Afineevskii, Tatiana Yurievna Osadchaia, Dmitrii Alekseevich Prozorov, Mikhail Viktorovich Lukin, Yaroslav Pavlovich Suhachev, et al. (2017). Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. International Journal of Oil, Gas and Coal Engineering, 5(6), 153-157. https://doi.org/10.11648/j.ogce.20170506.15

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ACS Style

Andrei Vladimirovich Afineevskii; Tatiana Yurievna Osadchaia; Dmitrii Alekseevich Prozorov; Mikhail Viktorovich Lukin; Yaroslav Pavlovich Suhachev, et al. Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. Int. J. Oil Gas Coal Eng. 2017, 5(6), 153-157. doi: 10.11648/j.ogce.20170506.15

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AMA Style

Andrei Vladimirovich Afineevskii, Tatiana Yurievna Osadchaia, Dmitrii Alekseevich Prozorov, Mikhail Viktorovich Lukin, Yaroslav Pavlovich Suhachev, et al. Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel. Int J Oil Gas Coal Eng. 2017;5(6):153-157. doi: 10.11648/j.ogce.20170506.15

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@article{10.11648/j.ogce.20170506.15,
  author = {Andrei Vladimirovich Afineevskii and Tatiana Yurievna Osadchaia and Dmitrii Alekseevich Prozorov and Mikhail Viktorovich Lukin and Yaroslav Pavlovich Suhachev and Marina Dmitrievna Chelysheva and Vladislav Olegovich Gundorov},
  title = {Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {5},
  number = {6},
  pages = {153-157},
  doi = {10.11648/j.ogce.20170506.15},
  url = {https://doi.org/10.11648/j.ogce.20170506.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20170506.15},
  abstract = {4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.},
 year = {2017}
}

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TY  - JOUR
T1  - Liquid Phase Hydrogenation of Maleic Acid Diethyl Ester and Its Mixture with 4-Nitrotoluene over Modified Skeletal Nickel
AU  - Andrei Vladimirovich Afineevskii
AU  - Tatiana Yurievna Osadchaia
AU  - Dmitrii Alekseevich Prozorov
AU  - Mikhail Viktorovich Lukin
AU  - Yaroslav Pavlovich Suhachev
AU  - Marina Dmitrievna Chelysheva
AU  - Vladislav Olegovich Gundorov
Y1  - 2017/11/28
PY  - 2017
N1  - https://doi.org/10.11648/j.ogce.20170506.15
DO  - 10.11648/j.ogce.20170506.15
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 153
EP  - 157
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20170506.15
AB  - 4-aminotoluene is known as a good octane additive, the mixture of maleic acid diethyl ester and Succinate acid diethyl ester has good lubricating characteristics. The process of hydrogenation of maleic acid diethyl ester at atmospheric pressure in aqueous solution of 2-propanol over skeletal nickel and modified skeletal one was investigated. It is established that the nickel surface modification by sulfur does not lead to the increase of the catalyst activity in the hydrogenation of maleic acid diethyl ester as opposed to 4-nitrotoluene. The principal possibility of selective hydrogenation of mixture of maleic acid diethyl ester with 4-nitrotoluene was demonstrated.
VL  - 5
IS  - 6
ER  -

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