Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane

Chioma Deborah Mbakaogu; Ngozi Claribelle Nwogu; Nkemakolam Chinedu Izuwa; Stanley Toochukwu Ekwueme

doi:doi:10.11648/j.ogce.20200806.15

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Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane

Chioma Deborah Mbakaogu, Ngozi Claribelle Nwogu, Nkemakolam Chinedu Izuwa, Stanley Toochukwu Ekwueme

Published in International Journal of Oil, Gas and Coal Engineering (Volume 8, Issue 6)

Received: 21 September 2020 Accepted: 5 October 2020 Published: 27 November 2020

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Abstract

The demand for membranes have increased enormously in the last decades due to increased applicability in many industrial activities. In the oil and gas industry, filtration membranes gain popularity over other types of membranes due to their usage in separation of oil-water emulsion using microfiltration and/or ultrafiltration techniques. Researchers have geared interest in the development of better performance membranes aimed at improving the efficiency of separation and antifouling properties. Developments in nanotechnology has made available nanoparticles which are used to further enhance the properties and performance of membranes, adding credence to membrane usage in emulsion separation. In this work, Polystyrene membrane of size 0.1µm is enhanced by coating with Aluminium oxide nanoparticle for improve fouling resistance properties and separation efficiency. Experiments were conducted in separation of oil-water emulsion using the prepared composite membrane system. Results show that the membrane system yields 97.86% and 97.54% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 2.433 ml/cm²-min and 1.944 ml/cm²-min for 80% stroke and 60% stroke pressure applications respectively. The results reveal that increase in pressure has less effect in the membrane efficiency. The application of aluminum oxide coating increased the efficiency of the membrane and reduced its fouling characteristics.

Published in	International Journal of Oil, Gas and Coal Engineering (Volume 8, Issue 6)
DOI	10.11648/j.ogce.20200806.15
Page(s)	151-156
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Aluminium Oxide, Emulsion, Nanoparticles, Membranes, Polystyrene

References

[1]	Abdel-Raouf M. E. (2012). Crude Oil Emulsions – Composition Stability and Characterization, InTech Janeza, Croatia.
[2]	Matsuyama Hideto and Yoshioka Tomohisa (2019). Development of ultrathin durable membrane for efficient oil and water separation. Journal of Material Chemistry.
[3]	Zhu Yuzhang, Wang Dong, Jiang Lei, and Jin Jian. (2014). Recent progress in developing advanced membranes for emulsified oil/water separation. NPG Asia Materials. Nature publishing group. Vol 6.
[4]	Mohammadian, E.; Taju Ariffin, T. S.; Azdarpour, A.; Hamidi, H.; Yusof, S.; Sabet, M.; Yahya, E. (2018). Demulsification of Light Malaysian Crude Oil Emulsions Using an Electric Field Method. Ind. Eng. Chem. Res., 57, 13247–13256.
[5]	Roshan, N.; Ghader, S.; Rahimpour, M. R. (2018). Application of the response surface methodo logy for modeling demulsification of crude oil emulsion using a demulsifier. J. Dispers. Sci. Technol, 39, 700–710.
[6]	Yu Qianqian, Wenbo Zhang, Xinyue Zhao, Guoliang Cao, Feng Liu, Xin Di, Haiyue Yang, Yazhou Wang and Chengyu Wang (2018). A Simple, Green Method to Fabricate Composite Membranes for Effective Oil-in-Water Emulsion Separation. Polymers.
[7]	Tiron, L. G., Pintilie, S. C, Vlad, M., Birsan, I. G., and Baltă, S. (2017). Characterization of Polysulfone Membranes Prepared with Thermally Induced Phase Separation Technique. International Conference on Innovative Research, IOP Conf. Series: Materials Science and Engineering 209.
[8]	Saki Seda & Uzal Nigmet (2018). Preparation and characterization of PSF/PEI/CaCO3 nanocomposite membranes for oil/water separation. Environmental Science and Pollution Research. Springer-Verlag GmbH Germany.
[9]	Wang Guowei, Yu Bin, Chen Shiguo & Uyama Hiroshi (2017). Template-free synthesis of polystyrene monoliths for the removal of oil-in-water emulsion. Scientific reports \|7: 6534\| doi: 10.1038/s41598-017-06572-7.
[10]	Shehzad, F.; Hussein, I. A.; Kamal, M. S.; Ahmad, W.; Sultan, A. S.; Nasser, M. S. (2018). Polymeric surfactants and emerging alternatives used in the demulsification of produced water: A review. Polym. Rev., 58, 63–101.
[11]	Borisov Ilya, Ovcharova Anna, Bakhtin Danila, Bazhenov Stepan, Volkov Alexey, Ibragimov Rustem, Gallyamov Rustem, Bondarenko Galina, Mozhchil Rais, Bildyukevich Alexandr and Volkov Vladimir (2017). Development of Polysulfone Hollow Fiber Porous Supports for High Flux Composite Membranes: Air Plasma and Piranha Etching.
[12]	Oh S, Ki S, Ryu S, Shin MC, Lee J, Lee C, Nam Y.(2019). Performance Analysis of Gravity-Driven Oil-Water Separation Using Membranes with Special Wettability. ACS Publications, USA.
[13]	Saad, M. A. Kamil, Mohammed Abdurahman, N. H. Yunus, R. M and Awad, O. I. (2019). An Overview of Recent Advances in State-of-the-Art Techniques in the Demulsification of Crude Oil Emulsions. Processes 2019, 7, 470.
[14]	Yang Y. N., Zhang, H. X., Wang, P., Zheng, Q. Z. & Li, J., (2007) Journal of Membrane Science. 288, 231.
[15]	Li, X. Y. Hu, D. Huang, K. Yang, C. F. (2014). J. Mater. Chem. A, 2, 11830.
[16]	Liu Zhi, Qin Detao, Zhao Jianghui, Feng Quan, Li Zhengtao, Bai Hongwei, and Sun Darren D. (2019). Efficient Oil/Water Separation Membrane Derived from Super-Flexible and Superhydrophilic Core–Shell Organic/Inorganic Nanofibrous Architectures. Polymers (Basel) vol. 11 (6).
[17]	Sterlitech Corporation (2019). Hydrophilic Polyester (PETE) Membrane Filters. https://www.sterlitech.com/.

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APA Style

Chioma Deborah Mbakaogu, Ngozi Claribelle Nwogu, Nkemakolam Chinedu Izuwa, Stanley Toochukwu Ekwueme. (2020). Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane. International Journal of Oil, Gas and Coal Engineering, 8(6), 151-156. https://doi.org/10.11648/j.ogce.20200806.15

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ACS Style

Chioma Deborah Mbakaogu; Ngozi Claribelle Nwogu; Nkemakolam Chinedu Izuwa; Stanley Toochukwu Ekwueme. Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane. Int. J. Oil Gas Coal Eng. 2020, 8(6), 151-156. doi: 10.11648/j.ogce.20200806.15

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AMA Style

Chioma Deborah Mbakaogu, Ngozi Claribelle Nwogu, Nkemakolam Chinedu Izuwa, Stanley Toochukwu Ekwueme. Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane. Int J Oil Gas Coal Eng. 2020;8(6):151-156. doi: 10.11648/j.ogce.20200806.15

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@article{10.11648/j.ogce.20200806.15,
  author = {Chioma Deborah Mbakaogu and Ngozi Claribelle Nwogu and Nkemakolam Chinedu Izuwa and Stanley Toochukwu Ekwueme},
  title = {Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {8},
  number = {6},
  pages = {151-156},
  doi = {10.11648/j.ogce.20200806.15},
  url = {https://doi.org/10.11648/j.ogce.20200806.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20200806.15},
  abstract = {The demand for membranes have increased enormously in the last decades due to increased applicability in many industrial activities. In the oil and gas industry, filtration membranes gain popularity over other types of membranes due to their usage in separation of oil-water emulsion using microfiltration and/or ultrafiltration techniques. Researchers have geared interest in the development of better performance membranes aimed at improving the efficiency of separation and antifouling properties. Developments in nanotechnology has made available nanoparticles which are used to further enhance the properties and performance of membranes, adding credence to membrane usage in emulsion separation. In this work, Polystyrene membrane of size 0.1µm is enhanced by coating with Aluminium oxide nanoparticle for improve fouling resistance properties and separation efficiency. Experiments were conducted in separation of oil-water emulsion using the prepared composite membrane system. Results show that the membrane system yields 97.86% and 97.54% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 2.433 ml/cm2-min and 1.944 ml/cm2-min for 80% stroke and 60% stroke pressure applications respectively. The results reveal that increase in pressure has less effect in the membrane efficiency. The application of aluminum oxide coating increased the efficiency of the membrane and reduced its fouling characteristics.},
 year = {2020}
}

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TY  - JOUR
T1  - Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane
AU  - Chioma Deborah Mbakaogu
AU  - Ngozi Claribelle Nwogu
AU  - Nkemakolam Chinedu Izuwa
AU  - Stanley Toochukwu Ekwueme
Y1  - 2020/11/27
PY  - 2020
N1  - https://doi.org/10.11648/j.ogce.20200806.15
DO  - 10.11648/j.ogce.20200806.15
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 151
EP  - 156
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20200806.15
AB  - The demand for membranes have increased enormously in the last decades due to increased applicability in many industrial activities. In the oil and gas industry, filtration membranes gain popularity over other types of membranes due to their usage in separation of oil-water emulsion using microfiltration and/or ultrafiltration techniques. Researchers have geared interest in the development of better performance membranes aimed at improving the efficiency of separation and antifouling properties. Developments in nanotechnology has made available nanoparticles which are used to further enhance the properties and performance of membranes, adding credence to membrane usage in emulsion separation. In this work, Polystyrene membrane of size 0.1µm is enhanced by coating with Aluminium oxide nanoparticle for improve fouling resistance properties and separation efficiency. Experiments were conducted in separation of oil-water emulsion using the prepared composite membrane system. Results show that the membrane system yields 97.86% and 97.54% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 2.433 ml/cm2-min and 1.944 ml/cm2-min for 80% stroke and 60% stroke pressure applications respectively. The results reveal that increase in pressure has less effect in the membrane efficiency. The application of aluminum oxide coating increased the efficiency of the membrane and reduced its fouling characteristics.
VL  - 8
IS  - 6
ER  -

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Author Information

Chioma Deborah Mbakaogu

Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria
Ngozi Claribelle Nwogu

Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria
Nkemakolam Chinedu Izuwa

Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria
Stanley Toochukwu Ekwueme

Department of Petroleum Engineering, Federal University of Technology, Owerri, Nigeria

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APA Style

Chioma Deborah Mbakaogu, Ngozi Claribelle Nwogu, Nkemakolam Chinedu Izuwa, Stanley Toochukwu Ekwueme. (2020). Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane. International Journal of Oil, Gas and Coal Engineering, 8(6), 151-156. https://doi.org/10.11648/j.ogce.20200806.15

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ACS Style

Chioma Deborah Mbakaogu; Ngozi Claribelle Nwogu; Nkemakolam Chinedu Izuwa; Stanley Toochukwu Ekwueme. Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane. Int. J. Oil Gas Coal Eng. 2020, 8(6), 151-156. doi: 10.11648/j.ogce.20200806.15

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AMA Style

Chioma Deborah Mbakaogu, Ngozi Claribelle Nwogu, Nkemakolam Chinedu Izuwa, Stanley Toochukwu Ekwueme. Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane. Int J Oil Gas Coal Eng. 2020;8(6):151-156. doi: 10.11648/j.ogce.20200806.15

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@article{10.11648/j.ogce.20200806.15,
  author = {Chioma Deborah Mbakaogu and Ngozi Claribelle Nwogu and Nkemakolam Chinedu Izuwa and Stanley Toochukwu Ekwueme},
  title = {Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane},
  journal = {International Journal of Oil, Gas and Coal Engineering},
  volume = {8},
  number = {6},
  pages = {151-156},
  doi = {10.11648/j.ogce.20200806.15},
  url = {https://doi.org/10.11648/j.ogce.20200806.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ogce.20200806.15},
  abstract = {The demand for membranes have increased enormously in the last decades due to increased applicability in many industrial activities. In the oil and gas industry, filtration membranes gain popularity over other types of membranes due to their usage in separation of oil-water emulsion using microfiltration and/or ultrafiltration techniques. Researchers have geared interest in the development of better performance membranes aimed at improving the efficiency of separation and antifouling properties. Developments in nanotechnology has made available nanoparticles which are used to further enhance the properties and performance of membranes, adding credence to membrane usage in emulsion separation. In this work, Polystyrene membrane of size 0.1µm is enhanced by coating with Aluminium oxide nanoparticle for improve fouling resistance properties and separation efficiency. Experiments were conducted in separation of oil-water emulsion using the prepared composite membrane system. Results show that the membrane system yields 97.86% and 97.54% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 2.433 ml/cm2-min and 1.944 ml/cm2-min for 80% stroke and 60% stroke pressure applications respectively. The results reveal that increase in pressure has less effect in the membrane efficiency. The application of aluminum oxide coating increased the efficiency of the membrane and reduced its fouling characteristics.},
 year = {2020}
}

Copy | Download

TY  - JOUR
T1  - Oil-Water Emulsion Separation Using Nanoparticle-Coated Polystyrene Membrane
AU  - Chioma Deborah Mbakaogu
AU  - Ngozi Claribelle Nwogu
AU  - Nkemakolam Chinedu Izuwa
AU  - Stanley Toochukwu Ekwueme
Y1  - 2020/11/27
PY  - 2020
N1  - https://doi.org/10.11648/j.ogce.20200806.15
DO  - 10.11648/j.ogce.20200806.15
T2  - International Journal of Oil, Gas and Coal Engineering
JF  - International Journal of Oil, Gas and Coal Engineering
JO  - International Journal of Oil, Gas and Coal Engineering
SP  - 151
EP  - 156
PB  - Science Publishing Group
SN  - 2376-7677
UR  - https://doi.org/10.11648/j.ogce.20200806.15
AB  - The demand for membranes have increased enormously in the last decades due to increased applicability in many industrial activities. In the oil and gas industry, filtration membranes gain popularity over other types of membranes due to their usage in separation of oil-water emulsion using microfiltration and/or ultrafiltration techniques. Researchers have geared interest in the development of better performance membranes aimed at improving the efficiency of separation and antifouling properties. Developments in nanotechnology has made available nanoparticles which are used to further enhance the properties and performance of membranes, adding credence to membrane usage in emulsion separation. In this work, Polystyrene membrane of size 0.1µm is enhanced by coating with Aluminium oxide nanoparticle for improve fouling resistance properties and separation efficiency. Experiments were conducted in separation of oil-water emulsion using the prepared composite membrane system. Results show that the membrane system yields 97.86% and 97.54% efficiency in terms of oil rejection for a pressure application of 60% stroke and 80% stroke respectively while the permeation fluxes are 2.433 ml/cm2-min and 1.944 ml/cm2-min for 80% stroke and 60% stroke pressure applications respectively. The results reveal that increase in pressure has less effect in the membrane efficiency. The application of aluminum oxide coating increased the efficiency of the membrane and reduced its fouling characteristics.
VL  - 8
IS  - 6
ER  -

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