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A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization

Received: 27 September 2015    Accepted: 14 October 2015    Published: 15 October 2015
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Abstract

A novel non-metallocene titanium complex was synthesized, and used as the catalyst for ethylene polymerization. It results in an acceptable activity, affording the polyethylene with ultra high molecular weights, and relative broad molecular weight distributions. Moreover, the molecular weight almost doesn’t change with the change of Al/Ti ratio.

Published in American Journal of Polymer Science and Technology (Volume 1, Issue 2)
DOI 10.11648/j.ajpst.20150102.11
Page(s) 15-17
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Non-metallocene, Titanium, Ethylene Polymerization, Molecular Weight

References
[1] G. J. P. Britovsek, V. C. Gibson, D. F. Wass. Angew. Chem., Int. Ed., 1999, 38, 429.
[2] V. C. Gibson, S. K. Spitzmesser, Chem. Rev., 2003, 103, 283.
[3] M. Hong, B. Li, Y. Li. Chin. J. Polym. Sci., 2011, 29, 692,
[4] S. Yuan, S. Bai, D. Liu, W. H. Sun. Organometallics, 2010, 29, 2132.
[5] S. Yuan, X. Wei, H. Tong, L. Zhang, D. Liu, W. H. Sun. Organometallics, 2010, 29, 2085.
[6] S. Liu, W. Zuo, S. Zhang, P. Hao, D. Wang, W. H. Sun. J. Polym. Sci. A: Polym. Chem., 2008, 46, 3411.
[7] V. C. Gibson, B. S. Kimberley, A. J. P. White, D. J. Williams, P. Howard. Chem. Commun., 1998, 313.
[8] M. R. Mason, B. N. Fneich, K. Kirschbaum. Inorg. Chem., 2003, 42, 6592.
[9] J. D. Scollard, D. H. McConville. J. Am. Chem. Soc., 1996, 118, 10008.
[10] A. Shafir, J. Arnold. Organometallics, 2003, 22, 567.
[11] J. Jin, S. Tsubaki, T. Uozumi, T. Sano, K. Soga. Macromol. Rapid Commun., 1998, 19, 597.
[12] A. Linden, C. J. Schaverien, N. Meijboom, N. C. Ganter, A. G. Orpen. J. Am. Chem. Soc., 1995, 117, 3008.
[13] S. Fokken, T. P. Spaniol, J. Okuda. Organometallics, 1997, 16, 4240.
[14] J. Canich, H. W. Turner. 1992 PCT Int. Appl. 92/12162.
[15] K. Vijayakrishna, G. Sundararajan. Polymer, 2006, 47, 8289.
[16] T. Xu, W. Gao, Y. Mu, L. Ye. Polyhedron, 2007, 26, 3357.
[17] J. C. W. Chien, A. Razavi. J. Polym. Sci.: Part A: Polym. Chem., 1998, 26, 2369.
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  • APA Style

    Wei Wang, Changcheng Liu. (2015). A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization. American Journal of Polymer Science and Technology, 1(2), 15-17. https://doi.org/10.11648/j.ajpst.20150102.11

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    ACS Style

    Wei Wang; Changcheng Liu. A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization. Am. J. Polym. Sci. Technol. 2015, 1(2), 15-17. doi: 10.11648/j.ajpst.20150102.11

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    AMA Style

    Wei Wang, Changcheng Liu. A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization. Am J Polym Sci Technol. 2015;1(2):15-17. doi: 10.11648/j.ajpst.20150102.11

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  • @article{10.11648/j.ajpst.20150102.11,
      author = {Wei Wang and Changcheng Liu},
      title = {A Novel Ti-based Non-metallocene Catalyst System for Ethylene Polymerization},
      journal = {American Journal of Polymer Science and Technology},
      volume = {1},
      number = {2},
      pages = {15-17},
      doi = {10.11648/j.ajpst.20150102.11},
      url = {https://doi.org/10.11648/j.ajpst.20150102.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpst.20150102.11},
      abstract = {A novel non-metallocene titanium complex was synthesized, and used as the catalyst for ethylene polymerization. It results in an acceptable activity, affording the polyethylene with ultra high molecular weights, and relative broad molecular weight distributions. Moreover, the molecular weight almost doesn’t change with the change of Al/Ti ratio.},
     year = {2015}
    }
    

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    AB  - A novel non-metallocene titanium complex was synthesized, and used as the catalyst for ethylene polymerization. It results in an acceptable activity, affording the polyethylene with ultra high molecular weights, and relative broad molecular weight distributions. Moreover, the molecular weight almost doesn’t change with the change of Al/Ti ratio.
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Author Information
  • Institute of Materials Science, Beijing Research Institute of Chemical Industry (BRICI), Sinopec, Chao Yang District, Beijing

  • Institute of Materials Science, Beijing Research Institute of Chemical Industry (BRICI), Sinopec, Chao Yang District, Beijing

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