American Journal of Heterocyclic Chemistry

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Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst

Received: 10 April 2015    Accepted: 22 April 2015    Published: 28 April 2015
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Abstract

Different Pyrazoline derivatives were synthesized by cyclization of substituted chalcone derivatives in presence of hydrazine hydrate. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of Silica-supported Preyssler Nanoparticles, H14[NaP5W30O110]/SiO2, Preyssler H14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, H7[PMo8V4O40], H6[PMo9V3O40], H5[PMo10V2O40], H4[PMo11VO40], H3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable. The structures of compounds obtained were determined by IR and 1H NMR spectra.

DOI 10.11648/j.ajhc.20150101.12
Published in American Journal of Heterocyclic Chemistry (Volume 1, Issue 1, April 2015)
Page(s) 6-12
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Pyrazoline, Nanoparticles, Preyssler, Heteropolyacids, Catalyst, Synthesis

References
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Author Information
  • Department of Chemistry, Islamic Azad University, Mashhad, Iran; Department of Chemistry, Agricultural Researches and Services Center, Mashhad, Iran

  • Department of Chemistry, Faculty of Science, Urmia University, Urmia, Iran

  • Education Ministry, Education Organization of Razavi Khorasan, Mashhad, Iran

  • Department of Chemistry, Islamic Azad University, Mashhad, Iran

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    Ali Gharib, Nader Noroozi Pesyan, Leila Vojdani Fard, Mina Roshani. (2015). Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst. American Journal of Heterocyclic Chemistry, 1(1), 6-12. https://doi.org/10.11648/j.ajhc.20150101.12

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    ACS Style

    Ali Gharib; Nader Noroozi Pesyan; Leila Vojdani Fard; Mina Roshani. Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst. Am. J. Heterocycl. Chem. 2015, 1(1), 6-12. doi: 10.11648/j.ajhc.20150101.12

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    AMA Style

    Ali Gharib, Nader Noroozi Pesyan, Leila Vojdani Fard, Mina Roshani. Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst. Am J Heterocycl Chem. 2015;1(1):6-12. doi: 10.11648/j.ajhc.20150101.12

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  • @article{10.11648/j.ajhc.20150101.12,
      author = {Ali Gharib and Nader Noroozi Pesyan and Leila Vojdani Fard and Mina Roshani},
      title = {Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst},
      journal = {American Journal of Heterocyclic Chemistry},
      volume = {1},
      number = {1},
      pages = {6-12},
      doi = {10.11648/j.ajhc.20150101.12},
      url = {https://doi.org/10.11648/j.ajhc.20150101.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajhc.20150101.12},
      abstract = {Different Pyrazoline derivatives were synthesized by cyclization of substituted chalcone derivatives in presence of hydrazine hydrate. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of Silica-supported Preyssler Nanoparticles, H14[NaP5W30O110]/SiO2, Preyssler H14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, H7[PMo8V4O40], H6[PMo9V3O40], H5[PMo10V2O40], H4[PMo11VO40], H3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable. The structures of compounds obtained were determined by IR and 1H NMR spectra.},
     year = {2015}
    }
    

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  • TY  - JOUR
    T1  - Catalytical Synthesis of Pyrazolines Using Nanoparticles of Preyssler Heteropolyacid Supported on Nano-SiO2, H14[NaP5W30O110]/SiO2: A Green and Reusable Catalyst
    AU  - Ali Gharib
    AU  - Nader Noroozi Pesyan
    AU  - Leila Vojdani Fard
    AU  - Mina Roshani
    Y1  - 2015/04/28
    PY  - 2015
    N1  - https://doi.org/10.11648/j.ajhc.20150101.12
    DO  - 10.11648/j.ajhc.20150101.12
    T2  - American Journal of Heterocyclic Chemistry
    JF  - American Journal of Heterocyclic Chemistry
    JO  - American Journal of Heterocyclic Chemistry
    SP  - 6
    EP  - 12
    PB  - Science Publishing Group
    SN  - 2575-5722
    UR  - https://doi.org/10.11648/j.ajhc.20150101.12
    AB  - Different Pyrazoline derivatives were synthesized by cyclization of substituted chalcone derivatives in presence of hydrazine hydrate. A series of novel 1,3,5-triaryl pyrazoline derivatives has been synthesized by the reaction of chalcone and phenylhydrazine in the presence of Silica-supported Preyssler Nanoparticles, H14[NaP5W30O110]/SiO2, Preyssler H14[NaP5W30O110] and Keggin heteropolyacids, H3PW12O40, H7[PMo8V4O40], H6[PMo9V3O40], H5[PMo10V2O40], H4[PMo11VO40], H3[PMo12O40] as catalyst under aqueous conditions is described. The best conditions were observed using Preyssler and Silica-supported Preyssler Nanoparticles as catalysts. The catalyst is recyclable and reusable. The structures of compounds obtained were determined by IR and 1H NMR spectra.
    VL  - 1
    IS  - 1
    ER  - 

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