American Journal of Heterocyclic Chemistry

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Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry

Received: 18 October 2017    Accepted: 23 November 2017    Published: 29 January 2018
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Abstract

Synthetic methods have been developed and Ru (IV) complex compounds with five types of donor ligands have been prepared: phenanthroline, nicotinic acid amide, imidazole, benzimidazole and their derivatives, and phthalocyanine. New method for the synthesis of rhenium and ruthenium phthalocyanines is proposed, which is distinguished by its availability and high yields. It is established that because of synthesis only one form of ruthenium phthalocyanine is formed, which can be attributed to the PcRuO structure based on physical and chemical studies.

DOI 10.11648/j.ajhc.20180401.12
Published in American Journal of Heterocyclic Chemistry (Volume 4, Issue 1, March 2018)
Page(s) 22-25
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Complex Compounds, Ruthenium, Nicotinic Acid Amide, Donor Ligands, Palladium

References
[1] Raevskaya MV: Physicochemistry of ruthenium and its alloys / MV Raevskaya // Chemistry of ruthenium, rhodium, palladium, osmium, iridium, platinum, per. With the English. M.: 1979.-P. 138-140.
[2] Brockhaus F. A. Encyclopedic Dictionary Brockhaus and I. A. Efron / F. A. Brockhaus, I. A. Efron. - S.-Pb.: Brockhaus - Efron, 1890-1907.-347 p.
[3] Prokhorov A. M. Physical encyclopedia in 5 volumes / А. М. Prokhorov, Moscow: Soviet Encyclopedia. Editor-in-chief A. M. Prokhorov. - Volume 3, p. 317-319.
[4] Sokolov I. V. Popular library of chemical elements / I. V. Petryanov-Sokolov // Moscow: Nauka Publishers, 1963. pp. 83-86.
[5] M. Cavazzini, S. Quici, C. Scalera, F. Puntoriero, G. La Ganga, S. Campagna. Synthesis, characterization, absorption spectra, and luminescence properties of multinuclear species made of Ru (II) and Ir (III) chromophores. // Inorg. Chem.-2009.-V. 48.-P. 8578-8592.
[6] R. Lalrempuia, M. R. Kollipara. Rectivity studies of η6-arene ruthenium (II) dimers with polypyridyl ligands: isolation of mono, binuclear p- cymene ruthenium (II) complexes and bisterpyridine ruthenium (II) complexes. //Polyhedron-2003.-V. 22.-P. 3155-316.
[7] C. Mikel, P. G. Potvin. Synthesis and enhanced photosensitization ability of a 4-carboxy-2, 2′:6′, 2″- terpyridine complex of ruthenium (II)// Polyhedron-2002.-V. 21.-P. 49-54.
[8] J. Mola, E. Mas-Marza, X. Sala, I. Romero, M. Rodriguez, C. Vinas, T. Parella, A. Llobet. Ru-Hbpp-based water-oxidation catalysts anchored on conducting solid supports. // Angew. Chem. Int. Ed.-2008.-V. 47.-P. 5830-5832.
[9] M. Agaguseynova, N. E. Jabbarova Coordination compounds of transition metals in catalysis.// Chem. Soc. Commun. Baku-2006 -p. 129-135.
[10] M. Agaguseynova, N. E. Jabbarova Complexes of transition metals with molecular oxygen.// Chem. Soc. Commun. Baku-2012 -p. 96-111.
Author Information
  • Scientific-Research Laboratory ?New Chemical Materials and Technologies?, "Azerbaijan State University of Oil and Industry", Baku, Republic of Azerbaijan

  • Scientific-Research Laboratory ?New Chemical Materials and Technologies?, "Azerbaijan State University of Oil and Industry", Baku, Republic of Azerbaijan

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    Mikayilova Mexriban Rahil, Mustafayeva Rena Eldar. (2018). Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry. American Journal of Heterocyclic Chemistry, 4(1), 22-25. https://doi.org/10.11648/j.ajhc.20180401.12

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    ACS Style

    Mikayilova Mexriban Rahil; Mustafayeva Rena Eldar. Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry. Am. J. Heterocycl. Chem. 2018, 4(1), 22-25. doi: 10.11648/j.ajhc.20180401.12

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    AMA Style

    Mikayilova Mexriban Rahil, Mustafayeva Rena Eldar. Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry. Am J Heterocycl Chem. 2018;4(1):22-25. doi: 10.11648/j.ajhc.20180401.12

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  • @article{10.11648/j.ajhc.20180401.12,
      author = {Mikayilova Mexriban Rahil and Mustafayeva Rena Eldar},
      title = {Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry},
      journal = {American Journal of Heterocyclic Chemistry},
      volume = {4},
      number = {1},
      pages = {22-25},
      doi = {10.11648/j.ajhc.20180401.12},
      url = {https://doi.org/10.11648/j.ajhc.20180401.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajhc.20180401.12},
      abstract = {Synthetic methods have been developed and Ru (IV) complex compounds with five types of donor ligands have been prepared: phenanthroline, nicotinic acid amide, imidazole, benzimidazole and their derivatives, and phthalocyanine. New method for the synthesis of rhenium and ruthenium phthalocyanines is proposed, which is distinguished by its availability and high yields. It is established that because of synthesis only one form of ruthenium phthalocyanine is formed, which can be attributed to the PcRuO structure based on physical and chemical studies.},
     year = {2018}
    }
    

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    T1  - Synthesis and Properties of Macrocyclic Complexes Ruthenium Azerbaijan State University of Oil and Industry
    AU  - Mikayilova Mexriban Rahil
    AU  - Mustafayeva Rena Eldar
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    DO  - 10.11648/j.ajhc.20180401.12
    T2  - American Journal of Heterocyclic Chemistry
    JF  - American Journal of Heterocyclic Chemistry
    JO  - American Journal of Heterocyclic Chemistry
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    EP  - 25
    PB  - Science Publishing Group
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    UR  - https://doi.org/10.11648/j.ajhc.20180401.12
    AB  - Synthetic methods have been developed and Ru (IV) complex compounds with five types of donor ligands have been prepared: phenanthroline, nicotinic acid amide, imidazole, benzimidazole and their derivatives, and phthalocyanine. New method for the synthesis of rhenium and ruthenium phthalocyanines is proposed, which is distinguished by its availability and high yields. It is established that because of synthesis only one form of ruthenium phthalocyanine is formed, which can be attributed to the PcRuO structure based on physical and chemical studies.
    VL  - 4
    IS  - 1
    ER  - 

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