American Journal of Heterocyclic Chemistry

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Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage

Received: 13 February 2020    Accepted: 27 February 2020    Published: 10 March 2020
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Abstract

Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH2 groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H3O+ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl2. 2H2O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh3Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh3Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).

DOI 10.11648/j.ajhc.20190504.12
Published in American Journal of Heterocyclic Chemistry (Volume 5, Issue 4, December 2019)
Page(s) 81-85
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Chloride, Infrared, Mössbauer, Sn-Ph Bonds Cleavage, Tin (IV), Urea Deamination

References
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[12] Nardelli M., Pelizzi C. and Pelizzi, G. (1977). Structulal researches on nitrato complexes of organotin: Coordinative interactions Sn–O in nitratotriphenyl (triphenylarsine oxide) tin (IV), Journal of Organometallic Chemistry. 125: 161–172.
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[14] Renamy S. V., Okio K. Y. A., Diop M. B. and Diop L. (2019). Some organotin (IV) nitrate adducts: syntheses, far infrared and mössbauer characterization, International Journal of Advanced Research. 7 (5): 12–22.
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Author Information
  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

  • Mineral and Analyical Chemestry Laboratory, Deparement of Chemesry, Faculy of Science and Technology, Cheikh Anta Diop Universiy, Dakar, Senegal

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    Dame Seye, Mouhamadou Birame Diop, Assane Toure, Tidiane Diop, Cheikh Abdoul Khadir Diop, et al. (2020). Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. American Journal of Heterocyclic Chemistry, 5(4), 81-85. https://doi.org/10.11648/j.ajhc.20190504.12

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    Dame Seye; Mouhamadou Birame Diop; Assane Toure; Tidiane Diop; Cheikh Abdoul Khadir Diop, et al. Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. Am. J. Heterocycl. Chem. 2020, 5(4), 81-85. doi: 10.11648/j.ajhc.20190504.12

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    AMA Style

    Dame Seye, Mouhamadou Birame Diop, Assane Toure, Tidiane Diop, Cheikh Abdoul Khadir Diop, et al. Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage. Am J Heterocycl Chem. 2020;5(4):81-85. doi: 10.11648/j.ajhc.20190504.12

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  • @article{10.11648/j.ajhc.20190504.12,
      author = {Dame Seye and Mouhamadou Birame Diop and Assane Toure and Tidiane Diop and Cheikh Abdoul Khadir Diop and Mamadou Sidibe and Aminata Diasse Sarr and Libasse Diop},
      title = {Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage},
      journal = {American Journal of Heterocyclic Chemistry},
      volume = {5},
      number = {4},
      pages = {81-85},
      doi = {10.11648/j.ajhc.20190504.12},
      url = {https://doi.org/10.11648/j.ajhc.20190504.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ajhc.20190504.12},
      abstract = {Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH2 groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H3O+ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl2. 2H2O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh3Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh3Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).},
     year = {2020}
    }
    

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    T1  - Synthesis, Infrared and Mössbauer Characterization of Some Chloridestannate (IV) Inorganic-organic Hybrid Complexes: Sn-Ph Bonds Cleavage
    AU  - Dame Seye
    AU  - Mouhamadou Birame Diop
    AU  - Assane Toure
    AU  - Tidiane Diop
    AU  - Cheikh Abdoul Khadir Diop
    AU  - Mamadou Sidibe
    AU  - Aminata Diasse Sarr
    AU  - Libasse Diop
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    DO  - 10.11648/j.ajhc.20190504.12
    T2  - American Journal of Heterocyclic Chemistry
    JF  - American Journal of Heterocyclic Chemistry
    JO  - American Journal of Heterocyclic Chemistry
    SP  - 81
    EP  - 85
    PB  - Science Publishing Group
    SN  - 2575-5722
    UR  - https://doi.org/10.11648/j.ajhc.20190504.12
    AB  - Five new compounds are isolated from reactions carried out in solution. All the compounds are characterized by, Infrared and Mössbauer spectroscopies. Spectroscopic studies have shown the presence of different carracterristic bands, notably υ (PO) vibrations coming from triphenylphosphine oxide, with wide absorption due to the NH2 groups coming from urea and the intense doublet which show the presence of phenyl groups. The proposed structures, in the solid state, are discrete though hydrogen bonding interactions may occur. Event in this study is the dearylation evidenced, cleaved Sn-Ph bonds occurring in the presence of triphenylphosphine oxide or urea, during some reaction processes. In the presence of triphenylphosphine oxide, the dearylation is followed by the formation of Sn-Cl new bonds while in the presence of urea, the Sn-Ph bonds cleavage undergo with a deamination of the urea giving rise to the formation of Sn-N and Sn-Cl new bonds whose presence are ascertained by the Mössbauer parameters. The oxidation of tin (II) to tin (IV) as well as the coordination behavior of the oxonium, H3O+ cation is also noted in this work. In the reaction of triphenylphosphine oxide with SnCl2. 2H2O and nitric acid, we have obtained compounds in which tin has oxidized. The reactions between urea and SnPh3Cl are the site of a species exchange which can be explained by a deamination of urea and a dephenylation of SnPh3Cl Studies aimed at understanding the processes of this transformation still unknown leading to the isolation of aminochlorotin (IV) compounds and isolating their single crystals are being carried in our laboratory (LA.CHI.MI.A).
    VL  - 5
    IS  - 4
    ER  - 

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