Non-Conventional Standpoint on Spin Crossovers in the Organometallic Compounds of Iron Group
Journal of Photonic Materials and Technology
Volume 1, Issue 2, September 2015, Pages: 40-45
Received: Jul. 13, 2015; Accepted: Jul. 24, 2015; Published: Jul. 28, 2015
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Authors
V. V. Shelest, Dept. of Dynamical Properties of Complex Systems, Galkin Institute for Physics & Engineering, Donetsk, Ukraine
A. V. Hristov, Dept. of Phase Transitions, Galkin Institute for Physics & Engineering, Donetsk, Ukraine
A. Yu. Prokhorov, Dept. of Phase Transitions, Galkin Institute for Physics & Engineering, Donetsk, Ukraine
D. A. Chervinskii, Dept. of Dynamical Properties of Complex Systems, Galkin Institute for Physics & Engineering, Donetsk, Ukraine
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Abstract
We have considered the spin crossover (SC) complex compounds containing spin-active metal ions of iron group, which can induce the spin transitions (ST) of high spin (HS) – low spin (LS) type under influence of temperature (TIST), pressure (PIST) or light (LIESST) from non-conventional point of view. We have analyzed the physical peculiarities of the studied ST systems observed in numerous papers for X ray, spectral, calorimetric and magnetic measurements. On this basis, we suppose that ST (for example, in bulk of SC compounds with TIST) can be considered as phase transitions (PT) of post-critical type (PCT)
Keywords
Spin Crossover, Phase Transition, Critical Phenomena, Supramolecular Compounds
To cite this article
V. V. Shelest, A. V. Hristov, A. Yu. Prokhorov, D. A. Chervinskii, Non-Conventional Standpoint on Spin Crossovers in the Organometallic Compounds of Iron Group, Journal of Photonic Materials and Technology. Vol. 1, No. 2, 2015, pp. 40-45. doi: 10.11648/j.jmpt.20150102.14
References
[1]
O. Kahn, Molecular magnetism, VCH Publishers, Inc. (1993).
[2]
P. Gütlich, A. Hauser, H. Spiering, Angew. Chem. 33, 2024 (1994).
[3]
P. Gütlich, Y. Garcia, H.A. Goodwin, Chem. Soc. Rev., 29, 419 (2000).
[4]
.P. Gütlich, P. J. van Koningsbruggen, F. Renz, Structure and Bonding 107, 27 (2004); A.B. Gaspar, M. Seredyuk, P. Gütlich, J. Mol. Struc., 924–926, 9 (2009).
[5]
V. Legrand, Présentée pour l’obtention du titre deDocteur de l’Université Henri Poincaré, Nancy-Ien Physique et Chimie de la Matière et des Matériaux. (2005).
[6]
G.G.Levchenko, A.V.Khristov, Molecular magnetism: high spin – low spin phase transitions. “Noulidge” Publishers, Donetsk, Ukraine (2010).
[7]
A.Bousseksou, G.Molnar, L.Salmona and W.Nicolazzi, Chem. Soc. Rev., v. 40, p. 3313 (2011).
[8]
J.Linares, E.Cojovi and Y.Garcia, Sensors, v. 12, p. 4479 (2012).
[9]
P. Gütlich, Eur. J. Inorg. Chem., p. 581 – 891 (2013).
[10]
G.Levchenko, A.Khristov, V.Kuznetsova, V.Shelest. Journal of Physics and Chemistry of Solid, v. 75, № 8, p.966 – 971 (2014)
[11]
K. L.Ronayne, H. Paulsen, A. Höfer, A.C. Dennis, J.A. Wolny, A.I. Chumakov, V. Schünemann, H. Winkler, H. Spiering, A. Bousseksou, P. Gütlich, A.X. Trautwein, J. McGarvey, Phys. Chem. Chem. Phys., 8, 4685, (2006).
[12]
I.B.Bersuker. Electronic structure and properties of coordination compounds, “Khimiya” Publishers, Leningrad (1976); Jan-Teller effect and vibronic interactions in modern chemistry, “Nauka” Publishers, Moscow (1987); Modern aspects of the Jahn-Teller effect theory and applications to molecular problems, Chem. Rev., 101, 1067 (2001).
[13]
S.V.Volkov, V.A.Zasukha, Quantum chemistry of coordination condensed systems, “Naukova dumka” Publishers, Kiev (1985).
[14]
V. Martínez, A.B. Gaspar, M.C. Muñoz, G.V. Bukin, G. Levchenko, J.A. Real, Chem. Eur. J., 15, 10960 (2009).
[15]
V. Gnezdilov, P. Lemmens, P. Sceib, M. Ghosh, Yu. G. Paskevich, H. Paulsen, V. Schünemann, J.A. Wolny, G. Agusti, J.A. Real, Phys. Rev. B, 79, 045122 (2009).
[16]
Sorai M., Ensling J., Gütlich P. // Chem.Phys. – 1976. – V. 18. – P. 199-209.
[17]
M. Sorai, Bull. Chem. Soc. Jpn., 74, 2223 (2001).
[18]
V.V.Shelest, A.V.Christov. Proceedings of International conference “Actual problems of solid state physics” Minsk, Belarus, Abstr., P.243 (2009).
[19]
J.A. Rodríguez-Velamazán, M. Castro, E. Palacios, R. Burriel, J.S. Costa, J.F. Létard, Chem. Phys. Lett., 435, 358 (2007).
[20]
M.M.N. Wolf, R. Groß, C. Schumann, J.A. Wolny, V. Schünemann, A. Døssong, H. Paulsen, J.J. McGarvey, R. Diller, Phys. Chem. Chem. Phys., 10, 4264 (2008).
[21]
Y. Konishi, N. Tokoro, M. Nishino, S. Miyashita, Phys. Rev. Lett. PRL 100, 067206 (2008).
[22]
K. Boukheddaden, M. Nishino, S. Miyashita, Phys. Rev. Lett., PRL 100, 177206 (2008).
[23]
N.F.Stepanov, Quantum mechanics and quantum physics. “Moscow state university Publishers”, Moscow (2001).
[24]
C. Day, J. Selbin, Theoretical inorganic chemistry, New York – Amsterdam – London, «Reinhold Book Corporation» (1962).
[25]
S. Klokishner, J. Linares, F. Varret, J. Phys.: Condens. Matter, 13, 595 (2001).
[26]
Structure and bonding. Volume 2, edited by C.K. Jørgensen, J.B. Nielands, R.S. Nyholm, D. Reinen, R.J.P. Williams, “Springer – Verlag” Berlin – Heidelberg – New York (1967).
[27]
G.A. Razuvaev, B.G. Gribov, G.A. Domracheev, B.A. Solomatin, Metallo-organic compounds in electronics, “Nauka” Publishers, Moscow (1972).
[28]
V.I.Shipilov, V.A.Fedirko, V.V.Zelentsov, V.M.Mokshin. Sov. Solid State Phys., v.21, No 12, P.3553 (1979).
[29]
E. Cartmell, G.W.A. Fowles, Valency and molecular structure, Butterworths (1978).
[30]
G. Dupouy, M. Marchivie, S. Triki, J. Sala-Pala, J.-Y. Salaün, C.J. Gómez-García, P. Guionneau, Inorg. Chem., 47, 8921 (2008).
[31]
John C. Slater, The self-cosistent field for molecules and solids, Москва, «Mc Graw-Hill Book Co.» New York – St. Louis – San Francisco (1974).
[32]
Theory of the inhomogeneous electron gas, edited by S. Lundqvist, N.H. March, “Plenum Press”, New York and London (1983).
[33]
Sov. Solis State Phys. Encyclopedia, “Naukova dumka” Publishers, Kiev, VV.1, 2 (1998).
[34]
Bruce A.D., Cowley R.A., Structure phase transitions, London (1981).
[35]
I.P.Bazarov, Thermodynamics, “Visshaya shkola” Publishers, Moscow (1991).
[36]
V.K.Semenchenko, Selected chapters of theoretical physics, “Prosveschenie” Publishers, Moscow (1966).
[37]
E. Stanley, Introduction to phase transitions and critical phenomena, «Clarendon Press», Oxford (1971).
[38]
A. Bousseksou, N. Negre, M. Goiran, L. Salmon, J.-P. Tuchagues, M.-L. Boillot, K. Boukheddaden, F. Varret. Eur. Phys. J. B, 13, 451 (2004).
[39]
N. Moliner, C. Muñoz, S. Létard, J-F. Létard et al., Inorg. Chem. Acta, 291, 279 (1999).
[40]
Y. Garcia, V. Ksenofontov, G. Levchenko, P. Gütlich, J. Mater Chem., 10, 2274 (2000).
[41]
D. Chernyshov, M. Hostettler, K. Tömroos, H.S. Bürgi, Angew. Chem. Int. End. 42, 3825 (2003).
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