Nanoscience and Nanometrology
Volume 3, Issue 1, June 2017, Pages: 34-39
Received: May 3, 2017;
Accepted: May 25, 2017;
Published: Jun. 30, 2017
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Mohammad Shahjahan, Industrial Physics Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific & Industrial Research (BCSIR), Dhaka, Bangladesh
Md Hasibur Rahman, Fibre & Polymer Reserch Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific & Industrial Research (BCSIR), Dhaka, Bangladesh
Mohammad Sajjad Hossain, Industrial Physics Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific & Industrial Research (BCSIR), Dhaka, Bangladesh
Most Afroza Khatun, Fibre & Polymer Reserch Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific & Industrial Research (BCSIR), Dhaka, Bangladesh
Aminul Islam, Jessore University of Science and Technology, Jessore, Bangladesh
Most Hosney Ara Begum, Industrial Physics Division, BCSIR Laboratories Dhaka, Bangladesh Council of Scientific & Industrial Research (BCSIR), Dhaka, Bangladesh
In recent nanotechnology is the most promising field for the researchers. This paper describes a simple and convenient procedure for the preparation of crystalline silver nanoparticles. The aggregation of silver nanoparticles was prevented by CH3COONa in a chemical bath and then washed away, leaving crystalline silver nanoparticles. The silver nanoparticles were synthesized by sol-gel technique in the presence of CH3COONa and hydrazine as reducing agent in water at room temperature. The structure and grain size of prepared particles were characterized by Scanning Electron Microscope and X-ray Diffraction. The whole experiment has been carried out at room temperature, using water as solvent and also within very less time. From XRD pattern we got the crystallinity and the position of the crystal plane of the prepared particles was similar to the standard nano silver pattern and the average size of the particles was 11nm. For SEM study it was observed that the particles are homogenous and uniform size in the nano range cracked free surfaces with regular granular shaped grains without any impurities. There was no peak in the carbonyl frequency region confirmed that sodium acetate was not present within the silver particles. From STA study, we have observed that the weight loss was negligible assured the particles were pure. Hence we will describe an excellent scope for large scale production of silver nanocrystals which will have applications in electronics and catalysis.
Md Hasibur Rahman,
Mohammad Sajjad Hossain,
Most Afroza Khatun,
Most Hosney Ara Begum,
Synthesis and Characterization of Silver Nanoparticles by Sol-Gel Technique, Nanoscience and Nanometrology.
Vol. 3, No. 1,
2017, pp. 34-39.
K. Mallikarjuna, G. R. Dillip, G. Narasimha, N. John Sushma, B. Deva Prasad Raju, “Phytofabrication and Characterization of Silver Nanoparticles from Piper betle Broth”, Res. J. Nanosci. and Nanotech, 2, 17-23 (2012).
M. A. Meyers, A. Mishra, D. J. Benson,“Mechanical properties of nanocrystalline materials”, Prog. Mater sci., 51 (4), 427-556 (2006).
G. Schimd, L. F. Chi. “Metal Clusters and Colloids,” Adv. Mater., 10 (7), 515 (1998).
M. C. Daniel, D. Astruc"Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology". Chem Rev, 104 (1), 293-346 (2004).
M. Willert, R. Rothe, K. Landfaster, M. Antonietti, “Synthesis of inorganic and metallic nanoparticles by miniemulsification of molten salts and metals”,Chem. Mater.,13 (12), 4681–4685, (2001).
V. Colvin, M. Schlamp, A. Alivisatos, "Light emitting diodes made from cadmium selenidenanocrystals and a semiconducting polymer.". Nature, 370, 354-357 (1994).
N. Yanagihara, K. Uchida, M. Wakabayashi, Y. Uetake, T. Hara, “Effect of Radical Initiators on the Size and Formation of Silver Nanoclusters in Poly (methyl methycrylate),” Langmuir,15 (9). 3038-3041, (1999).
H. J. Jeon, S. C. Yi, and S. G. Oh, ”Preparation and antibacterial effects of Ag-SiO2 thin films by sol-gel method”, Biomaterials, 24 (27), 4921-4928, (2003).
S. G. Kotthaus, B. H. Hang, R. H. Schafer, "Study of isotropically conductive bondings filled with aggregates of nano-sited Ag-particles". IEEE Trans Compon Packaging Technol, 20, 15-20 (1997).
L. Zhao, H. Wang, K. Huo, L. Cui, W. Zhang, H. Ni, Y. Zhang, Z. Wu, P. K. Chu, “Antibacterial nano-structured titania coating incorporated with silvernanoparticles”Biomaterials, 32, 5706, (2011).
T. Klaus-Joerger, R. Joerger, E.Olsson, C. G. Granqvist, "Bacteria as workers in the living factory: metal-accumulating bacteria and their potential for materials science". Trends in Biotechnology,19 (1), 15-20 (2001).
K. H. P. Hong, J. L. Park, I. H. Sul, J. H. Youk, T. J Kang, "Preparation of antimicrobial poly (vinyl alcohol) nanofibers containing silver nanoparticles".J PolymSci Part B PolymPhys, 2006. 44, 2468-2472 (2006).
K. H. Cho, J-E Park. Cho, T. Osaka, S. G. Park, "The study of antimicrobial activity and preservative effects of nanosilver ingredient",ElectrochimicaActa, 51 (5) 956-960, (2005).
N. Dura´n, P. D. Marcato, G. I. H. De Suoza, O. L. Alves, E. Esposito, "Antibacterial effect of silver nanoparticles produced by fungal process on textile fabrics and their effluent treatment". J Biomed Nanotechnol, 3, 203-208 (2007).
H. Jiang, S. Manolache, A. C. L. Wong, F. S. Denes, “Plasma enhanced deposition of silver nanoparticles onto polymer and metal surfaces for the generation of antimicrobial characteristics’’,J Appl. PolyrSci. 93 (3), 1411-1422 (2004).
N. Duran, P. D. Marcato, O. L. Alves, G. I. H. de Souza, E. Esposito, “Mechanistic aspects of biosynthesis of silver nano particles by several Fusariumoxyporum strains,” J. Nanobiotechnology, 3, 8-14 (2005).
R. O. Becker, “Silver ions in the treatment of local infections,” Met based drugs, 6, 297-300 (1999).
T. Klaus, R. Joerger, E. Olsson, E Olssan, C. G Granqvist, “Silver based crystalline nanoparticles, microbially fabricated”, Procnatlacad sci, 96 (24), 13611-13614 (1999).
K. S. Chou, C. C. Chen, “Fabrication and characterization of silver core and porous silica shell nanocomposites particles”, Micropor. Mesopor.Mat., 98, 208-213, (2007).
A. A. El-kheshen, S. F. G. EL-Rab, “Effect of reducing and protecting agents on size of silver nanoparticles and their anti-bacterial activity”, Der. Pharma. Chemica., 4 (1), 53-65, (2012).
M. G. Guzman, J. Dille, S. Godet, “Synthesis of silver nanoparticles by chemical reduction method and their antibacterial activity”, Int. J. Chem. Biomolecular Eng., 2-3, 104-111, (2009).
M. Epifani, C. Giannini,L. Tapfer,L. Vasanelli, “Sol-Gel synthesis and characterization of Ag and Au nanoparticles in SiO2, TiO2 and ZrO2 thin films” Journal of the American ceramic society, 83 (10), 2385-2393, (2000).
F. F H Kruis, & B. Rellinghaus, B., "Sintering and evaporation characteristics of gas-phase synthesis of size-selected PbS nanoparticles." Mater Sci Eng B, 2000. 69: p. 329-324.
M. D. K Magnusson, J. Malm, J. Bovin, & L. Samuelson, "Gold nanoparticles: production, reshaping, and thermal charging.". J Nanoparticle Res, 1999. 1: p. 243-251.
M. Sastry, A. Ahmad A, MI. Khan, R. Kumar. Biosynthesis of metal nanoparticles using fungi and actinomycete. Curr Sci. 2003; 85: 162–170.
S. Iravani. Green synthesis of metal nanoparticles using plants. Green Chem. 2011; 13: 2638–2650.
H. Korbekandi, S. Iravani S, S. Abbasi. Production of nanoparticles using organisms. Crit Rev Biotech. 2009; 29: 279–306.
J. Gubicza, N. Q. Chinh, J. L. Labar, Z. Hegedus, P. Szommer, G. Tichy, T. G. Langdon, J. Mater.Sci. 43, 5672 (2008).
J. R. Weertman, Mater. Sci. Eng. A. 166, 161 (1993).
H. Van Swygenhoven, Science 296, 66 (2002).