Study the Effect of Solvent / Non-solvent on Polycarbonate
American Journal of Nanosciences
Volume 3, Issue 3, September 2017, Pages: 59-62
Received: Mar. 20, 2017; Accepted: Apr. 1, 2017; Published: Oct. 23, 2017
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Raad S. Sabry, Physics Department, College of Science, Al-Mustansiriyah University, Baghdad, Iraq
Muntazer I. Al-mosawi, Physics Department, College of Science, Al-Mustansiriyah University, Baghdad, Iraq
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A stable superhydrophobic PC surface was obtained by a simple phase separation method at room temperature. The water contact angle of the superhydrophobic PC surface is 156± 2°. FESEM image exhibited that the PC surface composed of flower-like shaped linked together centrally with branches offered roughness on the surface with a hierarchical micro/nano-binary formation. When the PC superhydrophobic surface was immersed in water with the temperatures ranging from 5°C to 45°C for 1 h to 15 days, the water contact angle remained higher than 150°.
Superhydrophobic Surfaces, Biomimetic Surfaces, Phase Separation, Solvent / Non-solvent, Acetone, DMF, Polycarbonate, Self-Cleaning
To cite this article
Raad S. Sabry, Muntazer I. Al-mosawi, Study the Effect of Solvent / Non-solvent on Polycarbonate, American Journal of Nanosciences. Vol. 3, No. 3, 2017, pp. 59-62. doi: 10.11648/j.ajn.20170303.15
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Bharat Bhushan and Yong Chae Jung, “Natural and Biomimetic Arti-ficial Surfaces for Superhydrophobicity, Self-Cleaning, Low Adhesion, and Drag Reduction”, Progress in Mate- rials Science, Vol. 56, No. 1, pp. 1-108, (2011).
Thomas Wagner, Christoph Neinhuis and Wilhelm Barthlott, “Wettability and Contaminability of Insect Wings as a Function of Their Surface Sculptures”, Acta Zoologica, Vol. 77, No. 3, pp. 213-225, (1996).
Michael Nosonovsky, “Superhydrophobic Surfaces and Emerging Applications: Non-Adhesion, Energy, Green Engineering”, Current Opinion in Colloid & Interface Science, Vol. 14, No. 4, pp. 270-280, (2009).
Chih-Feng Wang, Wei-Yan Chen, Huy-Zu Cheng, and Shen-Li Fu, “Pressure-proof superhydrophobic films from flexible carbon nanotube/polymer coatings”, J. Phys. Chem. C, 114 (37), pp. 15607–15611 (2010).
M. N. Valipour, F. C. Birjandi, J. Sargolzaei, “Super-non-wettable surfaces: a review”, Colloid Surface. Vol. 448, 20, pp. 93–106, (2014).
Liang liang Cao, Tyler P. Price, Michael Weiss, and Di Gao, “Super water-and oil-repellent surfaces on intrinsically hydrophilic and oleophilic porous silicon films”, Langmuir, 24 (5), pp 1640–1643, (2008).
Sumit Barthwal, Young Su Kim, Si-Hyung Lim, “Superhydrophobic and superoleophobic copper plate fabrication using alkaline solution assisted surface oxidation methods”, Int. J. Precis. Eng. Manuf. 13, Vol. 13, Issue 8, pp. 1311–1315, (2012).
Reiner Fürstner and Wilhelm Barthlott, “Wetting and self-cleaning properties of artificial superhydrophobic surfaces”, Langmuir, pp. 956–961, (2005).
E Elena Celia, Thierry Darmanin, Elisabeth Taffin de Givenchy, Sonia Amigoni, Frédéric Guittard, “Recent advances in designing superhydrophobic surfaces”, J. Colloid Interface Sci, Vol. 402, pp. 1–18, (2013).
H. Y. Erbil, A. L. Demirel, Y. Avcı, O. Mert, “Transformation of a simple plastic into a superhydrophobic surface”, Science, Vol. 299, Issue 5611, pp. 1377-1380, (2003).
Donghui Chu, Akihiko Nemoto and Hiroshi Ito, “Biomimetic superhydrophobic polymer surfaces by replication of hierarchical structures fabricated using precision tooling machine and anodized aluminum oxidation”, Microsyst Technol, Vol. 21, Issue 1, pp. 123–130, (2015).
Adel M. A. Mohamed, Aboubakr M. Abdullah and Nathalie A. Younan, “Corrosion behavior of superhydrophobic surfaces: A review”, Arabian Journal of Chemistry, Vol. 8, Issue 6, pp. 749–765, (2015).
Zhang Xintong Zhang, Ming Jin, Zhaoyue Liu, Shunsuke Nishimoto, Hidenori Saito, Taketoshi Murakami, and Akira Fujishima, “Preparation and Photocatalytic Wettability Conversion of TiO2-Based Superhydrophobic Surfaces”, Langmuir, pp. 9477–9479, (2006).
Gowariker, V. R., Viswanathan, N. V. and Shreedhar, “Polymer Science”, New Age International, ISBN : 978-81-224-3813-0, (2015).
Georg H. Michler and F J Baltá-Calleja, “Nano- and Micromechanics of Polymers Structure Modification and Improvement of Properties”, Carl Hanser Verlag, ISBN: 978-3-446-42767-9 (2012).
Manas Chanda, “Introduction to Polymer Science and Chemistry”, CRC Press, Taylor and Francis Group, ISBN 9781466553842, (2006).
Marcia C Delpech, Fernanda M. B Coutinho and Maria Eunice S Habibe, “Bisphenol A-based polycarbonates: characterization of commercial samples”, Polymer Test, Vol. 21, Issue 2, pp. 155–161, (2002).
Chiu, S. T., Chen, S. H., Tsai, C. T., “Effect of metal chlorides on thermal degradation of (waste) polycarbonate”, Waste Manag, pp. 252–259, (2006).
Balart, R., Sanchez, L., Lopez, L., Jimenez, A., “Kinetic analysis of thermal degradation of recycled polycarbonate/acrylonitrilebutadiene-styrene mixtures from waste electric and electronic equipment”, Polymer Degradation and Stability, Vol. 91, Issue 3, pp. 527–534, (2006).
Schulz, U, “Review of modern techniques to generate anti reflective properties of thermoplastic polymers”, Applied Optics, Vol. 45, Issue 7, pp. 1608-1618, (2006).
Zhang X, Tan S, Zhao N, Guo X, Zhang X, Zhang Y, Xu J, “Evaporation of Sessile Water Droplets on Superhydrophobic Natural Lotus and Biomimetic Polymer Surfaces”, Chem Phys Chem, pp. 2067–2070, (2006).
Ning Zhao, Jian Xu, Qiongdan Xie, Lihui Weng, Xinglin Guo, Xiaoli Zhang, Lianghe Shi, "Fabrication of Biomimetic Superhydrophobic Coating with a Micro-Nano-Binary Structure", Macromolecular Rapid Communications, Vol. 26, Issue 13, pp. 1075–1080, (2005).
Ning Zhao, Lihui Weng Dr., Xiaoyan Zhang, Qiongdan Xie, Xiaoli Zhang, Jian Xu Prof, “A Lotus-Leaf-Like Superhydrophobic Surface Prepared by Solvent-Induced Crystallization”, ChemPhysChem, Vol. 7, Issue 4, pp. 824–827, (2006).
Chaowei Guo Dr., Lin Feng Dr., Jin Zhai Dr., Guojie Wang Dr., Yanlin Song Prof., Lei Jiang Prof., Daoben Zhu Prof., “Large-Area Fabrication of a Nanostructure-Induced Hydrophobic Surface from a Hydrophilic Polymer”, ChemPhysChem, Vol. 5, Issue 5, pp. 750–753, (2004).
Yuehua Cui, Adam T. Paxson, Katherine M. Smyth, Kripa K. Varanasi, “Hierarchical polymeric textures via solvent-induced phase transformation: A single-step production of large-area superhydrophobic surfaces”, Colloids and Surfaces A: Physicochem. Eng. Aspects, Vol. 394, pp. 8–13, (2012).
P. Jankowski, D. Ogonczyk, A. Kosinski,W. Lisowski, P. Garstecki, “Hydrophobic modification of polycarbonate for reproducible and stable formation of biocompatible microparticles”, Lab Chip, Vol. 11, pp. 748–752, (2011).
Seungcheol Go, Moonhee Han, and Younghyun Ahn, “Formation of Nanoporous Polycarbonate Surfaces and Their Chemical Modification for Superhydrophobicity”, Bulletin- Korean Chemical Society, Vol. 33, pp. 3899-3902, (2012).
Sharad D. Bhagat, Mool C. Gupta, “Superhydrophobic microtextured polycarbonate surfaces”, Surface and Coatings Technology, Vol. 270, pp. 117-122, (2015).
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