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Interfacial Colloidal Performance and Adhesive Strength of an Environmentally Friendly Cellulose-microcrystal-based Adhesive Substance

Received: 16 December 2020    Accepted: 29 December 2020    Published: 12 January 2021
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Abstract

As one of the high-value and environmentally friendly chemical products, cellulose-based adhesive substance has been widely developed recently due to its extraordinary adhesion, interfacial flowability and high stability, along with low-impact side effects, outstanding degradability and biocompatibility. Also, microcrystalline-shaped cellulose has been fully exploited in functinalizing modification engineering. To eliminate the gap in application of cellulose-ether-based adhesion, we fabricated a new category of optimized cellulose sulfate product based on a system of analysis of key experimental factors: solvent pretreatment, degree of esterification, type and morphology of cellulose. Additionally, we focused on an all-round family of performance test of our product, containing characterization of structural and morphological features, test of water-based properties and inspection of adhesion behaviour. Within, the effect of adhesive strength in various solvents and under various conditions have been highlighted. The whole result shows a generally feasible synthetic approach and splendid performance as a novel green adhesive. The optimal design and synthesis of cellulose sulfate is verified to be eco-friendly, easy for optimization and greatly reproducible. Also, the product is shown to have tiptop viscosity, great adhesive strength, and colloidal potential like film forming due to the cross-linking network in the water-based environment. Finally, the product are demonstrated to be outstanding and widely applicable in mechanical strength. Specifically, it shows strong adhesion on different materials (metal, timber and glass) and tunability related to the kinds of additives. The addition of metallic salts and polymeric amine can evidently boost its adhesive strength. Overall, optimal analysis of cellulose sulfate adhesive on a microscale has forecasted great potential in low-carbon, fine-tunable, adhesive-related industry.

Published in American Journal of Nanosciences (Volume 6, Issue 4)
DOI 10.11648/j.ajn.20200604.11
Page(s) 24-33
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Cellulose Sulfate, Adhesion, Viscoelasticity, Colloidal Behavior, Hydrodynamic Performance, Characterization, Cross-Linking, Environmentally Friendly

References
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[4] Zhang J., Zhang L. M. and Li Z. M. (2000) Synthesis and Aqueous Solution Properties of Hydrophobically Modified Graft Copolymer of Sodium Carboxymethyl Cellulose with Acrylamide and Dimethyloctyl (2-methacryloxyethyl) Ammonium Bromide. Journal of Applied Polymer Science 78 (3): 537-542.
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[8] Appaw C., Gilbert R. D. and Khan S. A. (2007) Viscoelastic Behavior of Cellulose Acetate in a Mixed Solvent System. Biomacromolecules 8 (5): 1541-1547.
[9] Nyström B., Walderhaug H., Hansen F. K. and Lindman B. (1995) Rheological Behavior during Thermoreversible Gelation of Aqueous Mixtures of Ethyl (Hydroxyethyl) Cellulose and Surfactants. Langmuir 11 (3): 750-757.
[10] Zhou J., Xu Y., Wang X., Qin Y. and Zhang L. (2008) Microstructure and Aggregation Behavior of Methylcelluloses Prepared in NaOH/Urea Aqueous Solutions. Carbohydrate Polymers 74 (4): 901-906.
[11] Lv X., Li L., Lin Z. and Cui S. (2011) Formation Mechanism of Ionic Liquid Regenerated Cellulose Hydrogel and Its Application in Gel Electrophoresis. Acta Polymerica Sinica 011 (9): 1026-1032.
[12] Kavanagh G. M. and Ross-Murphy S. B. (1998) Rheological Characterization of Polymer Gels. Progress in Polymer Science 23 (3): 533-562.
[13] Fan L., Zhou X., Wu P., Xie W., Zheng H., Tan W., Liu S. and Li Q. (2014) Preparation of Carboxymethyl Cellulose Sulfates and its Application as Anticoagulant and Wound dressing. International Journal of Biological Macromolecules 66 (0): 245-253.
[14] Gauche C. and Felisberti M. I. (2019) Colloidal Behavior of Cellulose Nanocrystals Grafted with Poly (2-alkyl-2-oxazoline)s. ACS Omega 4 (7): 11893-11905.
[15] Sandak A., Jaszczur A., Sandak J. and Modzelewska I. (2015) Near Infrared Assessment of Biodegradability and Mechanical Properties of Paper Made of Cellulose Sulfate Bleached Coniferous Pulp with Addition of Cationic Starch and Resinous Adhesive. International Biodeterioration & Biodegradation 97: 31-39.
[16] Lai Y. L., Zhang H., Sugano Y., Xie H. and Kallio P. (2019) Correlation of Surface Morphology and Interfacial Adhesive Behavior between Cellulose Surfaces: Quantitative Measurements in Peak-Force Mode with the Colloidal Probe Technique. Langmuir 35 (22): 7312-7321.
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Cite This Article
  • APA Style

    Zhexu Xi, Jianfei Feng, Xiaolin Lu. (2021). Interfacial Colloidal Performance and Adhesive Strength of an Environmentally Friendly Cellulose-microcrystal-based Adhesive Substance. American Journal of Nanosciences, 6(4), 24-33. https://doi.org/10.11648/j.ajn.20200604.11

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    ACS Style

    Zhexu Xi; Jianfei Feng; Xiaolin Lu. Interfacial Colloidal Performance and Adhesive Strength of an Environmentally Friendly Cellulose-microcrystal-based Adhesive Substance. Am. J. Nanosci. 2021, 6(4), 24-33. doi: 10.11648/j.ajn.20200604.11

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    AMA Style

    Zhexu Xi, Jianfei Feng, Xiaolin Lu. Interfacial Colloidal Performance and Adhesive Strength of an Environmentally Friendly Cellulose-microcrystal-based Adhesive Substance. Am J Nanosci. 2021;6(4):24-33. doi: 10.11648/j.ajn.20200604.11

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  • @article{10.11648/j.ajn.20200604.11,
      author = {Zhexu Xi and Jianfei Feng and Xiaolin Lu},
      title = {Interfacial Colloidal Performance and Adhesive Strength of an Environmentally Friendly Cellulose-microcrystal-based Adhesive Substance},
      journal = {American Journal of Nanosciences},
      volume = {6},
      number = {4},
      pages = {24-33},
      doi = {10.11648/j.ajn.20200604.11},
      url = {https://doi.org/10.11648/j.ajn.20200604.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajn.20200604.11},
      abstract = {As one of the high-value and environmentally friendly chemical products, cellulose-based adhesive substance has been widely developed recently due to its extraordinary adhesion, interfacial flowability and high stability, along with low-impact side effects, outstanding degradability and biocompatibility. Also, microcrystalline-shaped cellulose has been fully exploited in functinalizing modification engineering. To eliminate the gap in application of cellulose-ether-based adhesion, we fabricated a new category of optimized cellulose sulfate product based on a system of analysis of key experimental factors: solvent pretreatment, degree of esterification, type and morphology of cellulose. Additionally, we focused on an all-round family of performance test of our product, containing characterization of structural and morphological features, test of water-based properties and inspection of adhesion behaviour. Within, the effect of adhesive strength in various solvents and under various conditions have been highlighted. The whole result shows a generally feasible synthetic approach and splendid performance as a novel green adhesive. The optimal design and synthesis of cellulose sulfate is verified to be eco-friendly, easy for optimization and greatly reproducible. Also, the product is shown to have tiptop viscosity, great adhesive strength, and colloidal potential like film forming due to the cross-linking network in the water-based environment. Finally, the product are demonstrated to be outstanding and widely applicable in mechanical strength. Specifically, it shows strong adhesion on different materials (metal, timber and glass) and tunability related to the kinds of additives. The addition of metallic salts and polymeric amine can evidently boost its adhesive strength. Overall, optimal analysis of cellulose sulfate adhesive on a microscale has forecasted great potential in low-carbon, fine-tunable, adhesive-related industry.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Interfacial Colloidal Performance and Adhesive Strength of an Environmentally Friendly Cellulose-microcrystal-based Adhesive Substance
    AU  - Zhexu Xi
    AU  - Jianfei Feng
    AU  - Xiaolin Lu
    Y1  - 2021/01/12
    PY  - 2021
    N1  - https://doi.org/10.11648/j.ajn.20200604.11
    DO  - 10.11648/j.ajn.20200604.11
    T2  - American Journal of Nanosciences
    JF  - American Journal of Nanosciences
    JO  - American Journal of Nanosciences
    SP  - 24
    EP  - 33
    PB  - Science Publishing Group
    SN  - 2575-4858
    UR  - https://doi.org/10.11648/j.ajn.20200604.11
    AB  - As one of the high-value and environmentally friendly chemical products, cellulose-based adhesive substance has been widely developed recently due to its extraordinary adhesion, interfacial flowability and high stability, along with low-impact side effects, outstanding degradability and biocompatibility. Also, microcrystalline-shaped cellulose has been fully exploited in functinalizing modification engineering. To eliminate the gap in application of cellulose-ether-based adhesion, we fabricated a new category of optimized cellulose sulfate product based on a system of analysis of key experimental factors: solvent pretreatment, degree of esterification, type and morphology of cellulose. Additionally, we focused on an all-round family of performance test of our product, containing characterization of structural and morphological features, test of water-based properties and inspection of adhesion behaviour. Within, the effect of adhesive strength in various solvents and under various conditions have been highlighted. The whole result shows a generally feasible synthetic approach and splendid performance as a novel green adhesive. The optimal design and synthesis of cellulose sulfate is verified to be eco-friendly, easy for optimization and greatly reproducible. Also, the product is shown to have tiptop viscosity, great adhesive strength, and colloidal potential like film forming due to the cross-linking network in the water-based environment. Finally, the product are demonstrated to be outstanding and widely applicable in mechanical strength. Specifically, it shows strong adhesion on different materials (metal, timber and glass) and tunability related to the kinds of additives. The addition of metallic salts and polymeric amine can evidently boost its adhesive strength. Overall, optimal analysis of cellulose sulfate adhesive on a microscale has forecasted great potential in low-carbon, fine-tunable, adhesive-related industry.
    VL  - 6
    IS  - 4
    ER  - 

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Author Information
  • Bristol Centre for Functional Nanomaterials, University of Bristol, Bristol, UK

  • College of Materials, Xiamen University, Xiamen, China

  • College of Materials, Xiamen University, Xiamen, China

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