Journal of Biomaterials

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Adsorption of Malachite Green Dye Using Orange Peel

Received: 17 October 2018    Accepted: 02 November 2018    Published: 27 November 2018
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Abstract

High level of dyes production and their widespread use in many applications generate colours wastewaters which cause severe water pollution. The pollutant contributes to high suspended solids (SS), chemical oxygen demands (COD), biochemical oxygen demands (BOD), heat, colour, acidity, basicity and other soluble substances. The presence of these dyes in aquatic systems poses heavy risks to human health. Therefore, removal of such dyes from water bodies may be considered an interesting and important research activity. This study shows that orange peel can be used as a suitable adsorbent for the removal of malachite green dyes from solutions. This is a work on the removal of Malachite green dye from their solution with the use of orange peel. The orange peelis sourced locally. Proximate analysis done on the adsorbent revealed that the orange peels had 13.25% Moisture content, 5.68% Ash content and 4.7% Carbon content. FTIR technique was also used to identify the functional groups and organic compounds inherent in the orange peels. The adsorption isotherm models used were Henry, Langmuir I, Langmuir II, Langmuir III, Langmuir IV, Freundlich, Temkin and Dubinin-Radushkevich. The result from the models shows that Henry isotherm model fits better for the adsorption of the dye with Orange peels. Results obtained showed that adsorption followed second order kinetics. Thermodynamic data for enthalpy (ΔH) for the adsorption of the dye shows that adsorption was endothermic. The entropy result indicates that there is an increase in randomness at the solid liquid interface. Free energy change shows that adsorption for the dye at temperatures of 298, 323, 343 and 373 were spontaneous and feasible.

DOI 10.11648/j.jb.20180202.12
Published in Journal of Biomaterials (Volume 2, Issue 2, December 2018)
Page(s) 31-40
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Malachite Green Dye, Orange Peel, Adsorption Isotherm, Proximate Analysis, FTIR

References
[1] Anupa, U. (2014). Adsorption of reactive blue-4 dye from aqueous solution onto acid activated mustard stalk: equilibrium and kinetic studies. Global journal of biology, Agriculture and Health sciences, 3(1): 98-105.
[2] Balasubramani, K., Sivarajasekar, N. (2014). Adsorption Studies of Organic Pollutants onto Activated Carbon. International Journal of Innovative Research in Science, Engineering and Technology, 3(3): 10575-10581.
[3] Graham Solomon T. W. (2012): A text book of organic chemistry, 8th ed., Wiley and sons INC., Canada. pp 397-685.
[4] Upadhye, G. C., andYamgar, R. S. (2016). Analytical study of agricultural waste as non-conventional low cost adsorbent removal of dyes from aqueous solutions. International Journal of Chemical Studies, 4(1): 128-133.
[5] Okafor, P. C., Okon, P. U., Daniel, E. F. and Ebenso, E. E. (2012). Adsorption Capacity of Coconut (Cocosnucifera L.) Shell for Lead, Copper, Cadmium and Arsenic from Aqueous Solutions. International Journal of electrochemical science, 7(1): 12354-12369.
[6] Olugbenga, S. B., Olayinka, U. B., Ibrahim, O. L. (2014). Adsorption Characteristics of Mango Leaf (Mangiferaindica) Powder as Adsorbent for Malachite Green Dye Removal from Aqueous Solution. Covenant Journal of Physical and Life Sciences, 2(1): 1-6.
[7] Mohamad, A. K., MohdFaizMuaz A. Z., Mohd, S. Y., Mohd H. Z. (2016). Cotton Dyeing wastewater characteristics and its treatment efficiency by using coconut shell carbon and limestone powder. Journal of Scientific Research and Development 3 (5): 221‐228.
[8] Ibtissam, M., Fatiha, A., Mohamed, E., Abdelkbir, K., Omar, T., Mohamed, T. &Salouhi M. (2012). Comparison of Adsorption of Dye onto Low-Cost Adsorbents. Global Journal of Science Frontier Research Chemistry, 12(4): 6-11.
[9] Rao R. A. K., Ikram S. and Ahmad J. (2011): Adsorption of Pb(II) on a composite material prepared from polystyrene, Alumina and activated carbon: kinetic and thermodynamic studies. J. Iran. Chem. Soc. 8(4); 931-943.
[10] Sachin, M. K., Gaikwad, R. W. & Misal, S. A. (2010). Low cost Sugarcane Bagasse Ash as an Adsorbent for Dye Removal from Dye Effluent. International Journal of Chemical Engineering and Applications, 1(4): 309-318.
Author Information
  • Department of Chemistry, Ahmadu Bello University, Zaria, Nigeria

  • Department of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Chemistry, Federal University of Technology, Akure, Nigeria

  • Department of Pure & Industrial Chemistry, Nnamdi Azikiwe University, Awka, Nigeria

  • Department of Microbiology, Abia State University, Uturu, Nigeria

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    Abdussalam Zhul-quarnain, Iwuozor Kingsley Ogemdi, Ilesanmi Modupe, Emuobosa Gold, Ekpunobi Emmanuel Chidubem. (2018). Adsorption of Malachite Green Dye Using Orange Peel. Journal of Biomaterials, 2(2), 31-40. https://doi.org/10.11648/j.jb.20180202.12

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    ACS Style

    Abdussalam Zhul-quarnain; Iwuozor Kingsley Ogemdi; Ilesanmi Modupe; Emuobosa Gold; Ekpunobi Emmanuel Chidubem. Adsorption of Malachite Green Dye Using Orange Peel. J. Biomater. 2018, 2(2), 31-40. doi: 10.11648/j.jb.20180202.12

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    AMA Style

    Abdussalam Zhul-quarnain, Iwuozor Kingsley Ogemdi, Ilesanmi Modupe, Emuobosa Gold, Ekpunobi Emmanuel Chidubem. Adsorption of Malachite Green Dye Using Orange Peel. J Biomater. 2018;2(2):31-40. doi: 10.11648/j.jb.20180202.12

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  • @article{10.11648/j.jb.20180202.12,
      author = {Abdussalam Zhul-quarnain and Iwuozor Kingsley Ogemdi and Ilesanmi Modupe and Emuobosa Gold and Ekpunobi Emmanuel Chidubem},
      title = {Adsorption of Malachite Green Dye Using Orange Peel},
      journal = {Journal of Biomaterials},
      volume = {2},
      number = {2},
      pages = {31-40},
      doi = {10.11648/j.jb.20180202.12},
      url = {https://doi.org/10.11648/j.jb.20180202.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.jb.20180202.12},
      abstract = {High level of dyes production and their widespread use in many applications generate colours wastewaters which cause severe water pollution. The pollutant contributes to high suspended solids (SS), chemical oxygen demands (COD), biochemical oxygen demands (BOD), heat, colour, acidity, basicity and other soluble substances. The presence of these dyes in aquatic systems poses heavy risks to human health. Therefore, removal of such dyes from water bodies may be considered an interesting and important research activity. This study shows that orange peel can be used as a suitable adsorbent for the removal of malachite green dyes from solutions. This is a work on the removal of Malachite green dye from their solution with the use of orange peel. The orange peelis sourced locally. Proximate analysis done on the adsorbent revealed that the orange peels had 13.25% Moisture content, 5.68% Ash content and 4.7% Carbon content. FTIR technique was also used to identify the functional groups and organic compounds inherent in the orange peels. The adsorption isotherm models used were Henry, Langmuir I, Langmuir II, Langmuir III, Langmuir IV, Freundlich, Temkin and Dubinin-Radushkevich. The result from the models shows that Henry isotherm model fits better for the adsorption of the dye with Orange peels. Results obtained showed that adsorption followed second order kinetics. Thermodynamic data for enthalpy (ΔH) for the adsorption of the dye shows that adsorption was endothermic. The entropy result indicates that there is an increase in randomness at the solid liquid interface. Free energy change shows that adsorption for the dye at temperatures of 298, 323, 343 and 373 were spontaneous and feasible.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Adsorption of Malachite Green Dye Using Orange Peel
    AU  - Abdussalam Zhul-quarnain
    AU  - Iwuozor Kingsley Ogemdi
    AU  - Ilesanmi Modupe
    AU  - Emuobosa Gold
    AU  - Ekpunobi Emmanuel Chidubem
    Y1  - 2018/11/27
    PY  - 2018
    N1  - https://doi.org/10.11648/j.jb.20180202.12
    DO  - 10.11648/j.jb.20180202.12
    T2  - Journal of Biomaterials
    JF  - Journal of Biomaterials
    JO  - Journal of Biomaterials
    SP  - 31
    EP  - 40
    PB  - Science Publishing Group
    SN  - 2640-2629
    UR  - https://doi.org/10.11648/j.jb.20180202.12
    AB  - High level of dyes production and their widespread use in many applications generate colours wastewaters which cause severe water pollution. The pollutant contributes to high suspended solids (SS), chemical oxygen demands (COD), biochemical oxygen demands (BOD), heat, colour, acidity, basicity and other soluble substances. The presence of these dyes in aquatic systems poses heavy risks to human health. Therefore, removal of such dyes from water bodies may be considered an interesting and important research activity. This study shows that orange peel can be used as a suitable adsorbent for the removal of malachite green dyes from solutions. This is a work on the removal of Malachite green dye from their solution with the use of orange peel. The orange peelis sourced locally. Proximate analysis done on the adsorbent revealed that the orange peels had 13.25% Moisture content, 5.68% Ash content and 4.7% Carbon content. FTIR technique was also used to identify the functional groups and organic compounds inherent in the orange peels. The adsorption isotherm models used were Henry, Langmuir I, Langmuir II, Langmuir III, Langmuir IV, Freundlich, Temkin and Dubinin-Radushkevich. The result from the models shows that Henry isotherm model fits better for the adsorption of the dye with Orange peels. Results obtained showed that adsorption followed second order kinetics. Thermodynamic data for enthalpy (ΔH) for the adsorption of the dye shows that adsorption was endothermic. The entropy result indicates that there is an increase in randomness at the solid liquid interface. Free energy change shows that adsorption for the dye at temperatures of 298, 323, 343 and 373 were spontaneous and feasible.
    VL  - 2
    IS  - 2
    ER  - 

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