Journal of Energy, Environmental & Chemical Engineering

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Lanthanum-Doped Ceria Nanocomposite: A Highly Stable Monolithic Catalyst for Direct Synthesis of Dimethyl Carbonate

Received: 01 December 2020    Accepted: 22 December 2020    Published: 31 December 2020
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Abstract

That dimethyl carbonate is directly synthesized from methanol and carbon dioxide is an effective and environmental approach to solve the greenhouse effect. For the sake of solving the problems of low DMC productivity and poor catalysts stability in presence of the formed water. Here we design and prepare a serial of spherical La-doped ceria nanoparticles (Ce1-xLaxOδ nanocomposites, x=0.00, 0.05, 0.10, 0.15, and 0.20) via a co-precipitation method. These Ce1-xLaxOδ composites are ground into slurry by ball milled and then coated on cordierite honeycomb ceramics to obtain Ce1-xLaxOδ monolithic catalysts. These Ce1-xLaxOδ composites are characterized extensively by TEM, XRD, Raman spectroscopy, N2 adsorption-desorption isotherms, H2-TPR and XPS. The characterization results show that the Ce1-xLaxOδ composites nanoparticles possesses richer surface oxygen vacancies, higher BET surface area and smaller particle size than that of pure CeO2 nanoparticle. Besides, catalytic activity test shows these Ce1-xLaxOδ monolithic catalysts exhibit better catalytic performance than that of pure CeO2 nanoparticles. Among them, Ce0.95La0.05Oδ monolithic catalyst exhibits the highest CH3OH conversion and DMC yield, which is in good line with the oxygen vacancy content measured by XPS. Finally, the Ce0.95La0.05Oδ monolithic catalyst also shows an excellent durability of more than 100 hours, which is mainly due to the doping effect of lanthanum into the ceria oxides tailoring the structure and surface properties of the catalyst.

DOI 10.11648/j.jeece.20200504.12
Published in Journal of Energy, Environmental & Chemical Engineering (Volume 5, Issue 4, December 2020)
Page(s) 57-66
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

La-doped CeO2 Nanoparticles, Dimethyl Carbonate, Monolithic Catalysts, High Durability, CO2 Utilization

References
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Author Information
  • College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, China

  • College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, China

  • College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, China

  • College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, China

  • College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, China

  • College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu, China

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    Wei Chen, Zhongbin Ye, Yue Li, Nanjun Lai, Zhaohua Song, et al. (2020). Lanthanum-Doped Ceria Nanocomposite: A Highly Stable Monolithic Catalyst for Direct Synthesis of Dimethyl Carbonate. Journal of Energy, Environmental & Chemical Engineering, 5(4), 57-66. https://doi.org/10.11648/j.jeece.20200504.12

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    ACS Style

    Wei Chen; Zhongbin Ye; Yue Li; Nanjun Lai; Zhaohua Song, et al. Lanthanum-Doped Ceria Nanocomposite: A Highly Stable Monolithic Catalyst for Direct Synthesis of Dimethyl Carbonate. J. Energy Environ. Chem. Eng. 2020, 5(4), 57-66. doi: 10.11648/j.jeece.20200504.12

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    AMA Style

    Wei Chen, Zhongbin Ye, Yue Li, Nanjun Lai, Zhaohua Song, et al. Lanthanum-Doped Ceria Nanocomposite: A Highly Stable Monolithic Catalyst for Direct Synthesis of Dimethyl Carbonate. J Energy Environ Chem Eng. 2020;5(4):57-66. doi: 10.11648/j.jeece.20200504.12

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  • @article{10.11648/j.jeece.20200504.12,
      author = {Wei Chen and Zhongbin Ye and Yue Li and Nanjun Lai and Zhaohua Song and Yongdong Chen},
      title = {Lanthanum-Doped Ceria Nanocomposite: A Highly Stable Monolithic Catalyst for Direct Synthesis of Dimethyl Carbonate},
      journal = {Journal of Energy, Environmental & Chemical Engineering},
      volume = {5},
      number = {4},
      pages = {57-66},
      doi = {10.11648/j.jeece.20200504.12},
      url = {https://doi.org/10.11648/j.jeece.20200504.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.jeece.20200504.12},
      abstract = {That dimethyl carbonate is directly synthesized from methanol and carbon dioxide is an effective and environmental approach to solve the greenhouse effect. For the sake of solving the problems of low DMC productivity and poor catalysts stability in presence of the formed water. Here we design and prepare a serial of spherical La-doped ceria nanoparticles (Ce1-xLaxOδ nanocomposites, x=0.00, 0.05, 0.10, 0.15, and 0.20) via a co-precipitation method. These Ce1-xLaxOδ composites are ground into slurry by ball milled and then coated on cordierite honeycomb ceramics to obtain Ce1-xLaxOδ monolithic catalysts. These Ce1-xLaxOδ composites are characterized extensively by TEM, XRD, Raman spectroscopy, N2 adsorption-desorption isotherms, H2-TPR and XPS. The characterization results show that the Ce1-xLaxOδ composites nanoparticles possesses richer surface oxygen vacancies, higher BET surface area and smaller particle size than that of pure CeO2 nanoparticle. Besides, catalytic activity test shows these Ce1-xLaxOδ monolithic catalysts exhibit better catalytic performance than that of pure CeO2 nanoparticles. Among them, Ce0.95La0.05Oδ monolithic catalyst exhibits the highest CH3OH conversion and DMC yield, which is in good line with the oxygen vacancy content measured by XPS. Finally, the Ce0.95La0.05Oδ monolithic catalyst also shows an excellent durability of more than 100 hours, which is mainly due to the doping effect of lanthanum into the ceria oxides tailoring the structure and surface properties of the catalyst.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Lanthanum-Doped Ceria Nanocomposite: A Highly Stable Monolithic Catalyst for Direct Synthesis of Dimethyl Carbonate
    AU  - Wei Chen
    AU  - Zhongbin Ye
    AU  - Yue Li
    AU  - Nanjun Lai
    AU  - Zhaohua Song
    AU  - Yongdong Chen
    Y1  - 2020/12/31
    PY  - 2020
    N1  - https://doi.org/10.11648/j.jeece.20200504.12
    DO  - 10.11648/j.jeece.20200504.12
    T2  - Journal of Energy, Environmental & Chemical Engineering
    JF  - Journal of Energy, Environmental & Chemical Engineering
    JO  - Journal of Energy, Environmental & Chemical Engineering
    SP  - 57
    EP  - 66
    PB  - Science Publishing Group
    SN  - 2637-434X
    UR  - https://doi.org/10.11648/j.jeece.20200504.12
    AB  - That dimethyl carbonate is directly synthesized from methanol and carbon dioxide is an effective and environmental approach to solve the greenhouse effect. For the sake of solving the problems of low DMC productivity and poor catalysts stability in presence of the formed water. Here we design and prepare a serial of spherical La-doped ceria nanoparticles (Ce1-xLaxOδ nanocomposites, x=0.00, 0.05, 0.10, 0.15, and 0.20) via a co-precipitation method. These Ce1-xLaxOδ composites are ground into slurry by ball milled and then coated on cordierite honeycomb ceramics to obtain Ce1-xLaxOδ monolithic catalysts. These Ce1-xLaxOδ composites are characterized extensively by TEM, XRD, Raman spectroscopy, N2 adsorption-desorption isotherms, H2-TPR and XPS. The characterization results show that the Ce1-xLaxOδ composites nanoparticles possesses richer surface oxygen vacancies, higher BET surface area and smaller particle size than that of pure CeO2 nanoparticle. Besides, catalytic activity test shows these Ce1-xLaxOδ monolithic catalysts exhibit better catalytic performance than that of pure CeO2 nanoparticles. Among them, Ce0.95La0.05Oδ monolithic catalyst exhibits the highest CH3OH conversion and DMC yield, which is in good line with the oxygen vacancy content measured by XPS. Finally, the Ce0.95La0.05Oδ monolithic catalyst also shows an excellent durability of more than 100 hours, which is mainly due to the doping effect of lanthanum into the ceria oxides tailoring the structure and surface properties of the catalyst.
    VL  - 5
    IS  - 4
    ER  - 

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