The main aim of this work is to study the physical changes in the gasoline portion of the Sudanese petroleum upon treating with synthetic zeolite. Treating gasoline with zeolites usually performed in order to enhance the octane number of the oil. The octane number measures the degree of the gasoline resist to self-ignition prior to combustion. Gasoline with higher octane number has higher tendency to resist self-ignition. Gasoline containing branched and aromatic hydrocarbons resists self-ignition rather than gasoline containing straight chain hydrocarbons. 2,2,4 trimethyl pentane name disooctane (has octane number 100) and n-heptane (has octane number 0) are used to measure the octane number of the oil under the test. Zeolites are frame work of tetrahedral silicates (TO4), with a net negative charge balanced by a positive cation. Zeolite/Li indicating that the Li cation is used to neutralized the frame work. Zeolite/refinery refers to an industrial zeolite brought from Sudanese Petroleum Company. The gasoline portion used before treatment with any zeolites is considered to be a standard and is called a blank. Physical properties (distillation, density, S.G@15OC, Reid vapor pressure and the degree of corrosion) were carried out for the blank, the mixture of zeolite/Li with the gasoline and the mixture of zeolite/refinery with the gasoline. The density of the gasoline after treatment with zeolite/Li was found to be higher than the density of the blank. The Reid vapor pressure of the gasoline after treatment with zeolite/Li was found to be lower than the Reid vapor pressure of the blank. The distillate properties (the initial boiling point IBP and the final boiling point FBP) for the blank, gasoline after treatment with zeolite/Li and zeolite/refinery were not found to change considerably. The blank and the blank after treatment with zeolite/refinery were found to possess the same degree of corrosion (1b) which is the slightly corrosive whereas the blank after treatment with zeolite/Li has a (2c) degree which is moderate corrosive.
| Published in | International Journal of Bioorganic Chemistry (Volume 2, Issue 4) |
| DOI | 10.11648/j.ijbc.20170204.14 |
| Page(s) | 180-184 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Zeolite, Blank, IBP (Initial Boiling Point), FBP (Final Boiling Point), Reid Vapor Pressure, Corrosion, A. S. T. M. (American Standard Test for Materials)
| [1] | American fuel and petrochemical refiners, refining capacity report, 66, August (2017). |
| [2] | B. Hamilton, Automotive gasoline, FAQ (18 January 1995). |
| [3] | J. C. Clevel, R. Szostak, Cracking, Encyclopedia of Earth, National Council for Science and the Environment (2008), (Washington). |
| [4] | Chem. Commun. 51, 7602-7605(2015) |
| [5] | A. Frederick, Mineralogy and geology of the natural zeolites, Mineralogical Society of America, 4, (1997) Washington. |
| [6] | Eyidogan, Muharrem, Impact of alcohol–gasoline fuel blends on the performance and combustion characteristics of an SI engine Fuel, 89(10), 2713–2720, (2010). |
| [7] | M. M. Rahmana, N. Hasnidab, and W. B. Wan Nikb, Preparation of zeolite Y using local raw material rice husk as a silica source, J. Sci. Res. 1 (2), (2009), 285-291. |
| [8] | A. S. T. M., Petroleum Products and Lubricants, D, 86-04a, May (2004). |
| [9] | A. S. T. M., Petroleum Products and Lubricants D, 1298–85, (1999). |
| [10] | A. S. T. M., Petroleum Products and Lubricants, D, 323-30, June (1999). |
| [11] | S. T. M., Petroleum Products and Lubricants, D, 130–94, May (2004). |
APA Style
Mutaz Mohamed Ahmed Elshiekh, Nazar Abdulaziz Elnasri. (2017). Physical Properties Changes Accompanies Treating Gasoline Fraction of Petroleum with Synthetic Zeolite. International Journal of Bioorganic Chemistry, 2(4), 180-184. https://doi.org/10.11648/j.ijbc.20170204.14
ACS Style
Mutaz Mohamed Ahmed Elshiekh; Nazar Abdulaziz Elnasri. Physical Properties Changes Accompanies Treating Gasoline Fraction of Petroleum with Synthetic Zeolite. Int. J. Bioorg. Chem. 2017, 2(4), 180-184. doi: 10.11648/j.ijbc.20170204.14
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Download@article{10.11648/j.ijbc.20170204.14,
author = {Mutaz Mohamed Ahmed Elshiekh and Nazar Abdulaziz Elnasri},
title = {Physical Properties Changes Accompanies Treating Gasoline Fraction of Petroleum with Synthetic Zeolite},
journal = {International Journal of Bioorganic Chemistry},
volume = {2},
number = {4},
pages = {180-184},
doi = {10.11648/j.ijbc.20170204.14},
url = {https://doi.org/10.11648/j.ijbc.20170204.14},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbc.20170204.14},
abstract = {The main aim of this work is to study the physical changes in the gasoline portion of the Sudanese petroleum upon treating with synthetic zeolite. Treating gasoline with zeolites usually performed in order to enhance the octane number of the oil. The octane number measures the degree of the gasoline resist to self-ignition prior to combustion. Gasoline with higher octane number has higher tendency to resist self-ignition. Gasoline containing branched and aromatic hydrocarbons resists self-ignition rather than gasoline containing straight chain hydrocarbons. 2,2,4 trimethyl pentane name disooctane (has octane number 100) and n-heptane (has octane number 0) are used to measure the octane number of the oil under the test. Zeolites are frame work of tetrahedral silicates (TO4), with a net negative charge balanced by a positive cation. Zeolite/Li indicating that the Li cation is used to neutralized the frame work. Zeolite/refinery refers to an industrial zeolite brought from Sudanese Petroleum Company. The gasoline portion used before treatment with any zeolites is considered to be a standard and is called a blank. Physical properties (distillation, density, S.G@15OC, Reid vapor pressure and the degree of corrosion) were carried out for the blank, the mixture of zeolite/Li with the gasoline and the mixture of zeolite/refinery with the gasoline. The density of the gasoline after treatment with zeolite/Li was found to be higher than the density of the blank. The Reid vapor pressure of the gasoline after treatment with zeolite/Li was found to be lower than the Reid vapor pressure of the blank. The distillate properties (the initial boiling point IBP and the final boiling point FBP) for the blank, gasoline after treatment with zeolite/Li and zeolite/refinery were not found to change considerably. The blank and the blank after treatment with zeolite/refinery were found to possess the same degree of corrosion (1b) which is the slightly corrosive whereas the blank after treatment with zeolite/Li has a (2c) degree which is moderate corrosive.},
year = {2017}
}
TY - JOUR T1 - Physical Properties Changes Accompanies Treating Gasoline Fraction of Petroleum with Synthetic Zeolite AU - Mutaz Mohamed Ahmed Elshiekh AU - Nazar Abdulaziz Elnasri Y1 - 2017/11/30 PY - 2017 N1 - https://doi.org/10.11648/j.ijbc.20170204.14 DO - 10.11648/j.ijbc.20170204.14 T2 - International Journal of Bioorganic Chemistry JF - International Journal of Bioorganic Chemistry JO - International Journal of Bioorganic Chemistry SP - 180 EP - 184 PB - Science Publishing Group SN - 2578-9392 UR - https://doi.org/10.11648/j.ijbc.20170204.14 AB - The main aim of this work is to study the physical changes in the gasoline portion of the Sudanese petroleum upon treating with synthetic zeolite. Treating gasoline with zeolites usually performed in order to enhance the octane number of the oil. The octane number measures the degree of the gasoline resist to self-ignition prior to combustion. Gasoline with higher octane number has higher tendency to resist self-ignition. Gasoline containing branched and aromatic hydrocarbons resists self-ignition rather than gasoline containing straight chain hydrocarbons. 2,2,4 trimethyl pentane name disooctane (has octane number 100) and n-heptane (has octane number 0) are used to measure the octane number of the oil under the test. Zeolites are frame work of tetrahedral silicates (TO4), with a net negative charge balanced by a positive cation. Zeolite/Li indicating that the Li cation is used to neutralized the frame work. Zeolite/refinery refers to an industrial zeolite brought from Sudanese Petroleum Company. The gasoline portion used before treatment with any zeolites is considered to be a standard and is called a blank. Physical properties (distillation, density, S.G@15OC, Reid vapor pressure and the degree of corrosion) were carried out for the blank, the mixture of zeolite/Li with the gasoline and the mixture of zeolite/refinery with the gasoline. The density of the gasoline after treatment with zeolite/Li was found to be higher than the density of the blank. The Reid vapor pressure of the gasoline after treatment with zeolite/Li was found to be lower than the Reid vapor pressure of the blank. The distillate properties (the initial boiling point IBP and the final boiling point FBP) for the blank, gasoline after treatment with zeolite/Li and zeolite/refinery were not found to change considerably. The blank and the blank after treatment with zeolite/refinery were found to possess the same degree of corrosion (1b) which is the slightly corrosive whereas the blank after treatment with zeolite/Li has a (2c) degree which is moderate corrosive. VL - 2 IS - 4 ER -
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