Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom
International Journal of Photochemistry and Photobiology
Volume 1, Issue 1, June 2017, Pages: 13-20
Received: Sep. 21, 2016; Accepted: Jan. 12, 2017; Published: Mar. 1, 2017
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Authors
Mohammed Anwar Batal, Department of Physics, College of Science, Aleppo University, Aleppo City, Syria
Kaesar Alyamani, Department of Physics, College of Science, Aleppo University, Aleppo City, Syria
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Abstract
Multi layers CdSe artificial atoms system prepared using Spin coating method. Using W-H method, which based on XRD Broading line profile, structural parameters of FTO/CdSe system were calculated. XRD spectrum reveal that CdSe nanoparticles have hexagonal structure, have high strain, show deposition layer on other do more stress and strain (Crystallization size (6.16 A◦), lattice constant C(7.16A◦), effective strain (0.07377 (lin–2 m–4)) between the nano crystals and dislocation (irregular) (26.443×1020 (lin–2 m–4)) were determined), which confirm more later by anther spectroscopic method. By doing fitting between experimental and theoretical absorption using Gaussian profile and Doppler broading line. Different electronic transitions were deduced and other broading curve were studying such as effect of particle size of artificial atoms, with doing more accurate fitting reveals existence of two intensities lines attributed to diffusion layer between FTO and CdSe artificial atoms.
Keywords
CdSe, Artificial Atoms, XRD Broading, Absorption Spectra, Doppler Broading
To cite this article
Mohammed Anwar Batal, Kaesar Alyamani, Broading Spectral Line Method for Determination Structural Parameters and Electronic Transitions in CdSe Artificial Atom, International Journal of Photochemistry and Photobiology. Vol. 1, No. 1, 2017, pp. 13-20. doi: 10.11648/j.ijpp.20170101.13
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Copyright © 2017 Authors retain the copyright of this article.
This article is an open access article distributed under the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
References
[1]
U. Farva, N. T. N. Truong and C. Park “Optoelectronic properties of CdSe nanoparticles and therir application to bulk hetero-junction solar cells” in conference of ieee in june 2009.
[2]
X. Xu, Y. Wang, L. Zhor, L. Wu, J. G. Niu, L. Zhang and Q. Liu: “Synthesis and characterization of CdSe nanocrystals using NaHSeO3 as selenium source” in micro and nanoleters on 22nd april 2012.
[3]
P. K. Khanna: “Synthesis and optical properties of CdSe nanocrystal” Journal of Taylor & Francis in 26 sep 2008.
[4]
W. Xu, Y. Wang, S. Liang, R. Xu, G. Zhang, F. Xu and D. Yin: “Optimized synthesis and fluorescence spectrum analysis of CdSe quamtum dots” Journal of Taylor & Francis in 5 dec 2003.
[5]
Ashfaq M, Khan S, Verma N. Synthesis of PVACAP-based Biomaterial in situ dispersed with Cu nanoparticles and carbon micro-nano fibers for antibiotic drug delivery applications. Biochem Eng J. 2014; 90: 79-89.
[6]
Fernandes AP, Gandin V. Selenium compounds as The rapeutic agents in cancer. Biochim Biophys Acta. 2015; 1850: 1642-60.
[7]
Surana K, Singh PK, Rhee Hee-Woo, Bhattacharya B. Synthesis, characterization and application of CdSe quantum dots. J Ind Eng Chem. 2014; 20: 4188-93.
[8]
Tamaki H, Watanabe H, Kamiyama S, Oaki Y, Imai H. Size-dependent thermochromism through enhanced electron-phonon coupling in 1nm quantum dots. Angew Chem Int Ed Engl. 2014; 53: 10706-9.
[9]
Kenneth M. Goodfellow, Meni Wanunu, Chitraleema Chakraborty, Todd Krauss, Kristina Driscoll, Kelly Sowers, Pradeep Waduge, and A. Nick Vamivakas Distance-dependent energy transfer between CdSe/CdS quantum dots and a two-dimensional semiconductor. APPLIED PHYSICS LETTERS 108, 021101 (2016).
[10]
P. Gupta and M. Ramrakhiani "Influence of the Particle Size on the Optical Properties of CdSe Nanoparticles "The Open Nanoscience Journal, 2009, 3, 15-19.
[11]
ŞABAN MUSTAFA HUŞ. "Physical Properties Of Cdse Thin Films Produced By Thermal Evaporation And E-Beam Techniques" thises, middle east technical university, september 2006
[12]
G. Ramalingam and J. Madhavan “Investigation on the structural and morphological behaviour of CdSe nanoparticles by hydrothermal method” Archives of Applied Science Research, 2011, 3 (3): 217-224.
[13]
Lin-Wang Wang and Alex Zunger “High-Energy Excitonic Transitions in CdSe Quantum Dots “American Chemical Society volume 102, number 34, august 20, 1998.
[14]
A. Ayeshamariam “Synthesis, Structural and Optical Characterizations of SnO2 Nanoparticles” Journal on Photonics and Spintronics” Vol 2 No 2 May 2013.
[15]
N J Suthan Kissinger, M Jayachandran K Perumal And C Sanjeevi Raja ”Structural and optical properties of electron beam evaporated CdSe thin films” Bull. Mater. Sci., Vol. 30, No. 6, December 2007, pp. 547–551.
[16]
G. W. F. Drake “Atomic, Molecular, & Optical Physics Handbook, Chaps. 19 and 57, ed. (AIP, Woodbury, NY, 1996).
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