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Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol

Received: 22 June 2019     Accepted: 15 July 2019     Published: 8 January 2020
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Abstract

Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.

Published in American Journal of Mechanics and Applications (Volume 7, Issue 4)
DOI 10.11648/j.ajma.20190704.12
Page(s) 88-100
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2020. Published by Science Publishing Group

Keywords

Alcohols, Binary Mixtures, Excess Properties, Density, Modeling, Speed of Sound

References
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    Fatemeh Fadaei Nobandegani, Abouzar Roeintan. (2020). Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. American Journal of Mechanics and Applications, 7(4), 88-100. https://doi.org/10.11648/j.ajma.20190704.12

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    ACS Style

    Fatemeh Fadaei Nobandegani; Abouzar Roeintan. Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. Am. J. Mech. Appl. 2020, 7(4), 88-100. doi: 10.11648/j.ajma.20190704.12

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    AMA Style

    Fatemeh Fadaei Nobandegani, Abouzar Roeintan. Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol. Am J Mech Appl. 2020;7(4):88-100. doi: 10.11648/j.ajma.20190704.12

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  • @article{10.11648/j.ajma.20190704.12,
      author = {Fatemeh Fadaei Nobandegani and Abouzar Roeintan},
      title = {Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol},
      journal = {American Journal of Mechanics and Applications},
      volume = {7},
      number = {4},
      pages = {88-100},
      doi = {10.11648/j.ajma.20190704.12},
      url = {https://doi.org/10.11648/j.ajma.20190704.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajma.20190704.12},
      abstract = {Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.},
     year = {2020}
    }
    

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  • TY  - JOUR
    T1  - Volumetric and Ultrasonic Study of Mixtures of Benzyl Alcohol with 1-Propanol, 2-Propanol, and 1,2-Propandiol, 1,3-Propandiol and T-butanol
    AU  - Fatemeh Fadaei Nobandegani
    AU  - Abouzar Roeintan
    Y1  - 2020/01/08
    PY  - 2020
    N1  - https://doi.org/10.11648/j.ajma.20190704.12
    DO  - 10.11648/j.ajma.20190704.12
    T2  - American Journal of Mechanics and Applications
    JF  - American Journal of Mechanics and Applications
    JO  - American Journal of Mechanics and Applications
    SP  - 88
    EP  - 100
    PB  - Science Publishing Group
    SN  - 2376-6131
    UR  - https://doi.org/10.11648/j.ajma.20190704.12
    AB  - Densities and speeds of sound for five binary mixtures of benzylalcohol with 1,3-propandiol, 1- propanol, 2- propanol, 1,2-propandiol and phenylethnol were measured over the entire range of composition and at five temperatures from 298.15K to 323.15K at 5K interval and atmospheric pressure using a vibrating u-tube densimeter (DSA 5000). Besides, the densities for pure compounds in the above-mentioned temperature range were measured. The experimental densities were used to calculate the excess molar volumes, isentropic compressibility changes, the excess thermal expansion coefficients, and the excess partial molar volumes at infinite dilution, The results have been used to discuss the nature and strength of intermolecular interactions in these mixtures. The calculated excess and deviations quantities are correlated with the third-order Redlich–Kister equation. As a final work we modeled the experiment results by using TM and PR EOSs. This is clear that the results with TM EOS are more acceptable than PR EOS. TM and PR EOS can successfully predict density and excess molar volume. And are unable to predict speed of sound.
    VL  - 7
    IS  - 4
    ER  - 

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Author Information
  • Department of Food Science and Thecnology, Fasa University, Fasa, Iran

  • Department of Chemistry, Emam Hossein University, Tehran, Iran

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