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Statistical Analysis of Ozone Weekend Effect in the Largest Cities in Poland

Received: 27 September 2021    Accepted: 26 October 2021    Published: 10 November 2021
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Abstract

This study examines O3, NOx, NO2 and NO data from five large cities in Poland (Warszawa, Kraków, Łódź, Wrocław and Poznań) over a three-year period (2015-2017) to quantify the phenomenon of ozone weekend effect. The seasonal and diurnal variations of O3 and NOx species, showing the interdependence these two gaseous species, were presented. The number of 8-hour running average values above the threshold of 60 ppb and 1-hour above 90 ppb shows that ozone exceeded amounts are more frequent on Saturday and Sunday compared to other days of the week. The analysis of day of the week variations of O3 indicates distinct, temporal pattern with maximum O3 concentrations during weekend (especially on Sunday) and minimum noted on Wednesday, Thursday and Friday (depending on the station). The analysis of existence of the ozone weekend effect was performed on the basis of average O3 concentration at the weekend and on the day of the lowest O3 concentration during the week. Calculations were performed for the period of the whole year and for individual seasons of the year. The results of performance the non-parametric U-Mann-Whitney test indicate that differences of O3 concentration between weekend and a specific day of the week were statistically significant for most cases, despite the significantly lower concentration of ozone precursors (NOx). The analysis of Ox concentrations indicates that limited processes of O3 titration by NO (ozone quenching hypothesis) are the main cause of the ozone weekend effect in the Polish cities.

Published in Earth Sciences (Volume 10, Issue 6)
DOI 10.11648/j.earth.20211006.12
Page(s) 265-274
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Ozone Formation, Ozone Weekend Effect, VOC/NOx Ratio, Nitrogen Oxides

References
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[2] Sadanaga, Y.; Sengen, M.; Takenaka, N.; Bandow, H. Analyses of the Ozone Weekend Effect in Tokyo, Japan: Regime of Oxidant (O3 + NO2) Production. Aerosol and Air Quality Research 2012, 12, 161-168.
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[4] Heuss, J. M.; Kahlbaum, D. F.; Wolff, G. T. Weekday/Weekend Ozone Differences: What Can We Learn from Them? Journal of the Air & Waste Management Association 2003, 53, 772-788.
[5] Cleveland, W. S.; Graedel, T. E.; Kleiner, B.; Warner, J. L. Sunday and workday variations in photochemical air pollutants in New Jersey and New York. Science 1974, 186, 1037-1038.
[6] Wang, Y.; Shen, L.; Wu, S.; Mickley, L.; He, J.; Hao, J. Sensitivity of surface ozone over China to 2000-2050 global changes of climate and emission. Atmospheric Environment 2013, 75, 374-382.
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[19] Song, F.; Shin, J. Y.; Jusino-Atresino, R.; Gao, Y. Relationship among the spring time ground-level NOx, O3 and NO3 in the vicinity of highways in the US East Coast. Atmospheric Pollution Research 2011, 2 (3), 374-383.
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Cite This Article
  • APA Style

    Izabela Pawlak. (2021). Statistical Analysis of Ozone Weekend Effect in the Largest Cities in Poland. Earth Sciences, 10(6), 265-274. https://doi.org/10.11648/j.earth.20211006.12

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    ACS Style

    Izabela Pawlak. Statistical Analysis of Ozone Weekend Effect in the Largest Cities in Poland. Earth Sci. 2021, 10(6), 265-274. doi: 10.11648/j.earth.20211006.12

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    AMA Style

    Izabela Pawlak. Statistical Analysis of Ozone Weekend Effect in the Largest Cities in Poland. Earth Sci. 2021;10(6):265-274. doi: 10.11648/j.earth.20211006.12

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  • @article{10.11648/j.earth.20211006.12,
      author = {Izabela Pawlak},
      title = {Statistical Analysis of Ozone Weekend Effect in the Largest Cities in Poland},
      journal = {Earth Sciences},
      volume = {10},
      number = {6},
      pages = {265-274},
      doi = {10.11648/j.earth.20211006.12},
      url = {https://doi.org/10.11648/j.earth.20211006.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.earth.20211006.12},
      abstract = {This study examines O3, NOx, NO2 and NO data from five large cities in Poland (Warszawa, Kraków, Łódź, Wrocław and Poznań) over a three-year period (2015-2017) to quantify the phenomenon of ozone weekend effect. The seasonal and diurnal variations of O3 and NOx species, showing the interdependence these two gaseous species, were presented. The number of 8-hour running average values above the threshold of 60 ppb and 1-hour above 90 ppb shows that ozone exceeded amounts are more frequent on Saturday and Sunday compared to other days of the week. The analysis of day of the week variations of O3 indicates distinct, temporal pattern with maximum O3 concentrations during weekend (especially on Sunday) and minimum noted on Wednesday, Thursday and Friday (depending on the station). The analysis of existence of the ozone weekend effect was performed on the basis of average O3 concentration at the weekend and on the day of the lowest O3 concentration during the week. Calculations were performed for the period of the whole year and for individual seasons of the year. The results of performance the non-parametric U-Mann-Whitney test indicate that differences of O3 concentration between weekend and a specific day of the week were statistically significant for most cases, despite the significantly lower concentration of ozone precursors (NOx). The analysis of Ox concentrations indicates that limited processes of O3 titration by NO (ozone quenching hypothesis) are the main cause of the ozone weekend effect in the Polish cities.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Statistical Analysis of Ozone Weekend Effect in the Largest Cities in Poland
    AU  - Izabela Pawlak
    Y1  - 2021/11/10
    PY  - 2021
    N1  - https://doi.org/10.11648/j.earth.20211006.12
    DO  - 10.11648/j.earth.20211006.12
    T2  - Earth Sciences
    JF  - Earth Sciences
    JO  - Earth Sciences
    SP  - 265
    EP  - 274
    PB  - Science Publishing Group
    SN  - 2328-5982
    UR  - https://doi.org/10.11648/j.earth.20211006.12
    AB  - This study examines O3, NOx, NO2 and NO data from five large cities in Poland (Warszawa, Kraków, Łódź, Wrocław and Poznań) over a three-year period (2015-2017) to quantify the phenomenon of ozone weekend effect. The seasonal and diurnal variations of O3 and NOx species, showing the interdependence these two gaseous species, were presented. The number of 8-hour running average values above the threshold of 60 ppb and 1-hour above 90 ppb shows that ozone exceeded amounts are more frequent on Saturday and Sunday compared to other days of the week. The analysis of day of the week variations of O3 indicates distinct, temporal pattern with maximum O3 concentrations during weekend (especially on Sunday) and minimum noted on Wednesday, Thursday and Friday (depending on the station). The analysis of existence of the ozone weekend effect was performed on the basis of average O3 concentration at the weekend and on the day of the lowest O3 concentration during the week. Calculations were performed for the period of the whole year and for individual seasons of the year. The results of performance the non-parametric U-Mann-Whitney test indicate that differences of O3 concentration between weekend and a specific day of the week were statistically significant for most cases, despite the significantly lower concentration of ozone precursors (NOx). The analysis of Ox concentrations indicates that limited processes of O3 titration by NO (ozone quenching hypothesis) are the main cause of the ozone weekend effect in the Polish cities.
    VL  - 10
    IS  - 6
    ER  - 

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Author Information
  • Department of Physics of the Atmosphere, Institute of Geophysics Polish Academy of Sciences, Warsaw, Poland

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