Journal of Energy and Natural Resources

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Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Roselle (Hibiscus Sabdariffa) Flowers and Pawpaw (Carica Papaya) Leaves as Sensitizers

Received: 30 January 2016    Accepted: 09 February 2016    Published: 24 February 2016
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Abstract

Dye-sensitized solar cells (DSSCs) were fabricated using natural dyes extracted from roselle flowers and carica papaya leaves extract as photosensitizers. The photovoltaic perfomance of the DSSCs were evaluated under 100 mAcm-2 light intensity. The roselle (Hibiscus Sabdariffa) extract sensitized solar cell gave a short circuit current density (Jsc) of 0.180 mAcm-2, an open circuit voltage (Voc) of 0.470 V, a fill factor (FF) of 0.552, and an overall solar energy conversion efficiency (η) of 0.046%. Also, the pawpaw leaves extract sensitized cell gave a Jsc of 0.094 mAcm-2, Voc of 0.433 V, FF of 0.544 yielding a conversion efficiency of 0.022%. The cell sensitized by the roselle extract shows better sensitization, which was in agreement with the broadest spectrum of the extract adsorbed on TiO2 film. The sensitization performance related to interaction between the dye and TiO2 surface is discussed.

DOI 10.11648/j.jenr.20160501.12
Published in Journal of Energy and Natural Resources (Volume 5, Issue 1, February 2016)
Page(s) 11-15
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

DSSCs, Natural Dyes, Dye Extracts, Sensitization

References
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[3] O'Regan, B. & Grätzel, M. (1991). A low-cost, High-Efficiency Solar Cell Based on Dye-Sensitized Colloidal TiO2 Film. Nature 353, (6346), 737-740.
[4] Nazerruddin, M. K., Kay, A., Ridicio, I., Humphry-Baker, R., Mueller, E., Liska, P., Vlachopoulos, N. & Gratzel, M. (1993). J. Conversion of Light to Electricity on Nanocrystalline TiO2 Electrodes. Journal of the American Chemical Society, 115, 6382-6390.
[5] Hernandez-Martinez, A. R., Estevez, M., Vargas, S., Quintanilla, F., & Rodriguez, R. (2011). New Dye-Sensitized Solar Cells Obtained from Extracted Bracts of Bougainvillea Glabra and Spectabilis Betalain Pigments by Different Purification Processes. International Journal of Molecular Science, 12, 5565-5576.
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[7] Calogero, G. & Marco, G.D. (2008). Red Sicilian Orange and Purple Eggplant Fruits as Natural Sensitizers for Dye- Sensitized Solar Cells. Solar Energy Materials Solar Cells, 92(11), 1341-1346.
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[9] Tennakone, K., Kumara, G. R. R. A., Kumarasinghe, A. R., Sirimanne, P. M. & Wijayantha, K. G. U. (1996). Efficient Pho- tosensitization of Nanocrystalline TiO2 Films by Tannins and Related Phenolic Substances. Journal of Photo- chemistry & Photobiology A: Chemistry, 94(2-3), 1996, 217-220.
[10] Zhang, D., Lanier, S. M., Downing, J. A., Avent, J. L., Lumc, J., & McHale, J. L. (2008). Betalain Pigments for Dye- Sensitized Solar Cells. Journal of Photochemistry Photo- biology A: Chemistry, 195(1), 2008, 72-80.
[11] Rossetto, M., Vanzani, P., Mattivi, F., Lunelli, M., Scarpa, M. & Rigo, A. (2002). Synergistic Antioxidant Effect of Catechin and Malvidin 3-Glucoside on Free Radical-Ini- tiated Peroxidation of Linoleic Acid in Micelles. Archives of Biochemistry and Biophysics, 408(2), 239-245.
[12] Frank, T., Janssen, M., Netzel, M., Strass, G., Kler, A., Kriesl, E., & Bitsch, I (2005). Pharmacokinetics of anthocyanins-3-glycosides following consumption of Hibiscus sabdariffa L. extract. The Journal of Clinical Pharmacology, 45(2), 203-210
[13] Terahara, N., Saito, N., Honda, T., Toki, K. & Y. Osajima, (1990). Further structural elucidation of the anthocyanin, deacylternatin, from Clitoria ternatea. Phytochemistry, 29(11), 3686-3687.
[14] Hammadi, O. A., & Naji, N. I. (2014). Effect of Acidic Environment on the Spectral Properties of Hibiscus sabdariffa Organic Dye used in Dye-Sensitized Solar Cells. Iraqi journal of applied physics, 10(2), 27-31.
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[16] Martineau, D. (2012). Dye solar cells for real, http://creativecommons.org/licenses/by-nc-sa/3.0/
[17] Mphande, B.C., & Pogrebnoi, A. (2015). Outdoor Photoelectrochemical Characterization of Dyes from Acalypha wilkesiana ‘Haleakala’ and Hibiscus sabdariffa as Dye Solar Cells Sensitizers. British Journal of Applied Science & Technology, 7(2), 195-204.
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[19] Wongcharee, K., Meeyoo, V., & Chavadej, S. (2007). Dye-Sensitized Solar Cell Using Natural Dyes Extracted from Rosella and Blue Pea Flowers. Solar Energy Material Solar Cells, 91(7), 566-571.
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Author Information
  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

  • Department of Physics, Kaduna State University, Kaduna, Nigeria

  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

  • Department of Agricultural Science, Kaduna State University, Kaduna, Nigeria

  • Department of Physics, Nigerian Defence Academy, Kaduna, Nigeria

  • Department of Physics, Kaduna State University, Kaduna, Nigeria

Cite This Article
  • APA Style

    Eli Danladi, Muhammad Sani Ahmad, Maxwell Idodo, Ezra Bako Danladi, Francis Aungwa, et al. (2016). Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Roselle (Hibiscus Sabdariffa) Flowers and Pawpaw (Carica Papaya) Leaves as Sensitizers. Journal of Energy and Natural Resources, 5(1), 11-15. https://doi.org/10.11648/j.jenr.20160501.12

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    ACS Style

    Eli Danladi; Muhammad Sani Ahmad; Maxwell Idodo; Ezra Bako Danladi; Francis Aungwa, et al. Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Roselle (Hibiscus Sabdariffa) Flowers and Pawpaw (Carica Papaya) Leaves as Sensitizers. J. Energy Nat. Resour. 2016, 5(1), 11-15. doi: 10.11648/j.jenr.20160501.12

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    AMA Style

    Eli Danladi, Muhammad Sani Ahmad, Maxwell Idodo, Ezra Bako Danladi, Francis Aungwa, et al. Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Roselle (Hibiscus Sabdariffa) Flowers and Pawpaw (Carica Papaya) Leaves as Sensitizers. J Energy Nat Resour. 2016;5(1):11-15. doi: 10.11648/j.jenr.20160501.12

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  • @article{10.11648/j.jenr.20160501.12,
      author = {Eli Danladi and Muhammad Sani Ahmad and Maxwell Idodo and Ezra Bako Danladi and Francis Aungwa and Sunday Habila Sarki},
      title = {Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Roselle (Hibiscus Sabdariffa) Flowers and Pawpaw (Carica Papaya) Leaves as Sensitizers},
      journal = {Journal of Energy and Natural Resources},
      volume = {5},
      number = {1},
      pages = {11-15},
      doi = {10.11648/j.jenr.20160501.12},
      url = {https://doi.org/10.11648/j.jenr.20160501.12},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.jenr.20160501.12},
      abstract = {Dye-sensitized solar cells (DSSCs) were fabricated using natural dyes extracted from roselle flowers and carica papaya leaves extract as photosensitizers. The photovoltaic perfomance of the DSSCs were evaluated under 100 mAcm-2 light intensity. The roselle (Hibiscus Sabdariffa) extract sensitized solar cell gave a short circuit current density (Jsc) of 0.180 mAcm-2, an open circuit voltage (Voc) of 0.470 V, a fill factor (FF) of 0.552, and an overall solar energy conversion efficiency (η) of 0.046%. Also, the pawpaw leaves extract sensitized cell gave a Jsc of 0.094 mAcm-2, Voc of 0.433 V, FF of 0.544 yielding a conversion efficiency of 0.022%. The cell sensitized by the roselle extract shows better sensitization, which was in agreement with the broadest spectrum of the extract adsorbed on TiO2 film. The sensitization performance related to interaction between the dye and TiO2 surface is discussed.},
     year = {2016}
    }
    

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  • TY  - JOUR
    T1  - Dye-Sensitized Solar Cells Using Natural Dyes Extracted from Roselle (Hibiscus Sabdariffa) Flowers and Pawpaw (Carica Papaya) Leaves as Sensitizers
    AU  - Eli Danladi
    AU  - Muhammad Sani Ahmad
    AU  - Maxwell Idodo
    AU  - Ezra Bako Danladi
    AU  - Francis Aungwa
    AU  - Sunday Habila Sarki
    Y1  - 2016/02/24
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    DO  - 10.11648/j.jenr.20160501.12
    T2  - Journal of Energy and Natural Resources
    JF  - Journal of Energy and Natural Resources
    JO  - Journal of Energy and Natural Resources
    SP  - 11
    EP  - 15
    PB  - Science Publishing Group
    SN  - 2330-7404
    UR  - https://doi.org/10.11648/j.jenr.20160501.12
    AB  - Dye-sensitized solar cells (DSSCs) were fabricated using natural dyes extracted from roselle flowers and carica papaya leaves extract as photosensitizers. The photovoltaic perfomance of the DSSCs were evaluated under 100 mAcm-2 light intensity. The roselle (Hibiscus Sabdariffa) extract sensitized solar cell gave a short circuit current density (Jsc) of 0.180 mAcm-2, an open circuit voltage (Voc) of 0.470 V, a fill factor (FF) of 0.552, and an overall solar energy conversion efficiency (η) of 0.046%. Also, the pawpaw leaves extract sensitized cell gave a Jsc of 0.094 mAcm-2, Voc of 0.433 V, FF of 0.544 yielding a conversion efficiency of 0.022%. The cell sensitized by the roselle extract shows better sensitization, which was in agreement with the broadest spectrum of the extract adsorbed on TiO2 film. The sensitization performance related to interaction between the dye and TiO2 surface is discussed.
    VL  - 5
    IS  - 1
    ER  - 

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