Metal corrosion phenomenon is an important topic in many industries because of its consequences on industrial equipment. The purpose of this study was to investigate the inhibition potential of three vitamins on aluminum corrosion in 1M HCl using experimental and theoretical techniques. So, the inhibitive effect of three vitamins that are vitamin B1, B3 and B6 on aluminium corrosion in 1M hydrochloric acid solution was studied by gravimetric techniques and quantum chemical method based on density functional theory (DFT). Gravimetric proved that these compounds are excellent inhibitors in tested solution. Vitamins adsorption on aluminium surface obeys to modified Langmuir model or Villamil model. Thermodynamic adsorption parameters were determined and discussed. Kinetic study of aluminum dissolution in absence or presence of each inhibitor indicates that the addition of each vitamin in corrosive solution does not change dissolution reaction order which is zero order. Finally, it was found that quantum chemical and experimental calculations correlate and indicated that inhibition effect of investigated molecules is strongly related to EHOMO, ELUMO, and energy gap (DE).
| Published in | American Journal of Applied Chemistry (Volume 10, Issue 5) |
| DOI | 10.11648/j.ajac.20221005.12 |
| Page(s) | 120-128 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Vitamins, Aluminium, Gravimetric, Hydrochloric Acid, Density Functional Theory
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APA Style
Mamadou Yeo, Mougo Andre Tigori, M’Bouille Cisse, Paulin Marius Niamien. (2022). Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution. American Journal of Applied Chemistry, 10(5), 120-128. https://doi.org/10.11648/j.ajac.20221005.12
ACS Style
Mamadou Yeo; Mougo Andre Tigori; M’Bouille Cisse; Paulin Marius Niamien. Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution. Am. J. Appl. Chem. 2022, 10(5), 120-128. doi: 10.11648/j.ajac.20221005.12
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Download@article{10.11648/j.ajac.20221005.12,
author = {Mamadou Yeo and Mougo Andre Tigori and M’Bouille Cisse and Paulin Marius Niamien},
title = {Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution},
journal = {American Journal of Applied Chemistry},
volume = {10},
number = {5},
pages = {120-128},
doi = {10.11648/j.ajac.20221005.12},
url = {https://doi.org/10.11648/j.ajac.20221005.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20221005.12},
abstract = {Metal corrosion phenomenon is an important topic in many industries because of its consequences on industrial equipment. The purpose of this study was to investigate the inhibition potential of three vitamins on aluminum corrosion in 1M HCl using experimental and theoretical techniques. So, the inhibitive effect of three vitamins that are vitamin B1, B3 and B6 on aluminium corrosion in 1M hydrochloric acid solution was studied by gravimetric techniques and quantum chemical method based on density functional theory (DFT). Gravimetric proved that these compounds are excellent inhibitors in tested solution. Vitamins adsorption on aluminium surface obeys to modified Langmuir model or Villamil model. Thermodynamic adsorption parameters were determined and discussed. Kinetic study of aluminum dissolution in absence or presence of each inhibitor indicates that the addition of each vitamin in corrosive solution does not change dissolution reaction order which is zero order. Finally, it was found that quantum chemical and experimental calculations correlate and indicated that inhibition effect of investigated molecules is strongly related to EHOMO, ELUMO, and energy gap (DE).},
year = {2022}
}
TY - JOUR T1 - Experimental Aspect and Theoretical Modelling of Aluminium Inhibition Corrosion by Vitamins B1, B3 and B6 in Chloric Acid Solution AU - Mamadou Yeo AU - Mougo Andre Tigori AU - M’Bouille Cisse AU - Paulin Marius Niamien Y1 - 2022/09/26 PY - 2022 N1 - https://doi.org/10.11648/j.ajac.20221005.12 DO - 10.11648/j.ajac.20221005.12 T2 - American Journal of Applied Chemistry JF - American Journal of Applied Chemistry JO - American Journal of Applied Chemistry SP - 120 EP - 128 PB - Science Publishing Group SN - 2330-8745 UR - https://doi.org/10.11648/j.ajac.20221005.12 AB - Metal corrosion phenomenon is an important topic in many industries because of its consequences on industrial equipment. The purpose of this study was to investigate the inhibition potential of three vitamins on aluminum corrosion in 1M HCl using experimental and theoretical techniques. So, the inhibitive effect of three vitamins that are vitamin B1, B3 and B6 on aluminium corrosion in 1M hydrochloric acid solution was studied by gravimetric techniques and quantum chemical method based on density functional theory (DFT). Gravimetric proved that these compounds are excellent inhibitors in tested solution. Vitamins adsorption on aluminium surface obeys to modified Langmuir model or Villamil model. Thermodynamic adsorption parameters were determined and discussed. Kinetic study of aluminum dissolution in absence or presence of each inhibitor indicates that the addition of each vitamin in corrosive solution does not change dissolution reaction order which is zero order. Finally, it was found that quantum chemical and experimental calculations correlate and indicated that inhibition effect of investigated molecules is strongly related to EHOMO, ELUMO, and energy gap (DE). VL - 10 IS - 5 ER -
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