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Generation and Storage of Hydrogen Gas from Non-metal and Metal Hydrides Using Metal Complex Catalysts: A Review

Received: 10 February 2022    Accepted: 1 March 2022    Published: 12 March 2022
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Abstract

Sustainable renewable and environmentally friendly sources of fuel are in high demand. Hydrogen fuel appears to be the best energy source that is sustainable, renewable and environmentally friendly. In order to change the fossil fuel driven world economy to climate friendly hydrogen fuel driven economy, there is an urgent need for large scale development of new infrastructures and technologies to generate and store hydrogen. Pollution free hydrogen gas is the energy of the future. The application of hydrogen fuel in mobile machineries requires that hydrogen is stored in compact and lightweight systems. The storage of hydrogen in solid state has many advantages compared to compressed gas or cryogenic liquid in volumetric terms. The difficult with solid state hydrogen storage is that metal hydrides tend to release hydrogen at or above 90°C. The most critical component to the development of a hydrogen driven economy is elucidation of materials with efficient hydrogenation/dehydrogenation kinetics at a reduced operational temperature. This is possible with improvements in development of alloys and catalysts. By using advanced computer modelling for possible hydrogen storage complex metals, it is possible to develop a special type of a hydride metal complex that allows absorption and desorption of hydrogen at a much lower temperature for mobile application. Such a metal complex can allow development of hydrogen fueled automobiles and cheap large-scale application of hydrogen in generation of electricity for sustainable development worldwide, quickly replacing nuclear energy and fossil fuels. This paper identifies current difficulties that need to be overcome for hydrogen driven economy to be realized and proposes practical solutions.

Published in International Journal of Sustainable and Green Energy (Volume 11, Issue 1)
DOI 10.11648/j.ijrse.20221101.14
Page(s) 29-34
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Hydrides, Hydrogen Storage, Hydrogen Gas, Complex Metal Hydrides, Non-metal Hydrides

References
[1] Paraschiv, S. and Paraschiv, L. S. (2020). Trends of carbon dioxide (CO2) emissions from fossil fuels combustion (coal, gas and oil) in the EU member states from 1960 to 2018. Energy Reports, 6 (8), 237-242.
[2] Pingkuo, L. and Xue, H. (2022). Comparative analysis on similarities and differences of hydrogen energy development in the World's top 4 largest economies: A novel framework. International Journal of Hydrogen Energy, 47 (16): 9485-9503.
[3] Singla, M. K., Nijhawan, P., & Oberoi, A. S. (2021). Hydrogen fuel and fuel cell technology for cleaner future: a review. Environmental science and pollution research international, 28 (13), 15607–15626. https://doi.org/10.1007/s11356-020-12231-8
[4] Kahn Ribeiro, S., Kobayashi, S., Beuthe, M., Gasca, J., Greene, D., Lee, D. Muromachi, Y., Newton, P. J., Plotkin, S., Sperling, D., Wit, R. and Zhou, P. J. (2007). Transport and its infrastructure. In Climate Change 2007: Mitigation. Contribution of Working Group III to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change [B. Metz, O.R. Davidson, P.R. Bosch, R. Dave, L.A. Meyer (eds)], Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA.
[5] Sommer A. (2016). Burning Fossil Fuels: Impact of Climate Change on Health. International journal of health services: planning, administration, evaluation, 46 (1), 48–52. https://doi.org/10.1177/0020731415625253
[6] Zhao, Z., Chen, C., Liu, Z., Huang, J., Wu, M., Liu, H., Li, Y., and Huang, Y. (2019). Pt-Based Nanocrystal for Electrocatalytic Oxygen Reduction. Advanced materials (Deerfield Beach, Fla.), 31 (31), e1808115. https://doi.org/10.1002/adma.201808115
[7] Singla, S., Shetti, N. P., Basu, S., Mondal, K., & Aminabhavi, T. M. (2022). Hydrogen production technologies - Membrane based separation, storage and challenges. Journal of environmental management, 302 (Pt A), 113963. https://doi.org/10.1016/j.jenvman.2021.113963
[8] Bellosta von Colbe, J., Ares, J. R., Barale, J., Baricco, M., Buckley, C., Capurso, G.,… Dornheim, M. (2019). Application of hydrides in hydrogen storage and compression: achievements, outlook and perspectives. International Journal of Hydrogen Energy, 44 (15), 7780-7808. https://doi.org/10.1016/j.ijhydene.2019.01.104
[9] He, T., Cao, H., and Chen, P. (2019). Complex Hydrides for Energy Storage, Conversion, and Utilization. Advanced materials (Deerfield Beach, Fla.), 31 (50), e1902757. https://doi.org/10.1002/adma.201902757
[10] Ji, C., Wu, D., Lu, J., Shan, C., Ren, Y., Li, T., Lv, L., Pan, B., & Zhang, W. (2021). Temperature regulated adsorption and desorption of heavy metals to A-MIL-121: Mechanisms and the role of exchangeable protons. Water research, 189, 116599. https://doi.org/10.1016/j.watres.2020.116599
[11] Zhang, G., Zhang, J., & Xie, T. (2020). A solution to renewable hydrogen economy for fuel cell buses - A case study for Zhangjiakou in North China. International journal of hydrogen energy, 45 (29), 14603–14613. https://doi.org/10.1016/j.ijhydene.2020.03.206
[12] Thomas, J. M., Edwards, P. P., Dobson, P. J., & Owen, G. P. (2020). Decarbonising energy: The developing international activity in hydrogen technologies and fuel cells. Journal of energy chemistry, 51, 405–415. https://doi.org/10.1016/j.jechem.2020.03.087
[13] Filonenko, G. A., van Putten, R., Hensen, E. J. M. and Pidko, E. A. (2018). Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field. Chem. Soc. Rev., 47, 1459-1483.
[14] Castrillo, L., Romero, L., Rupérez, M. and Correas, L. (2010). Design of a Metal Hydride. in 18th World Hydrogen Energy Conference 2010 - WHEC 2010: Parallel Sessions Book 4: Storage Systems / Policy Perspectives, Initiatives and Cooperations / Detlef Stolten, Thomas Grube (Ed.) Forschungszentrum Jülich GmbH, Zentralbibliothek, Verlag: 2010; WHEC, May 16.-21. Essen; 73. http://hdl.handle.net/2128/4076
[15] Pedicini R. (2022). Special Issue "Hydrogen Storage and Fuel Cells: Materials, Characterization and Applications". Materials (Basel, Switzerland), 15 (2), 423. https://doi.org/10.3390/ma15020423
[16] Westerwaal, R.J. and Haije, W.G. (2008). Evaluation solid-state hydrogen storage systems, current status ECN-E-08-043 (2008), 74. http://resolver.tudelft.nl/uuid:2d9248e4-a37b-4b73-8572-df00db6c8f22
[17] Zore, U. K., Yedire, S. G., Pandi, N., Manickam, S., & Sonawane, S. H. (2021). A review on recent advances in hydrogen energy, fuel cell, biofuel and fuel refining via ultrasound process intensification. Ultrasonics sonochemistry, 73, 105536. https://doi.org/10.1016/j.ultsonch.2021.105536
[18] Velandia Vargas, J. E., & Seabra, J. (2021). Fuel-cell technologies for private vehicles in Brazil: Environmental mirage or prospective romance? A comparative life cycle assessment of PEMFC and SOFC light-duty vehicles. The Science of the total environment, 798, 149265. https://doi.org/10.1016/j.scitotenv.2021.149265
[19] Møller, K. T., Sheppard, D., Ravnsbæk, D. B., Buckley, C. E., Akiba, E., Li, H. W., & Jensen, T. R. (2017). Complex metal hydrides for hydrogen, thermal and electrochemical energy storage. Energies, 10 (10), 1645.
[20] Baran, A., and Polański, M. (2020). Magnesium-Based Materials for Hydrogen Storage-A Scope Review. Materials (Basel, Switzerland), 13 (18), 3993. https://doi.org/10.3390/ma13183993
[21] Von Colbe, J. B., Ares, J. R., Barale, J., Baricco, M., Buckley, C., Capurso, G.,... & Dornheim, M. (2019). Application of hydrides in hydrogen storage and compression: Achievements, outlook and perspectives. international journal of hydrogen energy, 44 (15), 7780-7808.
[22] Wang, Y., Yuan, H., Martinez, A., Hong, P., Xu, H. and Bockmiller, F. R. (2021). Polymer electrolyte membrane fuel cell and hydrogen station networks for automobiles: Status, technology, and perspectives. Advances in Applied Energy, 2, 100011, https://doi.org/10.1016/j.adapen.2021.100011.
[23] Sürer, M. G., & Arat, H. T. (2022). Advancements and current technologies on hydrogen fuel cell applications for marine vehicles. International Journal of Hydrogen Energy.
[24] Lakhnik, A. M., Kirian, I. M., & Rud, A. D. (2022). The Mg/MAX-phase composite for hydrogen storage. International Journal of Hydrogen Energy, 47 (11), 7274-7280.
[25] Lu, X., Zhang, L., Zheng, J., & Yu, X. (2022). Construction of carbon covered Mg2NiH4 nanocrystalline for hydrogen storage. Journal of Alloys and Compounds, 164169.
Cite This Article
  • APA Style

    Given Kalonga, Adrian Habanyama, Ned Silavwe, Rodrick Symon Katete. (2022). Generation and Storage of Hydrogen Gas from Non-metal and Metal Hydrides Using Metal Complex Catalysts: A Review. International Journal of Sustainable and Green Energy, 11(1), 29-34. https://doi.org/10.11648/j.ijrse.20221101.14

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    ACS Style

    Given Kalonga; Adrian Habanyama; Ned Silavwe; Rodrick Symon Katete. Generation and Storage of Hydrogen Gas from Non-metal and Metal Hydrides Using Metal Complex Catalysts: A Review. Int. J. Sustain. Green Energy 2022, 11(1), 29-34. doi: 10.11648/j.ijrse.20221101.14

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    AMA Style

    Given Kalonga, Adrian Habanyama, Ned Silavwe, Rodrick Symon Katete. Generation and Storage of Hydrogen Gas from Non-metal and Metal Hydrides Using Metal Complex Catalysts: A Review. Int J Sustain Green Energy. 2022;11(1):29-34. doi: 10.11648/j.ijrse.20221101.14

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  • @article{10.11648/j.ijrse.20221101.14,
      author = {Given Kalonga and Adrian Habanyama and Ned Silavwe and Rodrick Symon Katete},
      title = {Generation and Storage of Hydrogen Gas from Non-metal and Metal Hydrides Using Metal Complex Catalysts: A Review},
      journal = {International Journal of Sustainable and Green Energy},
      volume = {11},
      number = {1},
      pages = {29-34},
      doi = {10.11648/j.ijrse.20221101.14},
      url = {https://doi.org/10.11648/j.ijrse.20221101.14},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijrse.20221101.14},
      abstract = {Sustainable renewable and environmentally friendly sources of fuel are in high demand. Hydrogen fuel appears to be the best energy source that is sustainable, renewable and environmentally friendly. In order to change the fossil fuel driven world economy to climate friendly hydrogen fuel driven economy, there is an urgent need for large scale development of new infrastructures and technologies to generate and store hydrogen. Pollution free hydrogen gas is the energy of the future. The application of hydrogen fuel in mobile machineries requires that hydrogen is stored in compact and lightweight systems. The storage of hydrogen in solid state has many advantages compared to compressed gas or cryogenic liquid in volumetric terms. The difficult with solid state hydrogen storage is that metal hydrides tend to release hydrogen at or above 90°C. The most critical component to the development of a hydrogen driven economy is elucidation of materials with efficient hydrogenation/dehydrogenation kinetics at a reduced operational temperature. This is possible with improvements in development of alloys and catalysts. By using advanced computer modelling for possible hydrogen storage complex metals, it is possible to develop a special type of a hydride metal complex that allows absorption and desorption of hydrogen at a much lower temperature for mobile application. Such a metal complex can allow development of hydrogen fueled automobiles and cheap large-scale application of hydrogen in generation of electricity for sustainable development worldwide, quickly replacing nuclear energy and fossil fuels. This paper identifies current difficulties that need to be overcome for hydrogen driven economy to be realized and proposes practical solutions.},
     year = {2022}
    }
    

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  • TY  - JOUR
    T1  - Generation and Storage of Hydrogen Gas from Non-metal and Metal Hydrides Using Metal Complex Catalysts: A Review
    AU  - Given Kalonga
    AU  - Adrian Habanyama
    AU  - Ned Silavwe
    AU  - Rodrick Symon Katete
    Y1  - 2022/03/12
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    N1  - https://doi.org/10.11648/j.ijrse.20221101.14
    DO  - 10.11648/j.ijrse.20221101.14
    T2  - International Journal of Sustainable and Green Energy
    JF  - International Journal of Sustainable and Green Energy
    JO  - International Journal of Sustainable and Green Energy
    SP  - 29
    EP  - 34
    PB  - Science Publishing Group
    SN  - 2575-1549
    UR  - https://doi.org/10.11648/j.ijrse.20221101.14
    AB  - Sustainable renewable and environmentally friendly sources of fuel are in high demand. Hydrogen fuel appears to be the best energy source that is sustainable, renewable and environmentally friendly. In order to change the fossil fuel driven world economy to climate friendly hydrogen fuel driven economy, there is an urgent need for large scale development of new infrastructures and technologies to generate and store hydrogen. Pollution free hydrogen gas is the energy of the future. The application of hydrogen fuel in mobile machineries requires that hydrogen is stored in compact and lightweight systems. The storage of hydrogen in solid state has many advantages compared to compressed gas or cryogenic liquid in volumetric terms. The difficult with solid state hydrogen storage is that metal hydrides tend to release hydrogen at or above 90°C. The most critical component to the development of a hydrogen driven economy is elucidation of materials with efficient hydrogenation/dehydrogenation kinetics at a reduced operational temperature. This is possible with improvements in development of alloys and catalysts. By using advanced computer modelling for possible hydrogen storage complex metals, it is possible to develop a special type of a hydride metal complex that allows absorption and desorption of hydrogen at a much lower temperature for mobile application. Such a metal complex can allow development of hydrogen fueled automobiles and cheap large-scale application of hydrogen in generation of electricity for sustainable development worldwide, quickly replacing nuclear energy and fossil fuels. This paper identifies current difficulties that need to be overcome for hydrogen driven economy to be realized and proposes practical solutions.
    VL  - 11
    IS  - 1
    ER  - 

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Author Information
  • Department of Physics, School of Mathematics and Natural Science, Copperbelt University, Kitwe, Zambia

  • Department of Physics, School of Mathematics and Natural Science, Copperbelt University, Kitwe, Zambia

  • Department of Chemistry, School of Mathematics and Natural Science, Mukuba University, Kitwe, Zambia

  • Department of Biological Sciences, School of Mathematics and Natural Science, Mukuba University, Kitwe, Zambia

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