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The Potentials of Reaction Parameters on Rhynchophorus Phoenicis Nano-Catalysts Based Biodiesel Production from Waste Material Feedstocks

Received: 17 May 2023    Accepted: 5 June 2023    Published: 15 June 2023
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Abstract

Heterogeneous catalysts are known to improve the trans-esterification Process in biodiesel production by eliminating the extra processing costs involved in homogeneous catalysis, as well as reducing the generation of pollutants. Heterogeneous catalysts promote easy recovery, reusability and a cost-effective green process. These catalysts tolerate high FFA and moisture content. In this research the trans-esterification process was used to produce biodiesel from Carica papaya (pawpaw) and Citrullus lanatus (water melon) seed oil. To improve biodiesel performance, an alumina-chitosan nanocomposite a heterogeneous catalyst synthesized from hard shell of Rhynchophorus phoenicis using standard methods was compare to biodiesel production using a homogeneous catalyst potassium hydroxide (KOH). Reaction parameters (reaction temperature and reaction time) were used for optimization of biodiesel production. The average values obtained for effect of time ranged from 42.30±0.20-63.10±1.30%, 49.30±1.50-64.70±1.00%, 71.40±0.70-79.80±0.20%, 80.46±0.20-97.10±0.30%, 81.20±1.20-86.10±1.60% and 79.39±0.40-83.90±0.50% for 30 minutes, 60 minutes, 90 minutes, 120 minutes, 150 minutes and 180 minutes respectively. Variation of temperature for the production of biodiesel from Carica papaya and Citrullus lanatus seed oil with KOH and Nanocomposite catalyst range from 63.09±0.60-95.20±1.55, 49.10±0.45-79.30±0.75, 66.00±1.00-97.10±0.45 and 59.20±0.95-83.40±0.85% for 40, 45, 50, 60, 80 and 90°C respectively. The optimum conditions for the trans=esterification process were 80°C reaction temperature, and 120 minutes reaction time.

Published in Journal of Energy, Environmental & Chemical Engineering (Volume 8, Issue 2)
DOI 10.11648/j.jeece.20230802.12
Page(s) 40-44
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Reaction Parameter, Biocatalyst, Ethyl Ether, Seed Oil

References
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[7] Xie, W., & Wang, J. (2012). Immobilized lipase on magnetic chitosan microspheres for transesterification of soybean oil. Biomass and Bioenergy, 36, 373-380.
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[9] Gardy, J., Hassanpour, A., Lai, X., Ahmed, M. H., and Rehan, M. (2017). Applied catalysis B: environmental biodiesel production from used cooking oil using a novel surface functionalised TiO2 nano-catalyst. Appl. Catal. B Environ. 207, 297–310. doi: 10.1016/j.apcatb.2017.01.080.
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[13] Mohadi, R. (2015). Synthesis of Nanocomposite Chitosan-TiO2 and Its Application as Photodegradation Agent Of Methilen Blue In Aqueous Medium. SYNTHESIS OF NANOCOMPOSITE CHITOSAN-TiO2 AND ITS APPLICATION AS PHOTODEGRADATION AGENT OF METHILEN BLUE IN AQUEOUS MEDIUM, 20.
[14] Fatimah, I., Rubiyanto, D., Taushiyah, A., Najah, F. B., Azmi, U., & Sim, Y. L. (2019). Use of ZrO2 supported on bamboo leaf ash as a heterogeneous catalyst in microwave-assisted biodiesel conversion. Sustainable Chemistry and Pharmacy, 12, 100129.
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    Owhonda Juliet Nkeiru, Charles Ikenna Osu, Gordian Obute. (2023). The Potentials of Reaction Parameters on Rhynchophorus Phoenicis Nano-Catalysts Based Biodiesel Production from Waste Material Feedstocks. Journal of Energy, Environmental & Chemical Engineering, 8(2), 40-44. https://doi.org/10.11648/j.jeece.20230802.12

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    ACS Style

    Owhonda Juliet Nkeiru; Charles Ikenna Osu; Gordian Obute. The Potentials of Reaction Parameters on Rhynchophorus Phoenicis Nano-Catalysts Based Biodiesel Production from Waste Material Feedstocks. J. Energy Environ. Chem. Eng. 2023, 8(2), 40-44. doi: 10.11648/j.jeece.20230802.12

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    AMA Style

    Owhonda Juliet Nkeiru, Charles Ikenna Osu, Gordian Obute. The Potentials of Reaction Parameters on Rhynchophorus Phoenicis Nano-Catalysts Based Biodiesel Production from Waste Material Feedstocks. J Energy Environ Chem Eng. 2023;8(2):40-44. doi: 10.11648/j.jeece.20230802.12

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  • @article{10.11648/j.jeece.20230802.12,
      author = {Owhonda Juliet Nkeiru and Charles Ikenna Osu and Gordian Obute},
      title = {The Potentials of Reaction Parameters on Rhynchophorus Phoenicis Nano-Catalysts Based Biodiesel Production from Waste Material Feedstocks},
      journal = {Journal of Energy, Environmental & Chemical Engineering},
      volume = {8},
      number = {2},
      pages = {40-44},
      doi = {10.11648/j.jeece.20230802.12},
      url = {https://doi.org/10.11648/j.jeece.20230802.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20230802.12},
      abstract = {Heterogeneous catalysts are known to improve the trans-esterification Process in biodiesel production by eliminating the extra processing costs involved in homogeneous catalysis, as well as reducing the generation of pollutants. Heterogeneous catalysts promote easy recovery, reusability and a cost-effective green process. These catalysts tolerate high FFA and moisture content. In this research the trans-esterification process was used to produce biodiesel from Carica papaya (pawpaw) and Citrullus lanatus (water melon) seed oil. To improve biodiesel performance, an alumina-chitosan nanocomposite a heterogeneous catalyst synthesized from hard shell of Rhynchophorus phoenicis using standard methods was compare to biodiesel production using a homogeneous catalyst potassium hydroxide (KOH). Reaction parameters (reaction temperature and reaction time) were used for optimization of biodiesel production. The average values obtained for effect of time ranged from 42.30±0.20-63.10±1.30%, 49.30±1.50-64.70±1.00%, 71.40±0.70-79.80±0.20%, 80.46±0.20-97.10±0.30%, 81.20±1.20-86.10±1.60% and 79.39±0.40-83.90±0.50% for 30 minutes, 60 minutes, 90 minutes, 120 minutes, 150 minutes and 180 minutes respectively. Variation of temperature for the production of biodiesel from Carica papaya and Citrullus lanatus seed oil with KOH and Nanocomposite catalyst range from 63.09±0.60-95.20±1.55, 49.10±0.45-79.30±0.75, 66.00±1.00-97.10±0.45 and 59.20±0.95-83.40±0.85% for 40, 45, 50, 60, 80 and 90°C respectively. The optimum conditions for the trans=esterification process were 80°C reaction temperature, and 120 minutes reaction time.},
     year = {2023}
    }
    

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  • TY  - JOUR
    T1  - The Potentials of Reaction Parameters on Rhynchophorus Phoenicis Nano-Catalysts Based Biodiesel Production from Waste Material Feedstocks
    AU  - Owhonda Juliet Nkeiru
    AU  - Charles Ikenna Osu
    AU  - Gordian Obute
    Y1  - 2023/06/15
    PY  - 2023
    N1  - https://doi.org/10.11648/j.jeece.20230802.12
    DO  - 10.11648/j.jeece.20230802.12
    T2  - Journal of Energy, Environmental & Chemical Engineering
    JF  - Journal of Energy, Environmental & Chemical Engineering
    JO  - Journal of Energy, Environmental & Chemical Engineering
    SP  - 40
    EP  - 44
    PB  - Science Publishing Group
    SN  - 2637-434X
    UR  - https://doi.org/10.11648/j.jeece.20230802.12
    AB  - Heterogeneous catalysts are known to improve the trans-esterification Process in biodiesel production by eliminating the extra processing costs involved in homogeneous catalysis, as well as reducing the generation of pollutants. Heterogeneous catalysts promote easy recovery, reusability and a cost-effective green process. These catalysts tolerate high FFA and moisture content. In this research the trans-esterification process was used to produce biodiesel from Carica papaya (pawpaw) and Citrullus lanatus (water melon) seed oil. To improve biodiesel performance, an alumina-chitosan nanocomposite a heterogeneous catalyst synthesized from hard shell of Rhynchophorus phoenicis using standard methods was compare to biodiesel production using a homogeneous catalyst potassium hydroxide (KOH). Reaction parameters (reaction temperature and reaction time) were used for optimization of biodiesel production. The average values obtained for effect of time ranged from 42.30±0.20-63.10±1.30%, 49.30±1.50-64.70±1.00%, 71.40±0.70-79.80±0.20%, 80.46±0.20-97.10±0.30%, 81.20±1.20-86.10±1.60% and 79.39±0.40-83.90±0.50% for 30 minutes, 60 minutes, 90 minutes, 120 minutes, 150 minutes and 180 minutes respectively. Variation of temperature for the production of biodiesel from Carica papaya and Citrullus lanatus seed oil with KOH and Nanocomposite catalyst range from 63.09±0.60-95.20±1.55, 49.10±0.45-79.30±0.75, 66.00±1.00-97.10±0.45 and 59.20±0.95-83.40±0.85% for 40, 45, 50, 60, 80 and 90°C respectively. The optimum conditions for the trans=esterification process were 80°C reaction temperature, and 120 minutes reaction time.
    VL  - 8
    IS  - 2
    ER  - 

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Author Information
  • Institute of Natural Resources, Environment and Sustainable Development (Inres), University of Port Harcourt, Port Harcourt, Nigeria

  • Department of Plant Science and Biotechnology University of Port Harcourt, Port Harcourt, Nigeria

  • Department of Pure and Industrial Chemistry, University of Port Harcourt, Port Harcourt, Nigeria

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