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Comparison of Spectrophotometric Methods for Determination of Iron in Acid Cleaning, and Passivating Stainless Steel Solution by UV-VIS, ICP/MS, and FAAS

Received: 8 April 2021    Accepted: 28 April 2021    Published: 8 May 2021
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Abstract

Generally, more sophisticated techniques such as, flame atomic absorption (AAS), inductively coupled plasma spectrometer (ICP-MS), and UV/Visible Spectrophotometer were used to determine trace iron metals in pickling (acid cleaning), and passivating stainless steel solutions. Simple and novel spectrophotometric methods are described for simultaneous determination of iron. While these techniques provide excellent sensitivity and selectivity. The results were found to be in satisfactory agreement (shows no significant difference) with those acquired by the flame atomic absorption spectrophotometer (FAAS), UV-Vis Spectrometer, and ICP/MS techniques. The results shows that the concentration of iron are very close each other (less than 5.0%) in the pickling and passivating solutions.

Published in Science Journal of Analytical Chemistry (Volume 9, Issue 2)
DOI 10.11648/j.sjac.20210902.11
Page(s) 32-38
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Acid Cleaning (Pickling) Solution, Passivating Solution, Iron Determination, ICP-MS, UV-VIS Spectrophotometer, and FAAS

References
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[7] Eagleson, Mary (1994). Concise Encyclopedia Chemistry (revised ed.). Walter de Gruyter. p. 834. ISBN 978-3-11-011451-5.
[8] Monroe AS9100D&ISO 9001:2015 2990 Technology Dr. Rochester Hills, MI 48309.
[9] Y. Yildiz, A. Jan, S. Patel. Fluoride Determination in Pickling Solution of Stainless Steel by Ion Selective Electrode World Journal of Applied Chemistry, March 2018.
[10] Bohler Welding Nordic AB. Pickling Handbook. Surface Treatment of Stainless Steel.
[11] Avesta Sheffield Corrosion. Handbook for Stainless Steels, 1999.
[12] ASTM A 380/A380 M-13 Standard Practice for Cleaning, Descaling, and Passivation of Stainless Steel Parts, Equipment, and Systems; ASTM Committee of Standard. ASTM International, 100 Barr Harbor Drive, West Conshohocken, PA, 2013. www.astm.org
[13] Standard Operating Procedures. Determination of Metals by Inductively Coupled Plasma (ICP) Methods. (EPA/SW-846 Methods 30115/3050B/6010B
[14] Y. Yildiz, A. Jan, L. Pendyala, B. Yildiz Determination of Tin in Trityl Candesartan by UV-VIS Spectrophotometer using Phenylfluorone. World Journal of Applied Chemistry, October 20, 2107, 2 (4): 134-13
[15] Y. Yildiz, M. Kotb, A. Hussein, M. Sayedahmed, M. Rachid, M. Cheema Determination of Palladium (II) in 5% Pd BaSO4 by ICP/MS with Microwave Digestion, and UV-VIS Spectrophotometry. American Journal of Analytical Chemistry, volume 10, Number 4, April 2019.
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[18] Y. Yildiz, R. Karadag, M. Cordera, B. Gensinger Determination of Manganese in Tricalcium Phosphate (TCP) by Atomic Absorption Spectrometry. American Journal of Chemistry 2020, 11, 301-308.
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Cite This Article
  • APA Style

    Yusuf Yildiz, Recep Karadag, Irmak Cengiz. (2021). Comparison of Spectrophotometric Methods for Determination of Iron in Acid Cleaning, and Passivating Stainless Steel Solution by UV-VIS, ICP/MS, and FAAS. Science Journal of Analytical Chemistry, 9(2), 32-38. https://doi.org/10.11648/j.sjac.20210902.11

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    ACS Style

    Yusuf Yildiz; Recep Karadag; Irmak Cengiz. Comparison of Spectrophotometric Methods for Determination of Iron in Acid Cleaning, and Passivating Stainless Steel Solution by UV-VIS, ICP/MS, and FAAS. Sci. J. Anal. Chem. 2021, 9(2), 32-38. doi: 10.11648/j.sjac.20210902.11

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    AMA Style

    Yusuf Yildiz, Recep Karadag, Irmak Cengiz. Comparison of Spectrophotometric Methods for Determination of Iron in Acid Cleaning, and Passivating Stainless Steel Solution by UV-VIS, ICP/MS, and FAAS. Sci J Anal Chem. 2021;9(2):32-38. doi: 10.11648/j.sjac.20210902.11

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  • @article{10.11648/j.sjac.20210902.11,
      author = {Yusuf Yildiz and Recep Karadag and Irmak Cengiz},
      title = {Comparison of Spectrophotometric Methods for Determination of Iron in Acid Cleaning, and Passivating Stainless Steel Solution by UV-VIS, ICP/MS, and FAAS},
      journal = {Science Journal of Analytical Chemistry},
      volume = {9},
      number = {2},
      pages = {32-38},
      doi = {10.11648/j.sjac.20210902.11},
      url = {https://doi.org/10.11648/j.sjac.20210902.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjac.20210902.11},
      abstract = {Generally, more sophisticated techniques such as, flame atomic absorption (AAS), inductively coupled plasma spectrometer (ICP-MS), and UV/Visible Spectrophotometer were used to determine trace iron metals in  pickling (acid cleaning), and passivating stainless steel solutions. Simple and novel spectrophotometric methods are described for simultaneous determination of iron. While these techniques provide excellent sensitivity and selectivity. The results were found to be in satisfactory agreement (shows no significant difference) with those acquired by the flame atomic absorption spectrophotometer (FAAS), UV-Vis Spectrometer, and ICP/MS techniques. The results shows that the concentration of iron are very close each other (less than 5.0%) in the pickling and passivating solutions.},
     year = {2021}
    }
    

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  • TY  - JOUR
    T1  - Comparison of Spectrophotometric Methods for Determination of Iron in Acid Cleaning, and Passivating Stainless Steel Solution by UV-VIS, ICP/MS, and FAAS
    AU  - Yusuf Yildiz
    AU  - Recep Karadag
    AU  - Irmak Cengiz
    Y1  - 2021/05/08
    PY  - 2021
    N1  - https://doi.org/10.11648/j.sjac.20210902.11
    DO  - 10.11648/j.sjac.20210902.11
    T2  - Science Journal of Analytical Chemistry
    JF  - Science Journal of Analytical Chemistry
    JO  - Science Journal of Analytical Chemistry
    SP  - 32
    EP  - 38
    PB  - Science Publishing Group
    SN  - 2376-8053
    UR  - https://doi.org/10.11648/j.sjac.20210902.11
    AB  - Generally, more sophisticated techniques such as, flame atomic absorption (AAS), inductively coupled plasma spectrometer (ICP-MS), and UV/Visible Spectrophotometer were used to determine trace iron metals in  pickling (acid cleaning), and passivating stainless steel solutions. Simple and novel spectrophotometric methods are described for simultaneous determination of iron. While these techniques provide excellent sensitivity and selectivity. The results were found to be in satisfactory agreement (shows no significant difference) with those acquired by the flame atomic absorption spectrophotometer (FAAS), UV-Vis Spectrometer, and ICP/MS techniques. The results shows that the concentration of iron are very close each other (less than 5.0%) in the pickling and passivating solutions.
    VL  - 9
    IS  - 2
    ER  - 

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Author Information
  • John F. Kennedy Educational Complex, ACT Academy Science Department, Paterson NJ, USA

  • Istanbul Aydin University, Florya Campus Istanbul, Istanbul, Turkey

  • Chemical Engineering Department, Mersin University, Mersin, Turkey

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