Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate

Kazim Guliyev; Afat Aliyeva; Gulnara Ponomaryova; Abasgulu Guliyev; Dilbar Nurullayeva

doi:doi:10.11648/j.ajac.20150301.14

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Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate

Kazim Guliyev, Afat Aliyeva, Gulnara Ponomaryova, Abasgulu Guliyev, Dilbar Nurullayeva

Published in American Journal of Applied Chemistry (Volume 3, Issue 1)

Received: 25 December 2014 Accepted: 20 January 2015 Published: 2 February 2015

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Abstract

The radical copolymerization of (p-vinyl phenyl) cyclopropyl methyl cinnamate with methyl methacrylate has been studied. New cyclopropane-containing photosensitive copolymers have been prepared. The constant values of relative activity of monomers have been determined and the parameters of Q-e on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with methyl methacrylate (r2) calculated on Fineman-Ross method are r1 =1.05, r2 = 0.4, respectively; parameter values Q and e: Q1 =2.5, e1 = -0.9, respectively. The composition and structure of these copolymers have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that a structuring proceeds due to opening of cyclopropane ring and carbonyl groups and also double bond in cinnamate fragment.

Published in	American Journal of Applied Chemistry (Volume 3, Issue 1)
DOI	10.11648/j.ajac.20150301.14
Page(s)	21-24
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Copolymerization, P-Vinylphenyl) Cyclopropyl Methylcinnamate, Photosensitivity

References

[1]	Bokov Yu.S. “Photo-, electron- and X-ray resist”. Radio and bonds, p.136, 1982.
[2]	Filichkina V.N. Khim.promyshlennost za rubezhom (Chem.industry abroad), № 11. pp. 11-27, 1985.
[3]	Rupyshev V.G., Ivanko M.P., Kozlova G.I. et al. Plast.massy., № 3. pp. 58-59, 1983.
[4]	Tsarev P.K., Baranov V.G., Lipatov Yu.S. Vysokomolek.soyed. (High-molecular compounds), 12Б. pp. 115-117 (1970).
[5]	Galaktionov D. Plastics. № 7-8, p.53, 2007.
[6]	Vayner A.Ya., Dyumaev K.M. Khim.promyshlennost., № 7. p.3, 1989.
[7]	Vayner A.Ya., Dyumaev K.M., Likhachev I.A.et al. Dokl. Akademii Nauk (DAN), 396. № 3. pp. 362-365, 2004.
[8]	Hou H., Jiang J., Ding M. Eur. Polym. J, 35. N 11. p. 1993, 1999.
[9]	Guliyev K.G., Ponomaryeva G.Z., Guliyev A.M. ZhPKh, 79. № 3. pp. 497-500, 2006.
[10]	Guliyev K.G., Ponomaryeva G.Z., Guliyev A.M. Vysokomolek.soyed., 49Б, № 8, pp. 1577-1581, 2007.
[11]	Guliyev K.G., Ponomaryeva G.Z., Mamedli S.B. Processes of petrochemistry and oil-refining, 10, № 2. pp. 183-186, 2009.
[12]	Guliyev K.G., Ponomaryeva G.Z., Alieva A.M/. Guliyev A.M. ZhPKh, 86, N 1, pp. 101-104, 2013.
[13]	Guliyev K.G. ZhPKh, 84, N 12, pp. 2030-2033, 2011.
[14]	Guliyev K.G., Ponomaryeva G.Z., Guliyev A.M. Processes of petrochemistry and oil-refining, № 1, pp. 40-43, 2003.
[15]	Kuznetsov E.V., Divgun S.M. et al. Practical work on chemistry and physics of polymers. M.: Khimiya, p. 256, 1977.
[16]	Zilberman E.N. Vysokomolek.soyed., 21Б, № 1, pp. 33-36, 1979.
[17]	Guliyev K.G., Ponomaryeva G.Z., Mamedli S.B., Guliyev A.M. Journal of Structural Chemistry, 50, № 4, pp. 720-722, 2009.

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APA Style

Kazim Guliyev, Afat Aliyeva, Gulnara Ponomaryova, Abasgulu Guliyev, Dilbar Nurullayeva. (2015). Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate. American Journal of Applied Chemistry, 3(1), 21-24. https://doi.org/10.11648/j.ajac.20150301.14

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ACS Style

Kazim Guliyev; Afat Aliyeva; Gulnara Ponomaryova; Abasgulu Guliyev; Dilbar Nurullayeva. Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate. Am. J. Appl. Chem. 2015, 3(1), 21-24. doi: 10.11648/j.ajac.20150301.14

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AMA Style

Kazim Guliyev, Afat Aliyeva, Gulnara Ponomaryova, Abasgulu Guliyev, Dilbar Nurullayeva. Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate. Am J Appl Chem. 2015;3(1):21-24. doi: 10.11648/j.ajac.20150301.14

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@article{10.11648/j.ajac.20150301.14,
  author = {Kazim Guliyev and Afat Aliyeva and Gulnara Ponomaryova and Abasgulu Guliyev and Dilbar Nurullayeva},
  title = {Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate},
  journal = {American Journal of Applied Chemistry},
  volume = {3},
  number = {1},
  pages = {21-24},
  doi = {10.11648/j.ajac.20150301.14},
  url = {https://doi.org/10.11648/j.ajac.20150301.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20150301.14},
  abstract = {The radical copolymerization of (p-vinyl phenyl) cyclopropyl methyl cinnamate with methyl methacrylate has been studied. New cyclopropane-containing photosensitive copolymers have been prepared. The constant values of relative activity of monomers have been determined and the parameters of Q-e on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with methyl methacrylate (r2) calculated on Fineman-Ross method are r1 =1.05, r2 = 0.4, respectively; parameter values Q and e: Q1 =2.5, e1 = -0.9, respectively. The composition and structure of these copolymers have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that a structuring proceeds due to opening of cyclopropane ring and carbonyl groups and also double bond in cinnamate fragment.},
 year = {2015}
}

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TY  - JOUR
T1  - Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate
AU  - Kazim Guliyev
AU  - Afat Aliyeva
AU  - Gulnara Ponomaryova
AU  - Abasgulu Guliyev
AU  - Dilbar Nurullayeva
Y1  - 2015/02/02
PY  - 2015
N1  - https://doi.org/10.11648/j.ajac.20150301.14
DO  - 10.11648/j.ajac.20150301.14
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 21
EP  - 24
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20150301.14
AB  - The radical copolymerization of (p-vinyl phenyl) cyclopropyl methyl cinnamate with methyl methacrylate has been studied. New cyclopropane-containing photosensitive copolymers have been prepared. The constant values of relative activity of monomers have been determined and the parameters of Q-e on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with methyl methacrylate (r2) calculated on Fineman-Ross method are r1 =1.05, r2 = 0.4, respectively; parameter values Q and e: Q1 =2.5, e1 = -0.9, respectively. The composition and structure of these copolymers have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that a structuring proceeds due to opening of cyclopropane ring and carbonyl groups and also double bond in cinnamate fragment.
VL  - 3
IS  - 1
ER  -

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Author Information

Kazim Guliyev

Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Afat Aliyeva

Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Gulnara Ponomaryova

Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Abasgulu Guliyev

Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan
Dilbar Nurullayeva

Institute of Polymer Materials of Azerbaijan National Academy of Sciences, Sumgait, Azerbaijan

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Plain Text BibTeX RIS

APA Style

Kazim Guliyev, Afat Aliyeva, Gulnara Ponomaryova, Abasgulu Guliyev, Dilbar Nurullayeva. (2015). Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate. American Journal of Applied Chemistry, 3(1), 21-24. https://doi.org/10.11648/j.ajac.20150301.14

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ACS Style

Kazim Guliyev; Afat Aliyeva; Gulnara Ponomaryova; Abasgulu Guliyev; Dilbar Nurullayeva. Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate. Am. J. Appl. Chem. 2015, 3(1), 21-24. doi: 10.11648/j.ajac.20150301.14

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AMA Style

Kazim Guliyev, Afat Aliyeva, Gulnara Ponomaryova, Abasgulu Guliyev, Dilbar Nurullayeva. Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate. Am J Appl Chem. 2015;3(1):21-24. doi: 10.11648/j.ajac.20150301.14

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@article{10.11648/j.ajac.20150301.14,
  author = {Kazim Guliyev and Afat Aliyeva and Gulnara Ponomaryova and Abasgulu Guliyev and Dilbar Nurullayeva},
  title = {Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate},
  journal = {American Journal of Applied Chemistry},
  volume = {3},
  number = {1},
  pages = {21-24},
  doi = {10.11648/j.ajac.20150301.14},
  url = {https://doi.org/10.11648/j.ajac.20150301.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20150301.14},
  abstract = {The radical copolymerization of (p-vinyl phenyl) cyclopropyl methyl cinnamate with methyl methacrylate has been studied. New cyclopropane-containing photosensitive copolymers have been prepared. The constant values of relative activity of monomers have been determined and the parameters of Q-e on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with methyl methacrylate (r2) calculated on Fineman-Ross method are r1 =1.05, r2 = 0.4, respectively; parameter values Q and e: Q1 =2.5, e1 = -0.9, respectively. The composition and structure of these copolymers have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that a structuring proceeds due to opening of cyclopropane ring and carbonyl groups and also double bond in cinnamate fragment.},
 year = {2015}
}

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TY  - JOUR
T1  - Investigation of Photosensitivity of Copolymer with (P-Vinyl Phenyl) Cyclopropyl Methyl Cinnamate
AU  - Kazim Guliyev
AU  - Afat Aliyeva
AU  - Gulnara Ponomaryova
AU  - Abasgulu Guliyev
AU  - Dilbar Nurullayeva
Y1  - 2015/02/02
PY  - 2015
N1  - https://doi.org/10.11648/j.ajac.20150301.14
DO  - 10.11648/j.ajac.20150301.14
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 21
EP  - 24
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20150301.14
AB  - The radical copolymerization of (p-vinyl phenyl) cyclopropyl methyl cinnamate with methyl methacrylate has been studied. New cyclopropane-containing photosensitive copolymers have been prepared. The constant values of relative activity of monomers have been determined and the parameters of Q-e on Alfrey and Price have been calculated. The copolymerization constants of this compound (r1) with methyl methacrylate (r2) calculated on Fineman-Ross method are r1 =1.05, r2 = 0.4, respectively; parameter values Q and e: Q1 =2.5, e1 = -0.9, respectively. The composition and structure of these copolymers have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been established that a structuring proceeds due to opening of cyclopropane ring and carbonyl groups and also double bond in cinnamate fragment.
VL  - 3
IS  - 1
ER  -

Copy | Download