Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity

Andry Tahina Rabeharitsara; Maheriniaina Andriamasinoro Andriamandroso; Nambinina Richard Randriana; Rijalalaina Rakotosaona; Edouard Andrianarison; André Razafimandefitra; Baholy Robijaona

doi:doi:10.11648/j.ajac.20180601.12

Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity

Andry Tahina Rabeharitsara, Maheriniaina Andriamasinoro Andriamandroso, Nambinina Richard Randriana, Rijalalaina Rakotosaona, Edouard Andrianarison, André Razafimandefitra, Baholy Robijaona

Published in American Journal of Applied Chemistry (Volume 6, Issue 1)

Received: 11 September 2017 Accepted: 25 September 2017 Published: 23 December 2017

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Abstract

Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture.

Published in	American Journal of Applied Chemistry (Volume 6, Issue 1)
DOI	10.11648/j.ajac.20180601.12
Page(s)	6-14
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Citric Acid, Ammonia, Ethanol, Crystallization, Co-solvent Crystallization, Ammonium Di-hydrogenocitrate, Ammonium Mono-hydrogenocitrate, Sodium Bicarbonate, Swelling Test

References

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APA Style

Andry Tahina Rabeharitsara, Maheriniaina Andriamasinoro Andriamandroso, Nambinina Richard Randriana, Rijalalaina Rakotosaona, Edouard Andrianarison, et al. (2017). Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. American Journal of Applied Chemistry, 6(1), 6-14. https://doi.org/10.11648/j.ajac.20180601.12

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ACS Style

Andry Tahina Rabeharitsara; Maheriniaina Andriamasinoro Andriamandroso; Nambinina Richard Randriana; Rijalalaina Rakotosaona; Edouard Andrianarison, et al. Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. Am. J. Appl. Chem. 2017, 6(1), 6-14. doi: 10.11648/j.ajac.20180601.12

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AMA Style

Andry Tahina Rabeharitsara, Maheriniaina Andriamasinoro Andriamandroso, Nambinina Richard Randriana, Rijalalaina Rakotosaona, Edouard Andrianarison, et al. Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. Am J Appl Chem. 2017;6(1):6-14. doi: 10.11648/j.ajac.20180601.12

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@article{10.11648/j.ajac.20180601.12,
  author = {Andry Tahina Rabeharitsara and Maheriniaina Andriamasinoro Andriamandroso and Nambinina Richard Randriana and Rijalalaina Rakotosaona and Edouard Andrianarison and André Razafimandefitra and Baholy Robijaona},
  title = {Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity},
  journal = {American Journal of Applied Chemistry},
  volume = {6},
  number = {1},
  pages = {6-14},
  doi = {10.11648/j.ajac.20180601.12},
  url = {https://doi.org/10.11648/j.ajac.20180601.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180601.12},
  abstract = {Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture.},
 year = {2017}
}

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TY  - JOUR
T1  - Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity
AU  - Andry Tahina Rabeharitsara
AU  - Maheriniaina Andriamasinoro Andriamandroso
AU  - Nambinina Richard Randriana
AU  - Rijalalaina Rakotosaona
AU  - Edouard Andrianarison
AU  - André Razafimandefitra
AU  - Baholy Robijaona
Y1  - 2017/12/23
PY  - 2017
N1  - https://doi.org/10.11648/j.ajac.20180601.12
DO  - 10.11648/j.ajac.20180601.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 6
EP  - 14
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20180601.12
AB  - Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture.
VL  - 6
IS  - 1
ER  -

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Author Information

Andry Tahina Rabeharitsara

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Maheriniaina Andriamasinoro Andriamandroso

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Nambinina Richard Randriana

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Rijalalaina Rakotosaona

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Edouard Andrianarison

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
André Razafimandefitra

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar
Baholy Robijaona

Chemical Process Engineering Department (E. S. P. A), Antananarivo University, Antananarivo, Madagascar

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APA Style

Andry Tahina Rabeharitsara, Maheriniaina Andriamasinoro Andriamandroso, Nambinina Richard Randriana, Rijalalaina Rakotosaona, Edouard Andrianarison, et al. (2017). Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. American Journal of Applied Chemistry, 6(1), 6-14. https://doi.org/10.11648/j.ajac.20180601.12

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ACS Style

Andry Tahina Rabeharitsara; Maheriniaina Andriamasinoro Andriamandroso; Nambinina Richard Randriana; Rijalalaina Rakotosaona; Edouard Andrianarison, et al. Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. Am. J. Appl. Chem. 2017, 6(1), 6-14. doi: 10.11648/j.ajac.20180601.12

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AMA Style

Andry Tahina Rabeharitsara, Maheriniaina Andriamasinoro Andriamandroso, Nambinina Richard Randriana, Rijalalaina Rakotosaona, Edouard Andrianarison, et al. Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity. Am J Appl Chem. 2017;6(1):6-14. doi: 10.11648/j.ajac.20180601.12

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@article{10.11648/j.ajac.20180601.12,
  author = {Andry Tahina Rabeharitsara and Maheriniaina Andriamasinoro Andriamandroso and Nambinina Richard Randriana and Rijalalaina Rakotosaona and Edouard Andrianarison and André Razafimandefitra and Baholy Robijaona},
  title = {Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity},
  journal = {American Journal of Applied Chemistry},
  volume = {6},
  number = {1},
  pages = {6-14},
  doi = {10.11648/j.ajac.20180601.12},
  url = {https://doi.org/10.11648/j.ajac.20180601.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20180601.12},
  abstract = {Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Ammonium Di-Hydrogenocitrate and Mono-Hydrogenocitrate Synthesis by Citric Acid Neutralization with Ammonia Using Ethanol as Co-Solvent for the Crystallization – Swelling Test to Confirm Gases Emissions Capacity
AU  - Andry Tahina Rabeharitsara
AU  - Maheriniaina Andriamasinoro Andriamandroso
AU  - Nambinina Richard Randriana
AU  - Rijalalaina Rakotosaona
AU  - Edouard Andrianarison
AU  - André Razafimandefitra
AU  - Baholy Robijaona
Y1  - 2017/12/23
PY  - 2017
N1  - https://doi.org/10.11648/j.ajac.20180601.12
DO  - 10.11648/j.ajac.20180601.12
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 6
EP  - 14
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20180601.12
AB  - Citric acid is a α-hydroxylated tricarboxylic acid present in abundance in lemon. More than one million tons of citric acid are industrially produced throughout the year. Our objective in this manuscript was to increase the value of the citric acid to ammonium citric acid salts by crystallization such as ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate. Studies and tests were carried out in this direction but the characteristic of our last process was the use of a co-solvent ethanol which proved more effective and more economical. At the end, we tested the capacity of the ammonium Di-hydrogenocitrate and the ammonium mono-hydrogenocitrate to swell a mixture and compared theirs capacities to the sodium bicarbonate. Results showed an excellent swelling capacity of the ammonium Di-hydrogenocitrate and ammonium mono-hydrogenocitrate to produce a uniformly very not much porous product’s texture.
VL  - 6
IS  - 1
ER  -

Copy | Download