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Electrical Resistivity Behavior and Small Polaron Conduction Transport Mechanism in Semiconducting RMnO3 Manganites

Received: 21 January 2024     Accepted: 3 February 2024     Published: 28 February 2024
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Abstract

Rare earth manganites, denoted by the chemical formula RMnO3, where R signifies a rare earth element, have garnered significant interest in recent years. These perovskite oxides exhibit intriguing phenomena such as multiferroicity, ferroelectricity, and colossal magnetoresistance, primarily attributed to the role of polarons in conduction. The incorporation of rare earth ions imparts flexibility, making these compounds promising for applications in spintronics, sensors, and information storage devices. This study delves into the electrical resistivity behavior and Small Polaron Conduction (SPC) mechanisms of rare earth manganites, particularly RMnO3. In this manuscript, electrical resistivity of the pristine RMnO3 (R = Sm, Eu, Gd) manganites are analyzed within the framework of adiabatic nearest-neighbor hopping of SPC. The high temperature state of RMnO3 within the SPC mechanism is influenced by polaron concentration, hopping distance, and resistivity coefficient. The localized charge carriers in undoped manganites enable one to estimate the activation energy for the electrical conduction. The activation energy decreases with the decrease in ionic radii from Sm to Gd. Deduced polaron activation energy is low for GdMnO3 as compared to SmMnO3 and is attributed to reducing disorder state in GdMnO3 as compared to SmMnO3. This work contributes to the fundamental understanding of condensed matter physics and the potential applications of rare earth manganites in emerging technologies. The interplay between electrical resistivity and Small Polaron Conduction offers insights for customizing these materials for specific technological needs.

Published in Advances in Materials (Volume 13, Issue 1)
DOI 10.11648/j.am.20241301.13
Page(s) 16-19
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Manganites, Polaron, Small Polaron Conduction, Electrical Properties

References
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[10] M. Jaime, M. B. Salamon, Electronic Transport in La-Ca Manganites. In: Kaplan T. A., Mahanti S. D. (eds) Physics of Manganites. Fundamental Materials Research. Springer, Boston, MA (2002).
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  • APA Style

    Kumar, A., Sharma, P., Fujun, Q., Jiang, H., Jin, C. (2024). Electrical Resistivity Behavior and Small Polaron Conduction Transport Mechanism in Semiconducting RMnO3 Manganites. Advances in Materials, 13(1), 16-19. https://doi.org/10.11648/j.am.20241301.13

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    ACS Style

    Kumar, A.; Sharma, P.; Fujun, Q.; Jiang, H.; Jin, C. Electrical Resistivity Behavior and Small Polaron Conduction Transport Mechanism in Semiconducting RMnO3 Manganites. Adv. Mater. 2024, 13(1), 16-19. doi: 10.11648/j.am.20241301.13

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    AMA Style

    Kumar A, Sharma P, Fujun Q, Jiang H, Jin C. Electrical Resistivity Behavior and Small Polaron Conduction Transport Mechanism in Semiconducting RMnO3 Manganites. Adv Mater. 2024;13(1):16-19. doi: 10.11648/j.am.20241301.13

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  • @article{10.11648/j.am.20241301.13,
      author = {Ashwini Kumar and Poorva Sharma and Qiu Fujun and Hu Jiang and Cui Jin},
      title = {Electrical Resistivity Behavior and Small Polaron Conduction Transport Mechanism in Semiconducting RMnO3 Manganites},
      journal = {Advances in Materials},
      volume = {13},
      number = {1},
      pages = {16-19},
      doi = {10.11648/j.am.20241301.13},
      url = {https://doi.org/10.11648/j.am.20241301.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20241301.13},
      abstract = {Rare earth manganites, denoted by the chemical formula RMnO3, where R signifies a rare earth element, have garnered significant interest in recent years. These perovskite oxides exhibit intriguing phenomena such as multiferroicity, ferroelectricity, and colossal magnetoresistance, primarily attributed to the role of polarons in conduction. The incorporation of rare earth ions imparts flexibility, making these compounds promising for applications in spintronics, sensors, and information storage devices. This study delves into the electrical resistivity behavior and Small Polaron Conduction (SPC) mechanisms of rare earth manganites, particularly RMnO3. In this manuscript, electrical resistivity of the pristine RMnO3 (R = Sm, Eu, Gd) manganites are analyzed within the framework of adiabatic nearest-neighbor hopping of SPC. The high temperature state of RMnO3 within the SPC mechanism is influenced by polaron concentration, hopping distance, and resistivity coefficient. The localized charge carriers in undoped manganites enable one to estimate the activation energy for the electrical conduction. The activation energy decreases with the decrease in ionic radii from Sm to Gd. Deduced polaron activation energy is low for GdMnO3 as compared to SmMnO3 and is attributed to reducing disorder state in GdMnO3 as compared to SmMnO3. This work contributes to the fundamental understanding of condensed matter physics and the potential applications of rare earth manganites in emerging technologies. The interplay between electrical resistivity and Small Polaron Conduction offers insights for customizing these materials for specific technological needs.
    },
     year = {2024}
    }
    

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  • TY  - JOUR
    T1  - Electrical Resistivity Behavior and Small Polaron Conduction Transport Mechanism in Semiconducting RMnO3 Manganites
    AU  - Ashwini Kumar
    AU  - Poorva Sharma
    AU  - Qiu Fujun
    AU  - Hu Jiang
    AU  - Cui Jin
    Y1  - 2024/02/28
    PY  - 2024
    N1  - https://doi.org/10.11648/j.am.20241301.13
    DO  - 10.11648/j.am.20241301.13
    T2  - Advances in Materials
    JF  - Advances in Materials
    JO  - Advances in Materials
    SP  - 16
    EP  - 19
    PB  - Science Publishing Group
    SN  - 2327-252X
    UR  - https://doi.org/10.11648/j.am.20241301.13
    AB  - Rare earth manganites, denoted by the chemical formula RMnO3, where R signifies a rare earth element, have garnered significant interest in recent years. These perovskite oxides exhibit intriguing phenomena such as multiferroicity, ferroelectricity, and colossal magnetoresistance, primarily attributed to the role of polarons in conduction. The incorporation of rare earth ions imparts flexibility, making these compounds promising for applications in spintronics, sensors, and information storage devices. This study delves into the electrical resistivity behavior and Small Polaron Conduction (SPC) mechanisms of rare earth manganites, particularly RMnO3. In this manuscript, electrical resistivity of the pristine RMnO3 (R = Sm, Eu, Gd) manganites are analyzed within the framework of adiabatic nearest-neighbor hopping of SPC. The high temperature state of RMnO3 within the SPC mechanism is influenced by polaron concentration, hopping distance, and resistivity coefficient. The localized charge carriers in undoped manganites enable one to estimate the activation energy for the electrical conduction. The activation energy decreases with the decrease in ionic radii from Sm to Gd. Deduced polaron activation energy is low for GdMnO3 as compared to SmMnO3 and is attributed to reducing disorder state in GdMnO3 as compared to SmMnO3. This work contributes to the fundamental understanding of condensed matter physics and the potential applications of rare earth manganites in emerging technologies. The interplay between electrical resistivity and Small Polaron Conduction offers insights for customizing these materials for specific technological needs.
    
    VL  - 13
    IS  - 1
    ER  - 

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Author Information
  • School of Electrical and Electronics Engineering, Luzhou Vocational and Technical College, Luzhou, People’s Republic of China

  • School of Electrical and Electronics Engineering, Luzhou Vocational and Technical College, Luzhou, People’s Republic of China

  • School of Electrical and Electronics Engineering, Luzhou Vocational and Technical College, Luzhou, People’s Republic of China

  • School of Electrical and Electronics Engineering, Luzhou Vocational and Technical College, Luzhou, People’s Republic of China

  • School of Electrical and Electronics Engineering, Luzhou Vocational and Technical College, Luzhou, People’s Republic of China

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