Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake

Amer T. E.; Abdellah W. M.; Abdel Wahab G. M.; El-Shahat M. F.

doi:doi:10.11648/j.cbe.20160101.15

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Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake

Amer T. E., Abdellah W. M., Abdel Wahab G. M., El-Shahat M. F.

Published in Chemical and Biomolecular Engineering (Volume 1, Issue 1)

Received: 28 November 2016 Accepted: 10 December 2016 Published: 10 January 2017

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Abstract

The present work is concerned with selective separation of Y and Ce (IV) from the lanthanides cake prepared from the pregnant sulfate leach liquor of Abu Hamata sandy claystone ore material. This sulfate solution assays 0.32 g/L of Ln, 0.45 g/L of U together with 0.05 g/L V and 0.008 g/L B. It was used to prepare the lanthanides cake that contains 12.2% of Y and 37.4% of Ce. Ammonium carbonate solution in concentration of 200g/L was used for dissolving more than 95.1% of Y content selectively from the prepared lanthanides cake. The free Y lanthanides cake was then subjected to Ce (IV) separation via dissolving the other trivalent lanthanides in dilute hydrochloric acid while Ce(IV) remains insoluble.

Published in	Chemical and Biomolecular Engineering (Volume 1, Issue 1)
DOI	10.11648/j.cbe.20160101.15
Page(s)	26-31
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Sandy Claystone Ore, Agitation Leaching, Ln Direct Precipitation, (NH₄)₂CO₃, Y, Ce(IV)

References

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[8]	De Vasconcellos M. E., Da Rocha S. M. R., Pedreira, W. R., Queiroz, C. A. S. and Abrao, A. Solubility behavior of rare earths with ammonium carbonate and ammonium carbonate plus ammonium hydroxide:Precipitation of their peroxicarbonates, Alloys and Compounds, 2008, 451: 426–428.
[9]	Kedari, C. S., Pandit, S. S. and Ramanujam, A. Studies on the in situ electrooxidation and selective permeation of cerium (IV) across a bulk liquid membrane containing tributyl phosphate as the ion transporter. Sep. Sci. Technol., 1999, 34 (9): 1907–1923.
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Amer T. E., Abdellah W. M., Abdel Wahab G. M., El-Shahat M. F. (2017). Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake. Chemical and Biomolecular Engineering, 1(1), 26-31. https://doi.org/10.11648/j.cbe.20160101.15

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ACS Style

Amer T. E.; Abdellah W. M.; Abdel Wahab G. M.; El-Shahat M. F. Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake. Chem. Biomol. Eng. 2017, 1(1), 26-31. doi: 10.11648/j.cbe.20160101.15

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AMA Style

Amer T. E., Abdellah W. M., Abdel Wahab G. M., El-Shahat M. F. Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake. Chem Biomol Eng. 2017;1(1):26-31. doi: 10.11648/j.cbe.20160101.15

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@article{10.11648/j.cbe.20160101.15,
  author = {Amer T. E. and Abdellah W. M. and Abdel Wahab G. M. and El-Shahat M. F.},
  title = {Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake},
  journal = {Chemical and Biomolecular Engineering},
  volume = {1},
  number = {1},
  pages = {26-31},
  doi = {10.11648/j.cbe.20160101.15},
  url = {https://doi.org/10.11648/j.cbe.20160101.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20160101.15},
  abstract = {The present work is concerned with selective separation of Y and Ce (IV) from the lanthanides cake prepared from the pregnant sulfate leach liquor of Abu Hamata sandy claystone ore material. This sulfate solution assays 0.32 g/L of Ln, 0.45 g/L of U together with 0.05 g/L V and 0.008 g/L B. It was used to prepare the lanthanides cake that contains 12.2% of Y and 37.4% of Ce. Ammonium carbonate solution in concentration of 200g/L was used for dissolving more than 95.1% of Y content selectively from the prepared lanthanides cake. The free Y lanthanides cake was then subjected to Ce (IV) separation via dissolving the other trivalent lanthanides in dilute hydrochloric acid while Ce(IV) remains insoluble.},
 year = {2017}
}

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TY  - JOUR
T1  - Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake
AU  - Amer T. E.
AU  - Abdellah W. M.
AU  - Abdel Wahab G. M.
AU  - El-Shahat M. F.
Y1  - 2017/01/10
PY  - 2017
N1  - https://doi.org/10.11648/j.cbe.20160101.15
DO  - 10.11648/j.cbe.20160101.15
T2  - Chemical and Biomolecular Engineering
JF  - Chemical and Biomolecular Engineering
JO  - Chemical and Biomolecular Engineering
SP  - 26
EP  - 31
PB  - Science Publishing Group
SN  - 2578-8884
UR  - https://doi.org/10.11648/j.cbe.20160101.15
AB  - The present work is concerned with selective separation of Y and Ce (IV) from the lanthanides cake prepared from the pregnant sulfate leach liquor of Abu Hamata sandy claystone ore material. This sulfate solution assays 0.32 g/L of Ln, 0.45 g/L of U together with 0.05 g/L V and 0.008 g/L B. It was used to prepare the lanthanides cake that contains 12.2% of Y and 37.4% of Ce. Ammonium carbonate solution in concentration of 200g/L was used for dissolving more than 95.1% of Y content selectively from the prepared lanthanides cake. The free Y lanthanides cake was then subjected to Ce (IV) separation via dissolving the other trivalent lanthanides in dilute hydrochloric acid while Ce(IV) remains insoluble.
VL  - 1
IS  - 1
ER  -

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Author Information

Amer T. E.

Nuclear Materials Authority, El-Maadi, Cairo, Egypt
Abdellah W. M.

Nuclear Materials Authority, El-Maadi, Cairo, Egypt
Abdel Wahab G. M.

Nuclear Materials Authority, El-Maadi, Cairo, Egypt
El-Shahat M. F.

Chemistry Department, Faculty of Science, Ain Shams University, Cairo, Egypt

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Plain Text BibTeX RIS

APA Style

Amer T. E., Abdellah W. M., Abdel Wahab G. M., El-Shahat M. F. (2017). Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake. Chemical and Biomolecular Engineering, 1(1), 26-31. https://doi.org/10.11648/j.cbe.20160101.15

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ACS Style

Amer T. E.; Abdellah W. M.; Abdel Wahab G. M.; El-Shahat M. F. Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake. Chem. Biomol. Eng. 2017, 1(1), 26-31. doi: 10.11648/j.cbe.20160101.15

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AMA Style

Amer T. E., Abdellah W. M., Abdel Wahab G. M., El-Shahat M. F. Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake. Chem Biomol Eng. 2017;1(1):26-31. doi: 10.11648/j.cbe.20160101.15

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@article{10.11648/j.cbe.20160101.15,
  author = {Amer T. E. and Abdellah W. M. and Abdel Wahab G. M. and El-Shahat M. F.},
  title = {Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake},
  journal = {Chemical and Biomolecular Engineering},
  volume = {1},
  number = {1},
  pages = {26-31},
  doi = {10.11648/j.cbe.20160101.15},
  url = {https://doi.org/10.11648/j.cbe.20160101.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.cbe.20160101.15},
  abstract = {The present work is concerned with selective separation of Y and Ce (IV) from the lanthanides cake prepared from the pregnant sulfate leach liquor of Abu Hamata sandy claystone ore material. This sulfate solution assays 0.32 g/L of Ln, 0.45 g/L of U together with 0.05 g/L V and 0.008 g/L B. It was used to prepare the lanthanides cake that contains 12.2% of Y and 37.4% of Ce. Ammonium carbonate solution in concentration of 200g/L was used for dissolving more than 95.1% of Y content selectively from the prepared lanthanides cake. The free Y lanthanides cake was then subjected to Ce (IV) separation via dissolving the other trivalent lanthanides in dilute hydrochloric acid while Ce(IV) remains insoluble.},
 year = {2017}
}

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TY  - JOUR
T1  - Selective Separation of Yttrium and Cerium (IV) from the Prepared Abu Hamata Lanthanides Cake
AU  - Amer T. E.
AU  - Abdellah W. M.
AU  - Abdel Wahab G. M.
AU  - El-Shahat M. F.
Y1  - 2017/01/10
PY  - 2017
N1  - https://doi.org/10.11648/j.cbe.20160101.15
DO  - 10.11648/j.cbe.20160101.15
T2  - Chemical and Biomolecular Engineering
JF  - Chemical and Biomolecular Engineering
JO  - Chemical and Biomolecular Engineering
SP  - 26
EP  - 31
PB  - Science Publishing Group
SN  - 2578-8884
UR  - https://doi.org/10.11648/j.cbe.20160101.15
AB  - The present work is concerned with selective separation of Y and Ce (IV) from the lanthanides cake prepared from the pregnant sulfate leach liquor of Abu Hamata sandy claystone ore material. This sulfate solution assays 0.32 g/L of Ln, 0.45 g/L of U together with 0.05 g/L V and 0.008 g/L B. It was used to prepare the lanthanides cake that contains 12.2% of Y and 37.4% of Ce. Ammonium carbonate solution in concentration of 200g/L was used for dissolving more than 95.1% of Y content selectively from the prepared lanthanides cake. The free Y lanthanides cake was then subjected to Ce (IV) separation via dissolving the other trivalent lanthanides in dilute hydrochloric acid while Ce(IV) remains insoluble.
VL  - 1
IS  - 1
ER  -

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