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Effect of Date Palm Seed Pod Ash and Eggshell Powder on the Physico-Mechanical Properties of Cement Blends

Received: 10 December 2022    Accepted: 3 January 2023    Published: 13 January 2023
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Abstract

The aim of this research was to investigate the effect of replacing eggshell powder (ESP) with date palm seed pod ash (DPSA), curing age and cement replacement on the properties of cement blended with ESP and/or DPSA on the water consistence, setting times and mortar compressive strengths according to ASTM standards. DPSA was produced by calcining date palm seed pod at 590°C for 8 hours followed by 630°C for 3 hours and the resultant ash was ground and sieve with a 90-micron sieve. Portland limestone cement CEM II 42.5R was employed and replaced by eggshell powder and DPSA at various proportions between 0 – 12.5 wt.% at interval of 2.5 wt.% for consistence and setting times whereas cement replacement was varied between 0 -8 wt.% at interval of 2 wt.% for the mortar compressive strength by using 50 mm cubes with a mixing ratio 1:3:5 (water, binder and sand). DPSA revealed high silica content of 42.75 wt.% with SiO2+Al2O3+Fe2O3 < 70% (45.38 wt.%) and hence may not be considered as a good pozzolana whereas ESP revealed a high lime content of 55.45 wt.% and considered a filler respectively using X-ray fluorescence spectrometer. Results indicated an increase in the water consistence for DPSA cement blend in comparison with control which related to either presence of unburnt carbon, clinker diminution or formation of magnesium hydroxide as a protective layer. Most of the cement blends experienced a diminution in the setting time compared to control except for cement blended with higher DPSA content. The accelerated and retarded setting times could possibly be due to available lime which favors ettringite instead of monosulfate and unburnt carbon present resulting in high water demand. The compressive strengths of both the control and cement experienced increments as curing age progressed with most of the blends exhibiting enhanced strength especially at the later stage at 28 and 60 days in comparison with control PLC. The reason for the enhanced strength at the later stage despite clinker diminution could be attributed to pozzolanic reaction between silica present in DPSA coupled with the available lime present in ESP. The optimal cement replacement of 4 wt.% was observed beyond which cement blends produced slightly lower strength in comparison with control owing to clinker diminution effect and higher water demand due to unburnt carbon present.

Published in American Journal of Science, Engineering and Technology (Volume 8, Issue 1)
DOI 10.11648/j.ajset.20230801.11
Page(s) 1-12
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Date Palm Seed Pod Ash, Eggshell Powder, Consistence, Setting Times, Compressive Strength

References
[1] Nasir M. and Al-Kutti W. Performance of Date Palm Ash as a Cementitious Material by Evaluating Strength, Durability, and Characterization Buildings 2019, 9, 6; 1-13.
[2] Olubajo O. O. Abdullahi Basiru, and Osha O. A. (2019) The potential of Orange Peel Ash as a Cement Replacement Material Path of Science, Vol. 6 Issue 2 pg. 1629-1635.
[3] Gunarani, G. I., Chakkravarthy, S. P. (2017). Experimental studies on effect of Date Seed Ash (DSA) on strength properties of cement sand mortar. IOP Conf. Ser. Earth Environ. Sci. 80, 012015.
[4] Al-Kutti W., Islam S. A. B. M and Nasir M. (2019) Potential use of date palm ash in cement-based materials Journal of King Saud University – Engineering Sciences 31, 26–31.
[5] Islam, M. M. U., Mo, K. H., Alengaram, U. J., Jumaat, M. Z., 2016. Mechanical and fresh properties of sustainable oil palm shell lightweight concrete incorporating palm oil fuel ash. J. Cleaner Product. 115, 307–314.
[6] Olubajo, O., Osha, O., El-Natafty, U., and Adamu, H. (2017). A study on Coal bottom ash and limestone effects on the hydration and physico-mechanical properties of ternary cement blends (Doctoral thesis). Abubakar Tafawa Balewa University, Bauchi, Nigeria.
[7] FAO, Statistical Databases. Food and Agricultural Organization of the United Nation. 2011, [http://faostat.fao.org].
[8] Vandepopuliere J. M., Al–Yousef Y., Lyons J. J., Dates and date pits as ingredients in broiler starting and coturnix quail breeder diets. Poultry Sci., 1995, 74, 1134–1142.
[9] Devshony S., Eteshola A., Shani A., Characteristics and some potential application of date palm (Phoenix Dactlifera L.) seeds and seed oil. J. Am. Oil Chem. Soc., 1992, 69, 595–597.
[10] Saddiq A. A., Bawazir A. E., Antimicrobial activity of date palm (Phoenix Dactylifera) pits extracts and its role in reducing the side effect of methyl prednisolone on some neurotransmitter content in the brain. 2010, Paper presented at the IV International Date Palm Conference, 15 March 2010, Abu Dhabi, UAE.
[11] Alhamed Y. A., Adsorption kinetics and performance of packed bed adsorber for phenol removal using activated carbon from dates’ stones. J. Hazard. Mater., 2009, 170, 763–770. 16.
[12] Al–Ithari A. J., Sathasivan A., Ahmed R., Vuthaluru H. B., Zhan W., Ahmed M., Superiority of date seed ash as an adsorbent over other ashes and ferric chloride in removing boron from seawater. Desalination Water Treat., 2011, 32, 324–328.
[13] Hossain M. Z., Waly M. I., Singh V., Sequeira V., Rahman M. S. Pol. J. Chemical Composition of Date–Pits and Its Potential for Developing Value–Added Product – a Review Food Nutr. Sci., 2014, Vol. 64, No. 4, pp. 215–226.
[14] Yousif O. M., Osman M. F., Alhadrami G. A., Evaluation of dates and date pits as dietary ingredients in tilapia (Oreochromis aureus) diets differing in protein sources. Biores. Technol., 1996, 57, 81–85.
[15] Clemens R., Kranz S., Mobley A. R., Nicklas T. A., Raimondi M. P., Rodriguez J. C., Slavin J. L., Warshaw H., Filling America’s fiber intake gap: summary of a roundtable to probe realistic solutions with a focus on grain–based foods. J. Nutr., 2012, 142, 1390S–1401S.
[16] Basuny A. M. M., Al–Marzooq M. A., Production of mayonnaise from date pit oil. Food Nutr. Sci., 2011, 2, 938–943.
[17] Massazza, F. and Costa, V. (2016). Aspects of the Pozzolanic Activity and Properties of Pozzolanic Cements. IL Cemento, 76, 3-18.
[18] Pepper, L. S. and Mather, B. D. (2018). Effectiveness of Mineral Admixtures in Preventing Excessive Expansion of Concrete Due to Alkali Aggregate Reaction. Proceeding ASTM, Vol. 59, pp. 1178 -1203.
[19] Caldrone, M. A., Gruber, K. A. and Burg, R. G. (2015). High Reactivity Metakaolin: A New Generation Admixture. Concrete International, 11 (3), 37-40.
[20] Chik, F. A. W., Bakar, B. H. A., Johari, M. A. M. and Jaya, R. P. (2012). Properties of Concrete Block Containing Rice Husk Ash Subjected to Girha. International Journal of Research and Reviews in Applied Sciences, 8 (1), 57-64.
[21] Coleman, N. J. and Page, C. L. (2017). Aspects of the Pore Solution Chemistry of Hydrated Cement Pastes Containing Metakaolin. Cement and Concrete Research, 27 (1), 147-154.
[22] Naik, T. R., Singh, S. S. and Hossain, M. M. (2016). Permeability of Concrete Containing Large Amounts of Fly Ash. Cement Concrete Research, 24 (5), 913-922.
[23] Balendran, R. V. and Martin, W. H. (2016). The Influence of High Temperature Curing on The Compressive, Tensile and Flexural Strength of Pulverized Fuel Ash Concrete. Building and Environment, 35 (5), 415-423.
[24] Adefemi, A., Nensok, M. H., Ka’ase, E. T. and Wuna, I. A. (2013). Exploratory Study of Date Seed as Coarse Aggregate in Concrete Production. Civil and Environment Research, IISTE 3 (1), 85 –92.
[25] Olanipekun, E. A., Olusola, K. O. and Ata, O. G. (2013). A Comparative Study of Concrete Properties using Coconut Shell and Palm Kernel Shell as Coarse Aggregates. Building and Environment, 41, 297 - 301.
[26] Alengaram, U. J., Mahmud, H., Jumaat, M. Z. and Shirazi, S. M. (2014). Effect of Aggregate Size and Proportion on Strength Properties of Palm Kernel Shell Concrete. International Journal of Physical Sciences, 5 (12), 1848-1856.
[27] Guarani G. I. and Chakravarthy S. P. (2017), IOP Conference Series: Earth and Environmental Science 80, 1-8.
[28] Nasir, M., Al-Amoudi, O. S. B., Al-Gahtani, H. J., Maslehuddin, M., 2016. Effect of casting temperature on strength and density of plain and blended cement concretes prepared and cured under hot weather conditions. Constr. Build. Mater. 112, 529–537.
[29] Zain, M. F. M., Islam, M. N., Mahmud, F., Jamil, M., 2011. Production of rice husk ash for use in concrete as a supplementary cementitious material. Constr. Build. Mater. 25, 798–805.
[30] V Smith A. S. J. Ogork E. N. Aboshio A. (2018). Effect of Particle size of Date palm seed ash on concrete properties USEP: Journal of Research Information in civil Engineering Vol. 15, No. 1. Pp. 2159-2171.
[31] M. Almograbi (2010). Durability study of lightweight concrete material made from date palm seeds (DPS) High Performance Structures and Materials V 69 WIT Transactions on The Built Environment, Vol 112, WIT Press.
[32] ASTM C 187 (2010). Standard test method for normal consistency of hydraulic cement. Annual Book of ASTM Standards.
[33] ASTM C 191 (2008). Standard test method for time of setting of hydraulic cement by Vicat needle. Annual Book of ASTM Standards.
[34] De Weerdt, K., Kjellsen, K. O., Sellevold, E. and Justnes, H. (2011). Synergy between fly ash and limestone powder in ternary cements. Cement and Concrete Composites, 33 (1), 30-38.
[35] Lothenbach, B., Le Saout, G., Gallucci, E., and Scrivener, K. (2008). Influence of limestone on the hydration of Portland cements. Cement and Concrete Research, 38 (6), 848-860.
[36] Olubajo, O. O, Isa Y. M., Ayeni S., Menta S. and Nwuhu W. (2020). A Study on Ordinary Portland cement blended with Rice Husk Ash and Metakaolin Path of Science, Vol. 6 Issue 1 pg. 3001-3019.
[37] Olubajo O. O., Osha O. A. and Abubakar J. (2020) Setting Times of Portland Cement Blended with Locust Bean Pod and Eggshell Ashes, American Journal of Chemical Engineering, Vol. 8 Issue 5 pg. 103-111.
[38] Kaya A. (2010) A study on blended bottom ash cements MSc. Thesis, Middle East Technical University. 1-73.
[39] Venkateswara, R., Kontham, G., Venkata, R., and Chundupalli, S. (2011). Effect of potassium chloride (KCl) on ordinary Portland cement (OPC) concrete. Research Journal of Chemical Sciences, 1 (2), 103–107.
[40] Deng, M. (1992). Mechanism of MgO expansion in cement. Cement and Concrete 22, 1-5.
[41] BS 4550-3-3.6 Methods of testing cement. Physical tests. Test for setting times.
[42] Erdoğan, T. Y. (2005). Materials of construction. Ankara: METU Press.
[43] Georgescu, M., and Saca, N. (2009). Properties of blended cements with limestone filler and fly ash content. Scientific Bulletin, Series B, 71 (3), 13-14, 16.
[44] Olubajo O. O. and Osha O. A. Influence of bottom ash and limestone powder on the properties of ternary cement and mortar. International Journal of Engineering Research and Technology 2013; 2 (7), 1201-1212.
[45] Bonavetti, V., Rahhal, V., and Irassar, E. (2001). Studies on the carboaluminate formation in limestone filler-blended cements. Cement and Concrete Research, 31 (6), 853–859. doi: 10.1016/s0008-8846(01)00491-4
[46] Soroka, I. and Setter, N. (1977). The effect of fillers on strength of cement mortars. Cement and Concrete Research, 7 (4), 449-456.
[47] Péra, J., Husson, S., and Guilhot, B. (1999). Influence of finely ground limestone on cement hydration. Cement and Concrete Composites, 21 (2), 99-105.
[48] Ramachandran, V. S. and Zhang C. (1986). Thermal analysis of the 3CaO•Al2O3-CaSO4•2H2O-CaCO3-H2O system. Thermo chimica acta, 106, 273-282.
[49] Gowsika, D., Sarankokila, S., and Sargunan, K. (2014). Experimental investigation of egg shell powder as partial replacement with cement in concrete. International Journal of Engineering Trends and Technology (IJETT), 14 (2), 65-68.
[50] Amarnath, Y. (2014). Properties of concrete with eggshell powder as cement replacement. Indian Concrete Journal pg. 1-10.
[51] Olubajo O. O., Abubakar J. and Osha O. A. (2020c) The Effect of Eggshell ash and Locust Bean Pod Ash on the Compressive Strength of Ternary Cement, Path of Science, Vol. 6 Issue 3 pg. 4001-4016.
[52] Ojewunmi, M., Ayomide, A., Obanla, O., Awolu, O., and Ojewunmi, E. (2016). Pozzolanic properties of waste agricultural biomass – African locust bean pod waste. World Journal of Environmental Biosciences, 6 (3), 1–7.
[53] Mahmoud, A. H. (2006): Effect of alkalis and sulfate on Portland cement systems. PHD dissertation. Department of Civil Engineering, University of South Florida.
[54] Yilmaz B., Olgun A., 2011 “Studies on Cement and Mortar Containing Low-Calcium fly ash Limestone, and dolomitic limestone”. Cement & Concrete Composites 30, 200.
[55] British Standard Institute BS 1881 (1983): Method for Testing of Concrete Compressive Strength.
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    Iliya Bila Auta, Ibrahim Ikara Abdulkarim, Olubajo Olumide Olu. (2023). Effect of Date Palm Seed Pod Ash and Eggshell Powder on the Physico-Mechanical Properties of Cement Blends. American Journal of Science, Engineering and Technology, 8(1), 1-12. https://doi.org/10.11648/j.ajset.20230801.11

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    ACS Style

    Iliya Bila Auta; Ibrahim Ikara Abdulkarim; Olubajo Olumide Olu. Effect of Date Palm Seed Pod Ash and Eggshell Powder on the Physico-Mechanical Properties of Cement Blends. Am. J. Sci. Eng. Technol. 2023, 8(1), 1-12. doi: 10.11648/j.ajset.20230801.11

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    AMA Style

    Iliya Bila Auta, Ibrahim Ikara Abdulkarim, Olubajo Olumide Olu. Effect of Date Palm Seed Pod Ash and Eggshell Powder on the Physico-Mechanical Properties of Cement Blends. Am J Sci Eng Technol. 2023;8(1):1-12. doi: 10.11648/j.ajset.20230801.11

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  • @article{10.11648/j.ajset.20230801.11,
      author = {Iliya Bila Auta and Ibrahim Ikara Abdulkarim and Olubajo Olumide Olu},
      title = {Effect of Date Palm Seed Pod Ash and Eggshell Powder on the Physico-Mechanical Properties of Cement Blends},
      journal = {American Journal of Science, Engineering and Technology},
      volume = {8},
      number = {1},
      pages = {1-12},
      doi = {10.11648/j.ajset.20230801.11},
      url = {https://doi.org/10.11648/j.ajset.20230801.11},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajset.20230801.11},
      abstract = {The aim of this research was to investigate the effect of replacing eggshell powder (ESP) with date palm seed pod ash (DPSA), curing age and cement replacement on the properties of cement blended with ESP and/or DPSA on the water consistence, setting times and mortar compressive strengths according to ASTM standards. DPSA was produced by calcining date palm seed pod at 590°C for 8 hours followed by 630°C for 3 hours and the resultant ash was ground and sieve with a 90-micron sieve. Portland limestone cement CEM II 42.5R was employed and replaced by eggshell powder and DPSA at various proportions between 0 – 12.5 wt.% at interval of 2.5 wt.% for consistence and setting times whereas cement replacement was varied between 0 -8 wt.% at interval of 2 wt.% for the mortar compressive strength by using 50 mm cubes with a mixing ratio 1:3:5 (water, binder and sand). DPSA revealed high silica content of 42.75 wt.% with SiO2+Al2O3+Fe2O3 < 70% (45.38 wt.%) and hence may not be considered as a good pozzolana whereas ESP revealed a high lime content of 55.45 wt.% and considered a filler respectively using X-ray fluorescence spectrometer. Results indicated an increase in the water consistence for DPSA cement blend in comparison with control which related to either presence of unburnt carbon, clinker diminution or formation of magnesium hydroxide as a protective layer. Most of the cement blends experienced a diminution in the setting time compared to control except for cement blended with higher DPSA content. The accelerated and retarded setting times could possibly be due to available lime which favors ettringite instead of monosulfate and unburnt carbon present resulting in high water demand. The compressive strengths of both the control and cement experienced increments as curing age progressed with most of the blends exhibiting enhanced strength especially at the later stage at 28 and 60 days in comparison with control PLC. The reason for the enhanced strength at the later stage despite clinker diminution could be attributed to pozzolanic reaction between silica present in DPSA coupled with the available lime present in ESP. The optimal cement replacement of 4 wt.% was observed beyond which cement blends produced slightly lower strength in comparison with control owing to clinker diminution effect and higher water demand due to unburnt carbon present.},
     year = {2023}
    }
    

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  • TY  - JOUR
    T1  - Effect of Date Palm Seed Pod Ash and Eggshell Powder on the Physico-Mechanical Properties of Cement Blends
    AU  - Iliya Bila Auta
    AU  - Ibrahim Ikara Abdulkarim
    AU  - Olubajo Olumide Olu
    Y1  - 2023/01/13
    PY  - 2023
    N1  - https://doi.org/10.11648/j.ajset.20230801.11
    DO  - 10.11648/j.ajset.20230801.11
    T2  - American Journal of Science, Engineering and Technology
    JF  - American Journal of Science, Engineering and Technology
    JO  - American Journal of Science, Engineering and Technology
    SP  - 1
    EP  - 12
    PB  - Science Publishing Group
    SN  - 2578-8353
    UR  - https://doi.org/10.11648/j.ajset.20230801.11
    AB  - The aim of this research was to investigate the effect of replacing eggshell powder (ESP) with date palm seed pod ash (DPSA), curing age and cement replacement on the properties of cement blended with ESP and/or DPSA on the water consistence, setting times and mortar compressive strengths according to ASTM standards. DPSA was produced by calcining date palm seed pod at 590°C for 8 hours followed by 630°C for 3 hours and the resultant ash was ground and sieve with a 90-micron sieve. Portland limestone cement CEM II 42.5R was employed and replaced by eggshell powder and DPSA at various proportions between 0 – 12.5 wt.% at interval of 2.5 wt.% for consistence and setting times whereas cement replacement was varied between 0 -8 wt.% at interval of 2 wt.% for the mortar compressive strength by using 50 mm cubes with a mixing ratio 1:3:5 (water, binder and sand). DPSA revealed high silica content of 42.75 wt.% with SiO2+Al2O3+Fe2O3 < 70% (45.38 wt.%) and hence may not be considered as a good pozzolana whereas ESP revealed a high lime content of 55.45 wt.% and considered a filler respectively using X-ray fluorescence spectrometer. Results indicated an increase in the water consistence for DPSA cement blend in comparison with control which related to either presence of unburnt carbon, clinker diminution or formation of magnesium hydroxide as a protective layer. Most of the cement blends experienced a diminution in the setting time compared to control except for cement blended with higher DPSA content. The accelerated and retarded setting times could possibly be due to available lime which favors ettringite instead of monosulfate and unburnt carbon present resulting in high water demand. The compressive strengths of both the control and cement experienced increments as curing age progressed with most of the blends exhibiting enhanced strength especially at the later stage at 28 and 60 days in comparison with control PLC. The reason for the enhanced strength at the later stage despite clinker diminution could be attributed to pozzolanic reaction between silica present in DPSA coupled with the available lime present in ESP. The optimal cement replacement of 4 wt.% was observed beyond which cement blends produced slightly lower strength in comparison with control owing to clinker diminution effect and higher water demand due to unburnt carbon present.
    VL  - 8
    IS  - 1
    ER  - 

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Author Information
  • Department of Chemical Engineering, Abubakar Tafawa Balewa University, Bauchi, Nigeria

  • Department of Civil Engineering, Abubakar Tafawa Balewa University, Bauchi, Nigeria

  • Department of Chemical Engineering, Abubakar Tafawa Balewa University, Bauchi, Nigeria

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